Predict the products of the following nucleophilic acyl substitution reactions:
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Organic Chemistry
9th Edition
John E. McMurry
Publisher: Cengage Learning
ISBN: 9781305080485
BuyFindlaunch
Organic Chemistry
9th Edition
John E. McMurry
Publisher: Cengage Learning
ISBN: 9781305080485
Solutions
Chapter
Section
Chapter 21.2, Problem 5P
Textbook Problem
Predict the products of the following nucleophilic acyl substitution reactions:
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Organic Chemistry
Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Show the mechanism of the following nucleophilic...Ch. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - The following structure represents a tetrahedral...Ch. 21.3 - How might you prepare the following esters from...Ch. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Which method would you choose if you wanted to...
Ch. 21.4 - Write the mechanism of the reaction just shown...Ch. 21.4 - How could you prepare the following amides using...Ch. 21.4 - How could you prepare the following ketones by...Ch. 21.5 - Write the mechanism of the reaction between...Ch. 21.5 - What product would you expect from reaction of one...Ch. 21.6 - Why is the saponification of an ester...Ch. 21.6 - What product would you expect from the reaction of...Ch. 21.6 - Show the products you would obtain by reduction of...Ch. 21.6 - What ester and what Grignard reagent might you...Ch. 21.7 - How would you convert N-ethylbenzamide to each of...Ch. 21.7 - How would you use the reaction of an amide with...Ch. 21.8 - Write the mechanism of the reaction shown in...Ch. 21.9 - Draw structures of the step-growth polymers you...Ch. 21.9 - Kevlar, a nylon polymer prepared by reaction of...Ch. 21.10 - Prob. 25PCh. 21.10 - Prob. 26PCh. 21.SE - Name the following compounds:Ch. 21.SE - How would you prepare the following compounds...Ch. 21.SE - The following structure represents a tetrahedral...Ch. 21.SE - Electrostatic potential maps of a typical amide...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the complete...Ch. 21.SE - Pivalic mixed anhydrides are often used to form...Ch. 21.SE - When 4-dimethylaminopyridine (DMAP) is added in...Ch. 21.SE - Fats are biosynthesized from glycerol 3-phosphate...Ch. 21.SE - Treatment of an -amino acid with DCC yields a...Ch. 21.SE - Succinic anhydride yields the cyclic imide...Ch. 21.SE - The hydrolysis of a biological thioester to the...Ch. 21.SE - One step in the gluconeogenesis pathway for the...Ch. 21.SE - Bacteria typically develop a resistance to...Ch. 21.SE - The following reaction, called the benzilic acid...Ch. 21.SE - In the iodoform reaction, a triiodomethyl ketone...Ch. 21.SE - Give IUPAC names for the following compounds:Ch. 21.SE - Draw structures corresponding to the following...Ch. 21.SE - Draw and name compounds that meet the following...Ch. 21.SE - Predict the product, if any, of reaction between...Ch. 21.SE - Answer Problem 21-48 for reaction of the listed...Ch. 21.SE - Answer Problem 21-48 for reaction of the listed...Ch. 21.SE - What product would you expect to obtain from...Ch. 21.SE - How might you prepare the following compounds from...Ch. 21.SE - Predict the product(s) of the following reactions:Ch. 21.SE - The following reactivity order has been found for...Ch. 21.SE - Explain the observation that attempted Fischer...Ch. 21.SE - Outline methods for the preparation of...Ch. 21.SE - Treatment of 5-aminopentanoic acid with DCC...Ch. 21.SE - When ethyl benzoate is heated in methanol...Ch. 21.SE - tert-Butoxycarbonyl azide, a reagent used in...Ch. 21.SE - The step-growth polymer nylon 6 is prepared from...Ch. 21.SE - Qiana, a polyamide fiber with a silky texture, has...Ch. 21.SE - What is the structure of the polymer produced by...Ch. 21.SE - Polyimides with the structure shown are used as...Ch. 21.SE - How would you distinguish spectroscopically...Ch. 21.SE - Propose a structure for a compound, C4H7ClO2, that...Ch. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - The following reactivity order has been found for...Ch. 21.SE - When a carboxylic acid is dissolved in...Ch. 21.SE - We said in Section 21-6 that mechanistic studies...Ch. 21.SE - Treatment of a carboxylic acid with...Ch. 21.SE - Butacetin is an analgesic (pain-killing) agent...Ch. 21.SE - Phenyl 4-aminosalicylate is a drug used in the...Ch. 21.SE - N,N-Diethyl-m-toluamide (DEET) is the active...Ch. 21.SE - Tranexamic acid, a drug useful against blood...Ch. 21.SE - One frequently used method for preparing methyl...Ch. 21.SE - Draw the structure of the polymer you would expect...Ch. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - Propose structures for compounds with the...Ch. 21.SE - Propose a structure for the compound with the...Ch. 21.SE - Draw the structure of the compound that produced...Ch. 21.SE - When an amide is formed from an acid chloride or...Ch. 21.SE - Epoxy adhesives are prepared in two steps. SN2...
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