Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Sulfur Functional Groups
Many organic molecules contain sulfur functional groups and have their own importance in chemistry as well as biology. Some of the organic molecules which contain sulfur functional groups and the corresponding sulfur functionality is given below:
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Chapter 2, Problem 2.36EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the given compound has to be written.

Concept Introduction:

IUPAC nomenclature for alkene:  There are about eight rules to be followed in giving IUPAC name for alkene.

  • The suffix –ane has to be replaced with the suffix –ene.  This is used to indicate the presence of double bond.
  • The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
  • The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond.  In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
  • The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
  • Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
  • In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
  • In case if substituents are present in cycloalkene, then the double‑bonded carbon atoms are numbered 1 and 2 in a direction where the substituent gets the lower number.
  • If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.  To indicate a double bond between carbon atom, double line is used.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the given compound has to be written.

Concept Introduction:

IUPAC nomenclature for alkene:  There are about eight rules to be followed in giving IUPAC name for alkene.

  • The suffix –ane has to be replaced with the suffix –ene.  This is used to indicate the presence of double bond.
  • The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
  • The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond.  In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
  • The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
  • Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
  • In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
  • In case if substituents are present in cycloalkene, then the double‑bonded carbon atoms are numbered 1 and 2 in a direction where the substituent gets the lower number.
  • If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.  To indicate a double bond between carbon atom, double line is used.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the given compound has to be written.

Concept Introduction:

IUPAC nomenclature for alkene:  There are about eight rules to be followed in giving IUPAC name for alkene.

  • The suffix –ane has to be replaced with the suffix –ene.  This is used to indicate the presence of double bond.
  • The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
  • The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond.  In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
  • The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
  • Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
  • In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
  • In case if substituents are present in cycloalkene, then the double‑bonded carbon atoms are numbered 1 and 2 in a direction where the substituent gets the lower number.
  • If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.  To indicate a double bond between carbon atom, double line is used.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the given compound has to be written.

Concept Introduction:

IUPAC nomenclature for alkene:  There are about eight rules to be followed in giving IUPAC name for alkene.

  • The suffix –ane has to be replaced with the suffix –ene.  This is used to indicate the presence of double bond.
  • The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
  • The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond.  In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
  • The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
  • Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
  • In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
  • In case if substituents are present in cycloalkene, then the double‑bonded carbon atoms are numbered 1 and 2 in a direction where the substituent gets the lower number.
  • If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.  To indicate a double bond between carbon atom, double line is used.

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Chapter 2 Solutions

Organic And Biological Chemistry

Ch. 2.1 - Prob. 1QQCh. 2.1 - Prob. 2QQCh. 2.1 - Prob. 3QQCh. 2.2 - Prob. 1QQCh. 2.2 - Prob. 2QQCh. 2.2 - Prob. 3QQCh. 2.2 - Prob. 4QQCh. 2.3 - Prob. 1QQCh. 2.3 - Prob. 2QQCh. 2.3 - Prob. 3QQ
Ch. 2.3 - Prob. 4QQCh. 2.4 - Prob. 1QQCh. 2.4 - Prob. 2QQCh. 2.5 - Prob. 1QQCh. 2.5 - Prob. 2QQCh. 2.5 - Prob. 3QQCh. 2.6 - Prob. 1QQCh. 2.6 - Prob. 2QQCh. 2.6 - Prob. 3QQCh. 2.7 - Prob. 1QQCh. 2.7 - Prob. 2QQCh. 2.7 - Prob. 3QQCh. 2.8 - Prob. 1QQCh. 2.8 - Prob. 2QQCh. 2.9 - Prob. 1QQCh. 2.9 - Prob. 2QQCh. 2.10 - Prob. 1QQCh. 2.10 - Prob. 2QQCh. 2.10 - Prob. 3QQCh. 2.10 - Prob. 4QQCh. 2.10 - Prob. 5QQCh. 2.11 - Prob. 1QQCh. 2.11 - Prob. 2QQCh. 2.11 - Prob. 3QQCh. 2.11 - Prob. 4QQCh. 2.11 - Prob. 5QQCh. 2.12 - Prob. 1QQCh. 2.12 - Prob. 2QQCh. 2.12 - Prob. 3QQCh. 2.12 - Prob. 4QQCh. 2.12 - Prob. 5QQCh. 2.13 - Prob. 1QQCh. 2.13 - Prob. 2QQCh. 2.13 - Prob. 3QQCh. 2.14 - Prob. 1QQCh. 2.14 - Prob. 2QQCh. 2.14 - Prob. 3QQCh. 2.14 - Prob. 4QQCh. 2.15 - Prob. 1QQCh. 2.15 - Prob. 2QQCh. 2.15 - Prob. 3QQCh. 2.15 - Prob. 4QQCh. 2.16 - Prob. 1QQCh. 2.16 - Prob. 2QQCh. 2 - Classify each of the following hydrocarbons as...Ch. 2 - Prob. 2.2EPCh. 2 - Prob. 2.3EPCh. 2 - Prob. 2.4EPCh. 2 - Prob. 2.5EPCh. 2 - Prob. 2.6EPCh. 2 - Prob. 2.7EPCh. 2 - Characterize the physical properties of saturated...Ch. 2 - Prob. 2.9EPCh. 2 - Prob. 2.10EPCh. 2 - Prob. 2.11EPCh. 2 - Prob. 2.12EPCh. 2 - Prob. 2.13EPCh. 2 - Prob. 2.14EPCh. 2 - What is the name of the spatial arrangement for...Ch. 2 - Prob. 2.16EPCh. 2 - Prob. 2.17EPCh. 2 - Prob. 2.18EPCh. 2 - Draw a condensed structural formula for each of...Ch. 2 - Prob. 2.20EPCh. 2 - The following names are incorrect by IUPAC rules....Ch. 2 - The following names are incorrect by IUPAC rules....Ch. 2 - Prob. 2.23EPCh. 2 - Draw a condensed structural formula for each of...Ch. 2 - Prob. 2.25EPCh. 2 - Classify each of the following compounds as...Ch. 2 - Prob. 2.27EPCh. 2 - How many hydrogen atoms are present in a molecule...Ch. 2 - Draw a line-angle structural formula for each of...Ch. 2 - Draw a line-angle structural formula for each of...Ch. 2 - Prob. 2.31EPCh. 2 - Prob. 2.32EPCh. 2 - Prob. 2.33EPCh. 2 - Prob. 2.34EPCh. 2 - Prob. 2.35EPCh. 2 - Prob. 2.36EPCh. 2 - Prob. 2.37EPCh. 2 - Prob. 2.38EPCh. 2 - For each of the following pairs of alkenes,...Ch. 2 - For each of the following pairs of alkenes,...Ch. 2 - Prob. 2.41EPCh. 2 - Prob. 2.42EPCh. 2 - Prob. 2.43EPCh. 2 - Prob. 2.44EPCh. 2 - Prob. 2.45EPCh. 2 - Prob. 2.46EPCh. 2 - For each molecule, indicate whether cistrans...Ch. 2 - Prob. 2.48EPCh. 2 - Prob. 2.49EPCh. 2 - Prob. 2.50EPCh. 2 - Draw a structural formula for each of the...Ch. 2 - Prob. 2.52EPCh. 2 - Prob. 2.53EPCh. 2 - For each of the following molecules, indicate...Ch. 2 - Prob. 2.55EPCh. 2 - Prob. 2.56EPCh. 2 - Prob. 2.57EPCh. 2 - Prob. 2.58EPCh. 2 - Prob. 2.59EPCh. 2 - How many isoprene units are present in a....Ch. 2 - Prob. 2.61EPCh. 2 - Indicate whether each of the following statements...Ch. 2 - Prob. 2.63EPCh. 2 - Prob. 2.64EPCh. 2 - Prob. 2.65EPCh. 2 - Prob. 2.66EPCh. 2 - Prob. 2.67EPCh. 2 - Prob. 2.68EPCh. 2 - Prob. 2.69EPCh. 2 - Prob. 2.70EPCh. 2 - Prob. 2.71EPCh. 2 - Prob. 2.72EPCh. 2 - Prob. 2.73EPCh. 2 - Prob. 2.74EPCh. 2 - Prob. 2.75EPCh. 2 - Prob. 2.76EPCh. 2 - Supply the structural formula of the product in...Ch. 2 - Prob. 2.78EPCh. 2 - Prob. 2.79EPCh. 2 - What reactant would you use to prepare each of the...Ch. 2 - Prob. 2.81EPCh. 2 - Prob. 2.82EPCh. 2 - Prob. 2.83EPCh. 2 - Prob. 2.84EPCh. 2 - Prob. 2.85EPCh. 2 - Prob. 2.86EPCh. 2 - Prob. 2.87EPCh. 2 - Prob. 2.88EPCh. 2 - Prob. 2.89EPCh. 2 - Prob. 2.90EPCh. 2 - Prob. 2.91EPCh. 2 - Prob. 2.92EPCh. 2 - Prob. 2.93EPCh. 2 - Prob. 2.94EPCh. 2 - Prob. 2.95EPCh. 2 - Prob. 2.96EPCh. 2 - Prob. 2.97EPCh. 2 - Prob. 2.98EPCh. 2 - Prob. 2.99EPCh. 2 - Prob. 2.100EPCh. 2 - Prob. 2.101EPCh. 2 - Prob. 2.102EPCh. 2 - Prob. 2.103EPCh. 2 - Prob. 2.104EPCh. 2 - Prob. 2.105EPCh. 2 - Prob. 2.106EPCh. 2 - Prob. 2.107EPCh. 2 - Prob. 2.108EPCh. 2 - Assign each of the compounds in Problem 13-107 an...Ch. 2 - Assign each of the compounds in Problem 13-108 an...Ch. 2 - Prob. 2.111EPCh. 2 - Prob. 2.112EPCh. 2 - Prob. 2.113EPCh. 2 - Prob. 2.114EPCh. 2 - Prob. 2.115EPCh. 2 - Prob. 2.116EPCh. 2 - Prob. 2.117EPCh. 2 - Prob. 2.118EPCh. 2 - Prob. 2.119EPCh. 2 - Prob. 2.120EPCh. 2 - Prob. 2.121EPCh. 2 - Prob. 2.122EPCh. 2 - Prob. 2.123EPCh. 2 - Prob. 2.124EPCh. 2 - Prob. 2.125EPCh. 2 - Prob. 2.126EPCh. 2 - Prob. 2.127EPCh. 2 - Prob. 2.128EPCh. 2 - Prob. 2.129EPCh. 2 - Prob. 2.130EP
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