Which of these ligands can participate in linkage isomerism:(a) NO2-; (b) SO2; (c) NO3-? Explain with Lewis structures

Q: Which species are more likely to act as ligands? (a) Positivelycharged ions or negatively charged…

A: (a) Determine the species that act like as ligands among positively charged ions or negatively…

Q: Describe and differentiate strong field ligands and weak field ligands. Give two examples for each.

A: Given; We have to differentiate between weak field ligands and strong field ligands with two…

Q: Explain in words how potassium aluminum sulfate is formed via ligand exchange. Indicate clearly the…

A: A ligand exchange reaction is a reaction which involves the substitution of one or more ligands in a…

Q: chelating ligands?

A:

Q: Ligand A, B, and C form complexes with a metal cation resulting to  violet, indigo, and blue aqueous…

A:

Q: How many places on the ligand EDTA can simultaneously bind to a single metal atom?

A: EDTA is a hexadentate ligand because only one ligand donate the electrons from six donor sites to…

Q: Find a crystal structure for any metal complexes, define the oxidation state of metal, define the…

A:

Q: What is the distinction between a weak-field ligand and astrong-field ligand? Give an example of…

A:

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1. Linkage…

A: Linkage isomer :-       It is a isomer of coordination compound,  in which ambidentate ligands have…

Q: Dimethylglyoxime is unidentate or bidentate ligand ?

A: The chemical structure of Dimethylglyoxime is given as,

Q: If the ligands are either Cl", ethylenediamine or H₂O, which of the following is TRUE? O a. The…

A:

Q: The lobes of which d orbitals point directly betweenthe ligands in (a) octahedral geometry, (b)…

A: In Octahedral the ligands are pointing towards the X, Y & Z axis.  The 5 d orbitals are:  dxy…

Q: The octahedral structure is not the only possible sixcoordinate structure. Other possibilities…

A:

Q: (a) What is the crystal field splitting energy (Δ)?(b) How does it arise for an octahedral field of…

A: a) The crystal field splitting energy is the energy difference between the two sets of d orbitals…

Q: Why are multidentate ligands preferable to unidentate ligands for complexometric titrations?…

A: A unidentate ligand is that which donates only 1 electron pair (ex NH3). while multidentate ligand…

Q: When we consider the reaction of Ag+ ion (SCN) with its ligand, by showing the ion-ligand bond in…

A: In this reaction two types of bonds can occur because the ligand SCN is an ambidentate ligand.…

Q: When we consider the reaction of Fe3+ ion (SCN) with its ligand, by showing the ion-ligand bond in…

A: The reaction between Fe3+ and SCN- could be given as, Fe3+aq+SCN-aq→FeSCN2+ SCN- is a thiocyanate…

Q: Which class of ligands can give linkage isomers? a a. bidentate b b. tridentate C. ambidentate

A: C. ambidentate ligand is the correct option.

Q: For each of the following metals, write the electronic configurationof the atom and its 2+ ion: (a)…

A: Electronic Configuration is defined as the distribution of electrons of an atom or molecules in…

Q: Why d7,d8,d9 complexes prefer square planar with pi acceptor strong field ligands

A: Ligands are those species which forms a bond with metal by donating the electrons. Pi acceptor…

Q: By taking into account the following complexes: A) [Co(en):]³* B)[CoCl3Br3]+ a) Give the oxidation…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: What's the ligand field of metallo-porphyrins?

A: Porphyrins are chemicals used to make hemoglobin. The structure of porphyrin consists of four…

Q: The lobes of which d orbitals point directly between the ligands in  tetrahedral geometry?

A: The four ligands will be present at the surrounding of the central  atom. Thar arrangement is…

Q: Explain why, for the same metallic cation and the same ligands, the energy of the binding field is…

A: The question is based on the concept of coordination chemistry. We have to explain the low binding…

Q: he magnitude of delta octahedral (A.) epends on: he nature and charge of metal and whether the hetal…

A: The question is based on the concept of coordination compounds. We have to identify the factors on…

Q: "Ligand field theory provides a basis for explaining the chemical behaviour of octahedral transition…

A: Ligand field theory was put forward by Hund and Mulliken. According to this theory, all the atomic…

Q: Explain the following terms giving a suitable example in each case :(i) Ambident ligand(ii)…

A: Following terms are explained below-

Q: How many degenerate o, bonding orbitals (between the ligands and the metal p-orbitals) are there in…

A: Complexes are formed when ligands and metals form a coordinate bond between them. Ligands are the…

Q: How many bonds could each of the following chelating ligands form with a metal ion?

A: Given; structure of molecules

Q: EDTA ligand consider as

A: The word ligand means 'to bind'. Ligand is defined as a molecule that gives an electron pair to the…

Q: Write the hybridization and shape of the following complexes: (i) [CO(NH3)6]3+ (ii) [NiCl4]2-…

A: Hybridization involves the mixing up of of atomic orbitals into new hybrid orbitals with different…

Q: In a substitution reaction of an octahedral complex, the new ligands ends up in the same position as…

A: The arrangement of six ligands around the metal center at the vertices of octahedron results in the…

Q: (a) Using Werner’s definition of valence, which property isthe same as oxidation number, primary…

A: The coordination complexes can be defined as the complex compounds which have coordinate linkage…

Q: 3. Considering an octahedral complex for the d system,what are the effect of T-donor and t- acceptor…

A: Pi donar Ligands produce lesser splitting energy so high spin will be favored. Pi accepting lingands…

Q: Both H2O and ethylenediamine (en) have two nonbonding pairs of electrons. Whycan en act as a…

A: The number of donor atoms present in the ligand which can donate electrons to the central metal atom…

Q: In each the following generalized coordination complexes, M represents the central metal ion and L1,…

A: Two compounds that have the same molecular formula but the different structural representation of…

Q: Vhich of the following statement/s is/are true regarding coordination compounds? O A. The…

A: Coordination compounds have the tendency to retain their identity even after dissolving in the…

Q: Write the examples of Bidentate and Polydentate ligands? Also distinguish them.

A: Ligands can be described as an anions or cations or neutral molecules which is further classified as…

Q: What are the examples of molybdenum complexes? In each example state the physical and chemical…

A: The some of the examples of molybdenum complexes are needed to be provided along with their physical…

Q: a. Briefly describe the chelate effect b. Give the structure of a ligand that will exhibit the…

A: The metal complex carrying the ligand that is chelating (two or more donating sites) is named as…

Q: 1. Draw two possible resonance structures for DMSO, where S is the central atom. What kind of bond…

A: 1. DMSO means dimethyl sulfoxide contains two S-Me and one S=O with one l.p. on S atom. It's…

Q: f)) "Crystal field theory provides a basis for explaining the features of transition metal…

A: Two statements based on coordination complexes, which are to be explained.

Q: According to the theory of molecular orbitals, how are ligands classified and what effect do they…

A: On the basis of molecular orbital Theory , ligands are classified into :  1.) Only sigma donor 2.)…

Q: Giving a suitable example for each, explain the following: (i) Crystal field splitting (ii) Linkage…

A: With suitable examples, each of the following terms to be explained.

Q: Which of the following statement/s is/are true regarding coordination compounds? A. The interaction…

A:

Q: A, B, C, and D are four different ligands, draw all possible structures of geometric isomers for…

A: In square - planar complex- All the four ligand are different i.e A, B, C, and DThe complex is Pt…

Q: Which of the following ligands is bidentate?

A: Edta , diene and triene have more than 2 donor sites.

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.