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ChemistryChemistryThe Co(NH 3 ) 6 3+ ion is diamagnetic, but Fe(H 2 O) 6 2+ is paramagnetic. Explain.

The Co(NH 3 ) 6 3+ ion is diamagnetic, but Fe(H 2 O) 6 2+ is paramagnetic. Explain.

BuyFind

Chemistry

9th Edition
Steven S. Zumdahl
Publisher: Cengage Learning
ISBN: 9781133611097
BuyFind

Chemistry

9th Edition
Steven S. Zumdahl
Publisher: Cengage Learning
ISBN: 9781133611097

Solutions

Chapter
Section
Problem 1RQ
Problem 2RQ
Problem 3RQ
Problem 4RQ
Problem 5RQ
Problem 6RQ
Problem 7RQ
Problem 8RQ
Problem 9RQ
Problem 10RQ
Problem 1ALQ
Problem 2ALQ
Problem 3ALQ
Problem 4ALQ
Problem 5Q
Problem 6Q
Problem 7Q
Problem 8Q
Problem 9Q
Problem 10Q
Problem 11Q
Problem 12Q
Problem 13Q
Problem 14Q
Problem 15Q
Problem 16Q
Problem 17Q
Problem 18Q
Problem 19Q
Problem 20Q
Problem 21E
Problem 22E
Problem 23E
Problem 24E
Problem 25E
Problem 26E
Problem 27E
Problem 28E
Problem 29E
Problem 30E
Problem 31E
Problem 32E
Problem 33E
Problem 34E
Problem 35E
Problem 36E
Problem 37E
Problem 38E
Problem 39E
Problem 40E
Problem 41E
Problem 42E
Problem 43E
Problem 44E
Problem 45E
Problem 46E
Problem 47E
Problem 48E
Problem 49E
Problem 50E
Problem 51E
Problem 52E
Problem 53E
Problem 54E
Problem 55E
Problem 56E
Problem 57E
Problem 58E
Problem 59E
Problem 60E
Problem 61E
Problem 62E
Problem 63E
Problem 64E
Problem 65E
Problem 66E
Problem 67E
Problem 68E
Problem 69E
Problem 70E
Problem 71AE
Problem 72AE
Problem 73AE
Problem 74AE
Problem 75AE
Problem 76AE
Problem 77AE
Problem 78AE
Problem 79AE
Problem 80AE
Problem 81AE
Problem 82AE
Problem 83CWP
Problem 84CWP
Problem 85CWP
Problem 86CWP
Problem 87CWP
Problem 88CWP
Problem 89CP
Problem 90CP
Problem 91CP
Problem 92CP
Problem 93CP
Problem 94CP
Problem 95CP
Problem 96CP
Problem 97CP
Problem 98IP
Problem 99IP
Problem 100IP
Problem 101MP
Chapter 21, Problem 54E
Textbook Problem

The Co(NH3)63+ ion is diamagnetic, but Fe(H2O)62+ is paramagnetic. Explain.

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Chapter 21,
Problem 53E
Chapter 21,
Problem 55E

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Chapter 21 Solutions

Chemistry
Ch. 21 - What two first-row transition metals have...Ch. 21 - Define each of the following terms: a....Ch. 21 - When a metal ion has a coordination number of 2,...Ch. 21 - What is wrong with the following formula-name...Ch. 21 - Define each of the following and give examples of...Ch. 21 - What is the major focus of the crystal field...Ch. 21 - The crystal field model predicts magnetic...Ch. 21 - Why do tetrahedral complex ions have a different...Ch. 21 - Review Table 20-18, which lists some important...Ch. 21 - Define and give an example of each of the...
Ch. 21 - You isolate a compound with the formula PtCl4 ...Ch. 21 - Both Ni(NH3)42+ and Ni(SCN)42 have four ligands....Ch. 21 - Which is more likely to be paramagnetic, Fe(CN)64...Ch. 21 - A metal ion in a high-spin octahedral complex has...Ch. 21 - What is the lanthanide contraction? How does the...Ch. 21 - Four different octahedral chromium coordination...Ch. 21 - Figure 20-17 shows that the cis isomer of...Ch. 21 - A certain first-row transition metal ion forms...Ch. 21 - Oxalic acid is often used to remove rust stains....Ch. 21 - For the following crystal field diagrams, label...Ch. 21 - CoCl42 forms a tetrahedral complex ion and...Ch. 21 - The following statements discuss some coordination...Ch. 21 - When concentrated hydrochloric acid is added to a...Ch. 21 - Tetrahedral complexes of Co2+ are quite common....Ch. 21 - Which of the following ligands are capable of...Ch. 21 - Compounds of copper(II) are generally colored, but...Ch. 21 - Compounds of Sc3+ are not colored, but those of...Ch. 21 - Almost all metals in nature are found as ionic...Ch. 21 - What causes high-altitude sickness, and what is...Ch. 21 - Why are CN and CO toxic to humans?Ch. 21 - Write electron configurations for the following...Ch. 21 - Write electron configurations for the following...Ch. 21 - Write electron configurations for each of the...Ch. 21 - Write electron configurations for each of the...Ch. 21 - What is the electron configuration for the...Ch. 21 - What is the electron configuration for the...Ch. 21 - Molybdenum is obtained as a by-product of copper...Ch. 21 - Titanium dioxide, the most widely used white...Ch. 21 - When 6 M ammonia is added gradually to aqueous...Ch. 21 - When an aqueous solution of KCN is added to a...Ch. 21 - Consider aqueous solutions of the following...Ch. 21 - A coordination compound of cobalt(III) contains...Ch. 21 - Name the following complex ions: a. b. c.Ch. 21 - Name the following complex ions. a. Ru(NH3)5Cl2+...Ch. 21 - Name the following coordination compounds. a....Ch. 21 - Name the following coordination compounds. a....Ch. 21 - Give formulas for the following. a. potassium...Ch. 21 - Give formulas for the following complex ions. a....Ch. 21 - Draw geometrical isomers of each of the following...Ch. 21 - Draw structures of each of the following. a....Ch. 21 - The carbonate ion (CO32) can act as either a...Ch. 21 - Amino acids can act as ligands toward transition...Ch. 21 - How many bonds could each of the following...Ch. 21 - BAL is a chelating agent used in treating heavy...Ch. 21 - Draw all geometrical and linkage isomers of...Ch. 21 - Draw all geometrical and linkage isomers of square...Ch. 21 - Acetylacetone, abbreviated acacH, is a bidentate...Ch. 21 - Draw all geometrical isomers of Pt(CN)2Br2(H2O)2....Ch. 21 - Match the crystal field diagrams given below with...Ch. 21 - Match the crystal field diagrams given below with...Ch. 21 - Draw the d-orbital splitting diagrams for the...Ch. 21 - Draw the d-orbital splitting diagrams for the...Ch. 21 - The CrF64 ion is known to have four unpaired...Ch. 21 - The Co(NH3)63+ ion is diamagnetic, but Fe(H2O)62+...Ch. 21 - How many unpaired electrons are in the following...Ch. 21 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 21 - Rank the following complex ions in order of...Ch. 21 - The complex ion Cu(H2O)62+ has an absorption...Ch. 21 - The following test tubes each contain a different...Ch. 21 - Consider the complex ions Co(NH3)63+, Co(CN)63,...Ch. 21 - The wavelength of absorbed electromagnetic...Ch. 21 - The complex ion NiCL42 has two unpaired electrons,...Ch. 21 - How many unpaired electrons are present in the...Ch. 21 - The complex ion PdCl42is diamagnetic. Propose a...Ch. 21 - A blast furnace is used to reduce iron oxides to...Ch. 21 - Use the data in Appendix 4 for the following. a....Ch. 21 - Iron is present in the earths crust in many types...Ch. 21 - What roles do kinetics and thermodynamics play in...Ch. 21 - Silver is sometimes found in nature as large...Ch. 21 - One of the classic methods for the determination...Ch. 21 - Acetylacetone (see Exercise 43, part a),...Ch. 21 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 21 - Use standard reduction potentials to calculate ,...Ch. 21 - Until the discoveries of Alfred Werner, it was...Ch. 21 - Draw all the geometrical isomers of...Ch. 21 - A compound related to acetylacetone is...Ch. 21 - Would it be better to use octahedral Ni2+...Ch. 21 - Name the following coordination compounds. a....Ch. 21 - give formulas for the following. a....Ch. 21 - The complex ion Ru(phen)32+ has been used as a...Ch. 21 - Carbon monoxide is toxic because it binds more...Ch. 21 - For the process Co(NH3)5Cl2++ClCO(NH3)4Cl2++NH3...Ch. 21 - In which of the following is(are) the electron...Ch. 21 - Which of the following molecules exhibit(s)...Ch. 21 - Which of the following ions is( are) expected to...Ch. 21 - The following table indicates the number of...Ch. 21 - Which of the following crystal field diagram(s)...Ch. 21 - Which of the following statement(s) is( are) true?...Ch. 21 - Consider the following complex ion, where A and B...Ch. 21 - Consider the pseudo-octahedral complex ion of...Ch. 21 - Consider the following data: where en =...Ch. 21 - Henry Taube, 1983 Nobel Prize winner in chemistry,...Ch. 21 - Chelating ligands often form more stable complex...Ch. 21 - Qualitatively draw the crystal field splitting of...Ch. 21 - Qualitatively draw the crystal field splitting for...Ch. 21 - Sketch a d-orbital energy diagram for the...Ch. 21 - Sketch and explain the most likely crystal field...Ch. 21 - The ferrate ion, FeO42, is such a powerful...Ch. 21 - Ammonia and potassium iodide solutions are added...Ch. 21 - a. In the absorption spectrum of the complex ion...Ch. 21 - There are three salts that contain complex ions of...

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