Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Chapter 20, Problem 53E
Interpretation Introduction
Interpretation: The reaction corresponding to the decomposition of
Concept introduction: The expression to calculate the wavelength of light is,
To determine: The value of maximum wavelength of light is calculated for the given reaction using the bond energies.
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Chapter 20 Solutions
Chemistry
Ch. 20 - What are the two most abundant elements by mass in...Ch. 20 - Prob. 2RQCh. 20 - Prob. 3RQCh. 20 - What is the valence electron configuration for the...Ch. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Table 19-14 lists some common nitrogen compounds...Ch. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQ
Ch. 20 - Prob. 1QCh. 20 - Prob. 2QCh. 20 - Prob. 3QCh. 20 - Diagonal relationships in the periodic table exist...Ch. 20 - Prob. 6QCh. 20 - Prob. 7QCh. 20 - Prob. 8QCh. 20 - All the Group 1A (1) and 2A (2) metals are...Ch. 20 - Prob. 10QCh. 20 - Prob. 13ECh. 20 - Prob. 14ECh. 20 - Prob. 15ECh. 20 - Prob. 16ECh. 20 - Prob. 17ECh. 20 - Prob. 18ECh. 20 - Prob. 19ECh. 20 - Prob. 20ECh. 20 - Prob. 21ECh. 20 - Electrolysis of an alkaline earth metal chloride...Ch. 20 - Prob. 24ECh. 20 - Prob. 25ECh. 20 - Prob. 26ECh. 20 - Boron hydrides were once evaluated for possible...Ch. 20 - Prob. 28ECh. 20 - Prob. 29ECh. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - Prob. 32ECh. 20 - Prob. 33ECh. 20 - Prob. 34ECh. 20 - The following illustration shows the orbitals used...Ch. 20 - Prob. 36ECh. 20 - Silicon is produced for the chemical and...Ch. 20 - Prob. 38ECh. 20 - The compound Pb3O4 (red lead) contains a mixture...Ch. 20 - Prob. 40ECh. 20 - Prob. 41ECh. 20 - Prob. 42ECh. 20 - Prob. 43ECh. 20 - Prob. 44ECh. 20 - Prob. 45ECh. 20 - Prob. 46ECh. 20 - Prob. 47ECh. 20 - Prob. 48ECh. 20 - Prob. 49ECh. 20 - Phosphate buffers are important in regulating the...Ch. 20 - Prob. 51ECh. 20 - Trisodium phosphate (TSP) is an effective grease...Ch. 20 - Prob. 53ECh. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - Complete and balance each of the following...Ch. 20 - Prob. 57ECh. 20 - Prob. 58ECh. 20 - How can the paramagnetism of O2 be explained using...Ch. 20 - Describe the bonding in SO2 and SO3 using the...Ch. 20 - Write the Lewis structure for O2F2. Predict the...Ch. 20 - Give the Lewis structure, molecular structure, and...Ch. 20 - Prob. 63ECh. 20 - Prob. 64ECh. 20 - Prob. 65ECh. 20 - Prob. 66ECh. 20 - Prob. 67ECh. 20 - Prob. 68ECh. 20 - Prob. 69ECh. 20 - Prob. 70ECh. 20 - Prob. 71ECh. 20 - Prob. 72ECh. 20 - Prob. 73AECh. 20 - The inert-pair effect is sometimes used to explain...Ch. 20 - How could you determine experimentally whether the...Ch. 20 - Prob. 76AECh. 20 - Prob. 77AECh. 20 - Prob. 78AECh. 20 - Prob. 79AECh. 20 - Draw Lewis structures for the AsCl4+ and AsCl6...Ch. 20 - Prob. 81AECh. 20 - Prob. 82AECh. 20 - Prob. 83AECh. 20 - What is a disproportionation reaction? Use the...Ch. 20 - Sulfur forms a wide variety of compounds in which...Ch. 20 - Prob. 86AECh. 20 - Prob. 87CWPCh. 20 - Prob. 88CWPCh. 20 - Prob. 89CWPCh. 20 - Prob. 90CWPCh. 20 - Prob. 91CWPCh. 20 - Nitrous oxide (N2O) can be produced by thermal...Ch. 20 - What is the hybridization of the central atom in...Ch. 20 - Prob. 94CWPCh. 20 - Prob. 95CWPCh. 20 - Prob. 96CWPCh. 20 - Prob. 97CPCh. 20 - Prob. 98CPCh. 20 - Lead forms compounds in the +2 and +4 oxidation...Ch. 20 - Prob. 100CPCh. 20 - Prob. 101CPCh. 20 - Prob. 102CPCh. 20 - You travel to a distant, cold planet where the...Ch. 20 - Prob. 104CPCh. 20 - Prob. 105CPCh. 20 - Prob. 106IPCh. 20 - Prob. 107IPCh. 20 - Although nitrogen trifluoride (NF3) is a thermally...Ch. 20 - While selenic acid has the formula H2SeO4 and thus...Ch. 20 - Prob. 110MPCh. 20 - Prob. 111MP
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- Light of appropriate wavelength can break chemical bonds. Light having λ < 240 nm can dissociate gaseous O2. It requires light with λ < 819 nm to dissociate gaseous H2O2 to 2 OH. Assume that all of the photon energy is used solely for these dissociations. (a) Calculate the energy required to dissociate (i) O2 and (ii) H2O2. (b) Consider the results of part (a). How well do they correlate with the Lewis structures of O2 and H2O2? Explain your answer.arrow_forwardBond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardIn which of the following molecules does the sulfur have an expanded octet? For those that do, write the Lewis structure. (a) SO2 (b) SF4 (c) SO2Cl2 (d) SF6arrow_forward
- A Lewis structure obeying the octet rule can be drawn for O2 as follows: Use the molecular orbital energy-level diagram for O2 to show that the above Lewis structure corresponds to an excited state.arrow_forwardWhat is the molecular structure of the stable form of FNO2? (N is the central atom.)arrow_forwardThe standard enthalpy of formation for NO(g) is 90. kJ/mol. Use this and the values for the O=O and NN bond energies to estimate the bond strength in NO.arrow_forward
- Ethanol can be made by the reaction of ethylene and water: H2C=CH2(g) + H2O(g) CH3CH2OH(g) Use bond dissociation enthalpies to estimate the enthalpy change in this reaction. Compare the value obtained to the value calculated from enthalpies of formation.arrow_forwardThe standard enthalpy of formation for NO(g) is 90. kJ/mol. Use this and the values for the O 9 O and N N bond energies to estimate the bond strength in NO.arrow_forwardCalculate the wavelength of light required to break the bond between the two chlorine atoms in a chlorine molecule. The Cl-Cl bond energy is 243 kH mol^-1.arrow_forward
- Use bond energies to calculate the heat of reaction: =kjarrow_forwardThe reaction of a metal, M, with a halogen, X2, proceeds by an exothermic reaction as indicated by this equation: M(s) + X2(g) ⟶ MX2(s). For each of the following, indicate which option will make the reaction moreexothermic. Explain your answers.(a) a large radius vs. a small radius for M+2(b) a high ionization energy vs. a low ionization energy for M(c) an increasing bond energy for the halogen(d) a decreasing electron affinity for the halogen(e) an increasing size of the anion formed by the halogenarrow_forwardCalculate the mass of Li if... In a reaction between water and lithium, 82.14 J of energy was released. The molar enthalpy change with respect to lithium for this reaction is +59.00 kJ/mol Li.arrow_forward
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Types of bonds; Author: Edspira;https://www.youtube.com/watch?v=Jj0V01Arebk;License: Standard YouTube License, CC-BY