CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE
CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE
7th Edition
ISBN: 9781119457282
Author: JESPERSEN
Publisher: WILEY
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Chapter 21, Problem 60RQ
Interpretation Introduction

Interpretation:

The IUPAC names of the given coordination complexes are to be determined

Concept Information:

Complex ions are the ions that are formed when a metal atom is at the center and other non-metallic molecules or ions surround it.

Ligands are the molecules or ions that are bonded to a metal ion with a coordinate covalent bond.

Coordination complexes are the complexes formed through coordinate covalent bonds between ligands and metals.

Usually, in IUPAC nomenclature, the name of a neutral ligand does not change when naming a coordination complex, but water and ammonia are exceptions and their names change to aqua and ammine, respectively.

Anionic ligands change their name when naming a coordination complex, based on the suffix in their names. The ligands ending with –ide change to the suffix –o, those ending with –ite change to the suffix –ito, and the ligands ending with –ate change to the suffix –ato.

For naming a metallic ion, if the complex is anionic, then the name of the central metal ion in the coordinate complex ends with the suffix –ate and for neutral and cationic complexes, no changes are made to the name. The oxidation state of the metal is indicated by the roman numeral within the parenthesis following, without any space, the name of the metal.

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Chapter 21 Solutions

CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE

Ch. 21 - Prob. 11PECh. 21 - Prob. 12PECh. 21 - The iron metal center in hemoglobin sits in an...Ch. 21 - Prob. 1RQCh. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Complex Ions Use Lewis structures to diagram the...Ch. 21 - Complex Ions 21.6 What must be true about the...Ch. 21 - Prob. 7RQCh. 21 - Complex Ions What is a chelate? Use Lewis...Ch. 21 - Prob. 9RQCh. 21 - Complex Ions Explain how a sale of EDTA4- can...Ch. 21 - Prob. 11RQCh. 21 - Complex Ions 21.12 The cobalt(III) ion, , forms a...Ch. 21 - Prob. 13RQCh. 21 - Complex Ions What is the chelate effect? How does...Ch. 21 - Prob. 15RQCh. 21 - Prob. 16RQCh. 21 - Prob. 17RQCh. 21 - Prob. 18RQCh. 21 - Prob. 19RQCh. 21 - Prob. 20RQCh. 21 - Prob. 21RQCh. 21 - Prob. 22RQCh. 21 - Prob. 23RQCh. 21 - Prob. 24RQCh. 21 - Coordination Number and Structure Draw (a) a...Ch. 21 - Prob. 26RQCh. 21 - Prob. 27RQCh. 21 - Prob. 28RQCh. 21 - Prob. 29RQCh. 21 - Prob. 30RQCh. 21 - Prob. 31RQCh. 21 - Bonding in Metal Complexes 21.32 On appropriate...Ch. 21 - Prob. 33RQCh. 21 - Prob. 34RQCh. 21 - Prob. 35RQCh. 21 - Prob. 36RQCh. 21 - Prob. 37RQCh. 21 - Prob. 38RQCh. 21 - Prob. 39RQCh. 21 - Prob. 40RQCh. 21 - Prob. 41RQCh. 21 - Prob. 42RQCh. 21 - Bonding in Metal Complexes What factors about the...Ch. 21 - Prob. 44RQCh. 21 - Bonding in Metal Complexes The complex [...Ch. 21 - Bonding in Metal Complexes 21.46 Consider the...Ch. 21 - Prob. 47RQCh. 21 - Prob. 48RQCh. 21 - Prob. 49RQCh. 21 - Prob. 50RQCh. 21 - Prob. 51RQCh. 21 - Biological Functions of Metals Ions 21.52 List...Ch. 21 - Prob. 53RQCh. 21 - Prob. 54RQCh. 21 - Prob. 55RQCh. 21 - Write the formula, including its correct charge,...Ch. 21 - Metal Complex Nomenclature How would the following...Ch. 21 - Metal Complex Nomenclature 21.58 How would the...Ch. 21 - Give IUPAC names for each of the following:...Ch. 21 - Prob. 60RQCh. 21 - Prob. 61RQCh. 21 - Prob. 62RQCh. 21 - Coordination Number and Structure 21.63 What is...Ch. 21 - Prob. 64RQCh. 21 - Draw a reasonable structure for (a) [ Zn(NH3)4 ]2+...Ch. 21 - Prob. 66RQCh. 21 - Prob. 67RQCh. 21 - 21.68 The following compound is called...Ch. 21 - Prob. 69RQCh. 21 - Isomers of Metal Complexes *21.70 Below is a...Ch. 21 - Prob. 71RQCh. 21 - Prob. 72RQCh. 21 - Prob. 73RQCh. 21 - Prob. 74RQCh. 21 - Bonding in Metal Complexes *21.75 In which complex...Ch. 21 - Prob. 76RQCh. 21 - Prob. 77RQCh. 21 - Prob. 78RQCh. 21 - Prob. 79RQCh. 21 - Prob. 80RQCh. 21 - Referring to the two ligands, A and B, described...Ch. 21 - Referring to the complexes in Problems 21.80 and...Ch. 21 - Prob. 83RQCh. 21 - Prob. 84RQCh. 21 - *21.85 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.86 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.87 ions can be either four coordinate or six...Ch. 21 - Prob. 88RQCh. 21 - Most of the first row transition metals form 2+...Ch. 21 - *21.90 Is the complex chiral? Illustrate your...Ch. 21 - The complex [PtCl2(NH3)2] can be obtained as two...Ch. 21 - Prob. 92RQCh. 21 - Prob. 93RQCh. 21 - The compound Cr2(NH3)3(H2O)3Cl is a neutral salt...Ch. 21 - Prob. 95RQCh. 21 - Prob. 96RQCh. 21 - Prob. 97RQCh. 21 - Prob. 98RQCh. 21 - Prob. 99RQCh. 21 - Platinum(IV) makes compounds with coordination...Ch. 21 - Prob. 101RQCh. 21 - Prob. 102RQ
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