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Draw a structural formula for each compound. (a) 1-Bromo-2-chloro-4-ethylbenzene (b) m -Nitrocumene (c) 4-Chloro-1,2-dimethylbenzene (d) 3,5-Dinitrotoluene (e) 2,4,6-Trinitrotoluene (f) (2 S, 4 R )-4-Phenyl-2-pentanol (g) p -Cresol (h) Pentachlorophenol (i) 1-Phenylcyclopropanol (j) Triphenylmethane (k) Phenylethylene (styrene) (l) Benzyl bromide (m) 1-Phenyl-1-butyne (n) ( E )-3-Phenyl-2-propen-1-ol

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Organic Chemistry

8th Edition
William H. Brown + 3 others
Publisher: Cengage Learning
ISBN: 9781305580350

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Chapter
Section
BuyFindarrow_forward

Organic Chemistry

8th Edition
William H. Brown + 3 others
Publisher: Cengage Learning
ISBN: 9781305580350
Chapter 21, Problem 21.9P
Textbook Problem
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Draw a structural formula for each compound.

  1. (a) 1-Bromo-2-chloro-4-ethylbenzene
  2. (b) m-Nitrocumene
  3. (c) 4-Chloro-1,2-dimethylbenzene
  4. (d) 3,5-Dinitrotoluene
  5. (e) 2,4,6-Trinitrotoluene
  6. (f) (2S,4R)-4-Phenyl-2-pentanol
  7. (g) p-Cresol
  8. (h) Pentachlorophenol
  9. (i) 1-Phenylcyclopropanol
  10. (j) Triphenylmethane
  11. (k) Phenylethylene (styrene)
  12. (l) Benzyl bromide
  13. (m) 1-Phenyl-1-butyne
  14. (n) (E)-3-Phenyl-2-propen-1-ol

(a)

Interpretation Introduction

Interpretation:

The structural formula for 1-Bromo-2-chloro-4-ethylbenzene has to be drawn.

Explanation of Solution

The structural formula for 1-Bromo-2-chloro-4-ethylbenzene is given below.

The naming of the compound can be done with re...

(b)

Interpretation Introduction

Interpretation:

The structural formula for m-Nitrocumene has to be drawn.

(c)

Interpretation Introduction

Interpretation:

The structural formula for 4-Chloro-1,2-dimethyl benzene has to be drawn.

(d)

Interpretation Introduction

Interpretation:

The structural formula for 3,5-Dinitrotoluene has to be drawn.

(e)

Interpretation Introduction

Interpretation:

The structural formula for 2,4,6-Trinitrotoluene has to be drawn.

(f)

Interpretation Introduction

Interpretation:

The structural formula for (2S,4R)-4-Phenyl-2-pentanol has to be drawn.

(g)

Interpretation Introduction

Interpretation:

The structural formula for p-Cresol has to be drawn.

(h)

Interpretation Introduction

Interpretation:

The structural formula for pentachlorophenol has to be drawn.

(i)

Interpretation Introduction

Interpretation:

The structural formula for 1-Phenylcyclopropanol has to be drawn.

(j)

Interpretation Introduction

Interpretation:

The structural formula for Triphenylmethane has to be drawn.

(k)

Interpretation Introduction

Interpretation:

The structural formula for Phenylethylene (styrene) has to be drawn.

(l)

Interpretation Introduction

Interpretation:

The structural formula for benzyl bromide has to be drawn.

Concept Introduction:

Structural formula gives information about how the atoms are arranged in a molecule.

(m)

Interpretation Introduction

Interpretation:

The structural formula for 1-Phenyl-1-butyne has to be drawn.

(n)

Interpretation Introduction

Interpretation:

The structural formula for (E)-3-Phenyl-2-propen-1-ol has to be drawn.

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Chapter 21 Solutions

Organic Chemistry
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Ch. 21 - Name the following compounds and ions.Ch. 21 - Draw a structural formula for each compound. (a)...Ch. 21 - Draw a structural formula for each compound. (a)...Ch. 21 - Molecules of 6,6-dinitrobiphenyl-2,2-dicarboxylic...Ch. 21 - Following each name is the number of Kekul...Ch. 21 - Each molecule in this problem can be drawn as a...Ch. 21 - Following are structural formulas for furan and...Ch. 21 - State the number of 2p orbital electrons in each...Ch. 21 - Which of the molecules and ions given in Problem...Ch. 21 - Construct MO energy diagrams for the cyclopropenyl...Ch. 21 - Naphthalene and azulene are constitutional isomers...Ch. 21 - Compound A (C9H12) shows prominent peaks in its...Ch. 21 - Compound C shows a molecular ion at m/z 148 and...Ch. 21 - Following are IR and 1H-NMR spectra of compound D....Ch. 21 - Compound E (C8H10O2) is a neutral solid. Its mass...Ch. 21 - Following are 1H-NMR and 13C-NMR spectral data for...Ch. 21 - Following are 1H-NMR and 13C-NMR spectral data for...Ch. 21 - Compound H (C8H6O3) gives a precipitate when...Ch. 21 - Compound I (C11H14O2) is insoluble in water,...Ch. 21 - Propose a structural formula for compound J...Ch. 21 - Propose a structural formula for the analgesic...Ch. 21 - Compound K, C10H12O2, is insoluble in water, 10%...Ch. 21 - Propose a structural formula for each compound...Ch. 21 - Given here are 1H-NMR and 13C-NMR spectral data...Ch. 21 - Account for the fact that p-nitrophenol (Ka 7.0 ...Ch. 21 - Account for the fact that water-insoluble...Ch. 21 - Match each compound with its appropriate pKa...Ch. 21 - Arrange the molecules and ions in each set in...Ch. 21 - Explain the trends in the acidity of phenol and...Ch. 21 - Suppose you want to determine the inductive...Ch. 21 - From each pair, select the stronger base.Ch. 21 - Describe a chemical procedure to separate a...Ch. 21 - The compound 2-hydroxypyridine, a derivative of...Ch. 21 - Write a balanced equation for the oxidation of...Ch. 21 - Each of the following reactions occurs by a...Ch. 21 - Following is an equation for iodination of...Ch. 21 - Although most alkanes react with chlorine by a...Ch. 21 - Following is an equation for hydroperoxidation of...Ch. 21 - Para-substituted benzyl halides undergo reaction...Ch. 21 - When warmed in dilute sulfuric acid,...Ch. 21 - In the chemical synthesis of DNA and RNA, hydroxyl...Ch. 21 - Use the reaction roadmaps you made for Problem...Ch. 21 - Write the products of the following sequences of...Ch. 21 - Using ethylbenzene as the only aromatic starting...Ch. 21 - Show how to convert 1-phenylpropane into the...Ch. 21 - Carbinoxamine is a histamine antagonist,...Ch. 21 - Cromolyn sodium, developed in the 1960s, has been...Ch. 21 - The following stereospecific synthesis is part of...Ch. 21 - Following is an outline of one of the first...Ch. 21 - Following is a synthesis for the antiarrhythmic...Ch. 21 - A finding that opened a route to -blockers was the...Ch. 21 - Side effects of propranolol (Problem 21.58)...Ch. 21 - In certain clinical situations, there is need for...Ch. 21 - Following is an outline of a synthesis of the...Ch. 21 - Following is a synthesis for albuterol...Ch. 21 - Estrogens are female sex hormones, the most potent...Ch. 21 - Following is a synthesis for toremifene, a...

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