Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Textbook Question
Chapter 21, Problem 21.48E

Which solid phase (that is, which allotrope) of carbon is more stable, graphite or diamond? (You should consult some of the tables in the thermodynamics section of this text.). Both solid phases exist under normal conditions of pressure and temperature. Explain why this is so, given that one solid phase is more thermodynamically stable than the other. Do their unit cells provide any suggestion for their relative stabilities?

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