Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 21, Problem 32E
When an aqueous solution of KCN is added to a solution containing Ni2+ ions, a precipitate forms, which redissolves on addition of more KCN solution. Write reactions describing what happens in this solution. [Hint: CN− is a Brønsted-Lowry base (Kb ≈ 10−5) and a Lewis base.]
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Chapter 21 Solutions
Chemistry
Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Prob. 5RQCh. 21 - Prob. 6RQCh. 21 - Prob. 7RQCh. 21 - Prob. 8RQCh. 21 - Prob. 9RQCh. 21 - Prob. 10RQ
Ch. 21 - Prob. 1ALQCh. 21 - Prob. 2ALQCh. 21 - Prob. 3ALQCh. 21 - Prob. 4ALQCh. 21 - Prob. 5QCh. 21 - Four different octahedral chromium coordination...Ch. 21 - Prob. 7QCh. 21 - Prob. 8QCh. 21 - Prob. 9QCh. 21 - Prob. 10QCh. 21 - Prob. 11QCh. 21 - Prob. 13QCh. 21 - Prob. 14QCh. 21 - Which of the following ligands are capable of...Ch. 21 - Prob. 16QCh. 21 - Prob. 17QCh. 21 - What is the maximum number of unpaired d electrons...Ch. 21 - Prob. 19QCh. 21 - Prob. 20QCh. 21 - Prob. 21QCh. 21 - Prob. 22QCh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - When an aqueous solution of KCN is added to a...Ch. 21 - Consider aqueous solutions of the following...Ch. 21 - A coordination compound of cobalt(III) contains...Ch. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Give formulas for the following complex ions. a....Ch. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Amino acids can act as ligands toward transition...Ch. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Prob. 54ECh. 21 - The CrF64 ion is known to have four unpaired...Ch. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - The wavelength of absorbed electromagnetic...Ch. 21 - The complex ion NiCL42 has two unpaired electrons,...Ch. 21 - How many unpaired electrons are present in the...Ch. 21 - The complex ion PdCl42is diamagnetic. Propose a...Ch. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Silver is sometimes found in nature as large...Ch. 21 - Prob. 72ECh. 21 - Prob. 73AECh. 21 - Prob. 74AECh. 21 - Prob. 75AECh. 21 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 21 - Prob. 77AECh. 21 - Prob. 78AECh. 21 - Prob. 79AECh. 21 - Prob. 80AECh. 21 - Prob. 81AECh. 21 - Name the following coordination compounds. a....Ch. 21 - Prob. 83AECh. 21 - Prob. 84AECh. 21 - Prob. 85AECh. 21 - Prob. 86AECh. 21 - Carbon monoxide is toxic because it binds more...Ch. 21 - Prob. 88AECh. 21 - Prob. 89CWPCh. 21 - Which of the following molecules exhibit(s)...Ch. 21 - Prob. 91CWPCh. 21 - The following table indicates the number of...Ch. 21 - Prob. 93CWPCh. 21 - Which of the following statement(s) is( are) true?...Ch. 21 - Consider the following complex ion, where A and B...Ch. 21 - Consider the pseudo-octahedral complex ion of...Ch. 21 - Prob. 97CPCh. 21 - Prob. 98CPCh. 21 - Chelating ligands often form more stable complex...Ch. 21 - Prob. 100CPCh. 21 - Prob. 101CPCh. 21 - Prob. 102CPCh. 21 - Sketch and explain the most likely crystal field...Ch. 21 - Ethylenediaminetetraacetate (EDTA4 ) is used as a...Ch. 21 - Prob. 105CPCh. 21 - The ferrate ion, FeO42, is such a powerful...Ch. 21 - Ammonia and potassium iodide solutions are added...Ch. 21 - a. In the absorption spectrum of the complex ion...Ch. 21 - There are three salts that contain complex ions of...
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- Write the state of hybridisation, the shape and the magnetic behaviour of the following complex entities: (i) [Cr(NH3)4Cl2] Cl (ii) [Co(en)3] Cl3 (iii) K2[Ni(CN)4]arrow_forwardWrite the formula for each of the following compounds, being sure to use brackets to indicate the coordination sphere: (a) dichlorobis(ethylenediamine)platinum(IV) bromide (b) potassium diaquatetrabromovanadate(III)arrow_forwardWrite the state of hybridization, the shape and the magnetic behaviour of the following complex entities :(t) [Cr(NH3)4Cl2]Cl(ii) [Co(en)3]Cl3(iii) K2[Ni(CN)4]arrow_forward
- Is the interaction between an ammonia ligand and a metal cation a Lewis acid-base interaction?arrow_forwardOne of the following nitrogen compounds or ions is not capable of serving as a ligand: NH4+, NH3, NH2. Identify this species, and explain your answer.arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forward
- What structural feature is used to determine whether a compound can exist as optical isomers?arrow_forwardHow would you account for the following?(i) Many of the transition elements are known to form interstitial compounds.(ii) The metallic radii of the third (5d) series of transition metals are virtually the same as those of the corresponding group members of the second (4d) series.(iii) Lanthanoids form primarily +3 ions, while the actinoids usually have higher oxidation states in their compounds, +4 or even +6 being typical.arrow_forwardConsider the insoluble compound cobalt(II) carbonate , CoCO3 . The cobalt(II) ion also forms a complex with ammonia . Write a balanced net ionic equation to show why the solubility of CoCO3 (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction.For Co(NH3)62+ , Kf = 7.7×104 . Be sure to specify states such as (aq) or (s).arrow_forward
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