Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 21, Problem 21.32E

Consider Figure 21.21. If the lower rightmost corner of the unit cell were selected arbitrarily as the origin, what would be the Miller indices of the indicated plane? Compare your answer to the solution of Example 21.7.

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Determine the Miller indices for the planes shown in the following unit cell:
Calcium carbonate crystals in the form of aragonite have orthorhombic unit cells of dimensions a = 574.1 pm, b = 796.8 pm, and c = 495.9 pm. Calculate the values of θ for the (100), (010), and (111) reflections using radiation of wavelength 83.42 pm.
Potassium nitrate crystals have orthorhombic unit cells of dimensions a = 542 pm, b = 917 pm, and c = 645 pm. Calculate the values of θ for the (100), (010), and (111) reflections using radiation of wavelength 154 pm.

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