Chapter 22, Problem 22.73AP

A 1.00-mol sample of an ideal monatomic gas is taken through the cycle shown in Figure P21.37. The process A → B is a reversible isothermal expansion. Calculate (a) the net work done by the gas, (b) the energy added to the gas by heat, (c) the energy exhausted from the gas by heat, and (d) the efficiency of the cycle. (e) Explain how the efficiency compares with that of a Carnot engine operating between the same temperature extremes.

Figure P21.37

To determine

The net work done by the gas.

Answer to Problem 22.73AP

The net work done by the gas is $4.10\times {10}^3\text{J}$.

Explanation of Solution

The pressure and volume at A are $5\text{atm}$ and $10\text{L}$ respectively, the pressure and volume at B are $1\text{atm}$ and $50\text{L}$ and the pressure and volume at C are $1\text{atm}$ and $10\text{L}$.

Write the formula for the net work done by the gas at $AB$

  $W_{\text{AB}}=-P_{\text{A}}{V}_{\text{A}}\ln \left(\frac{V_{\text{B}}}{V_{\text{A}}}\right)$

Here, $P_{\text{A}}$ is the pressure at $A$, $V_{\text{A}}$ is the volume at $A$ and $V_{\text{B}}$ is the volume at $B$.

Substitute $5\text{atm}$ for $P_{\text{A}}$, $10\text{L}$ for $V_{\text{A}}$ and $50\text{L}$ for $V_{\text{B}}$ in above equation to find $W_{\text{AB}}$.

  $\begin{array}{c}{W}_{\text{AB}}=-5\text{atm}\cdot \left(\frac{1.013\times {10}^5\text{Pa}}{1\text{atm}}\right)\cdot 10\text{L}\cdot \left(\frac{{10}^{-3}{\text{m}}^3}{1\text{L}}\right)\ln \left(\frac{50}{10}\right)\\ =-8.15\times {10}^3\text{J}\end{array}$

Write the formula for the net work done by the gas at $BC$

  $\begin{array}{c}{W}_{\text{BC}}=-P_{\text{B}}\Delta V\\ =-P_{\text{B}}\left(V_C-V_{\text{B}}\right)\end{array}$

Here, $P_{\text{B}}$ is the pressure at B, $V_{\text{C}}$ is the volume at A and $V_{\text{B}}$ is the volume at B.

Substitute $1\text{atm}$ for $P_{\text{B}}$ , $10\text{L}$ for $V_{\text{C}}$ and $50\text{L}$ for $V_{\text{B}}$ in above equation to find $W_{\text{BC}}$.

  $\begin{array}{c}{W}_{\text{BC}}=-1\text{atm}\cdot \left(\frac{1.013\times {10}^5\text{Pa}}{1\text{atm}}\right)\cdot \left(10-50\right)\text{L}\cdot \left(\frac{{10}^{-3}{\text{m}}^3}{1\text{L}}\right)\\ =4.05\times {10}^3\text{J}\end{array}$

Write the formula for the net work done by the gas at $CA$

    $W_{\text{CA}}=0\text{J}$

As the change in the volume during processes $CA$ is zero, the work done is zero.

Write the formula for the total work done by the gas

    $W_{\text{T}}=W_{\text{AB}}+W_{\text{BC}}+W_{\text{CA}}$

Conclusion:

Substitute $-8.15\times {10}^3\text{J}$ for $W_{\text{AB}}$, $4.05\times {10}^3\text{J}$ for $W_{\text{BC}}$ and $0\text{J}$ for $W_{\text{CA}}$ in above equation to find $W_{\text{T}}$.

    $\begin{array}{c}{W}_{\text{T}}=-\left(-8.15\times {10}^3\text{J}+4.05\times {10}^3\text{J}+0\text{J}\right)\\ =4.10\times {10}^3\text{J}\end{array}$

Therefore, the total work done is $4.10\times {10}^3\text{J}$.

To determine

The energy added to the gas by heat.

Answer to Problem 22.73AP

The energy added to the gas by heat is $1.42\times {10}^4\text{J}$.

Explanation of Solution

The pressure and volume at $A$ are $5\text{atm}$ and $10\text{L}$ respectively, the pressure and volume at $B$ are $1\text{atm}$ and $50\text{L}$ and the pressure and volume at $C$ are $1\text{atm}$ and $10\text{L}$.

The formula for the energy added by the gas in process $AB$

    $Q_{\text{AB}}=-W_{\text{AB}}$

Substitute $-8.15\times {10}^3\text{J}$ for $W_{\text{AB}}$ in above equation to find $Q_{\text{AB}}$.

    $\begin{array}{c}{Q}_{\text{AB}}=-\left(-8.15\times {10}^3\text{J}\right)\\ =8.15\times {10}^3\text{J}\end{array}$

Thus, the energy added by the gas in process $AB$ is $8.15\times {10}^3\text{J}$.

Write the formula for temperature at $A$ and $B$ are,

    $\begin{array}{l}{T}_{\text{A}}=T_{\text{B}}=\frac{P_{\text{B}}{V}_{\text{B}}}{nR}\\ \end{array}$

Substitute $1\text{atm}$ for $P_{\text{B}}$, $1\text{mole}$ for $n$ and $50\text{L}$ for $V_{\text{B}}$ in above equation to find $T_{\text{A}}$.

    $\begin{array}{c}{T}_{\text{A}}=T_{\text{B}}=\frac{1\text{atm}\left(\frac{1.013\times {10}^5\text{Pa}}{1\text{atm}}\right)\times 50\text{L}\times \left(\frac{1{\text{m}}^3}{1\text{L}}\right)}{1\times R}\\ =\frac{5.05\times {10}^3}{R}\text{K}\end{array}$

Write the formula for temperature at $C$

    $\begin{array}{l}{T}_{\text{C}}=\frac{P_{\text{C}}{V}_{\text{C}}}{nR}\\ \end{array}$

Substitute $1\text{atm}$ for $P_{\text{C}}$, $1\text{mole}$ for $n$ and $10\text{L}$ for $V_{\text{C}}$ in above equation to find the $T_{\text{C}}$.

    $\begin{array}{c}{T}_{\text{C}}=\frac{1\text{atm}\left(\frac{1.013\times {10}^5\text{Pa}}{1\text{atm}}\right)\times 10\text{L}\times \left(\frac{1{\text{m}}^3}{1\text{L}}\right)}{1\times R}\\ =\frac{1.01\times {10}^3}{R}\text{K}\end{array}$

Write the formula for the energy added by the gas in process $CA$

    $Q_{\text{CA}}=n{C}_{\text{V}}\left(T_{\text{A}}-T_{\text{C}}\right)$

Here, $C_{\text{V}}$ is the specific heat at constant volume.

Substitute $\frac{1.01\times {10}^3}{R}\text{K}$ for $T_{\text{C}}$, $\frac{5.05\times {10}^3}{R}\text{K}$ for $T_{\text{A}}$ and $\frac{3}{2}R$ for $C_{\text{V}}$  in above equation to find $Q_{\text{CA}}$.

    $\begin{array}{c}{Q}_{\text{CA}}=\left(1\text{mol}\right)\left(\frac{3}{2}R\right)\left(\frac{5.05\times {10}^3}{R}\text{K}-\frac{1.01\times {10}^3}{R}\text{K}\right)\\ =6.08\times {10}^3\text{J}\end{array}$

Write the formula for the total energy added

    $Q_{\text{T}}=Q_{\text{CA}}+Q_{\text{AB}}$

Conclusion:

Substitute $8.15\times {10}^3\text{J}$ for $Q_{\text{AB}}$ and $6.08\times {10}^3\text{J}$ for $Q_{\text{CA}}$ in above equation to find $Q_{\text{T}}$.

    $\begin{array}{c}{Q}_{\text{T}}=6.08\times {10}^3\text{J}+8.15\times {10}^3\text{J}\\ =1.42\times {10}^4\text{J}\end{array}$

Thus, the total energy added is $1.42\times {10}^4\text{J}$.

To determine

The energy exhausted from the gas by heat.

Answer to Problem 22.73AP

The energy exhausted from the gas by heat is $1.01\times {10}^4\text{J}$.

Explanation of Solution

The pressure and volume at A are $5\text{atm}$ and $10\text{L}$ respectively, the pressure and volume at B are $1\text{atm}$ and $50\text{L}$ and the pressure and volume at C are $1\text{atm}$ and $10\text{L}$.

Write the formula for the energy added by the gas in process $BC$

    $Q_{\text{BC}}=\frac{5}{2}{P}_{\text{B}}\left(V_{\text{C}}-V_{\text{B}}\right)$

Conclusion:

Substitute $1\text{atm}$ for $P_{\text{B}}$, $50\text{L}$ for $V_{\text{B}}$ and $50\text{L}$ for $V_{\text{C}}$  in above equation to find $Q_{\text{BC}}$.

    $\begin{array}{c}{Q}_{\text{BC}}=\frac{5}{2}\left(1\text{atm}\right)\left(\frac{1.013\times {10}^5\text{Pa}}{1\text{atm}}\right)\left(10-50\right)\text{L}\left(\frac{{10}^{-3}{\text{m}}^3}{1\text{L}}\right)\\ =-\text{1}\text{.01}\times {\text{10}}^4\text{J}\end{array}$

Thus, the energy exhausted in process $BC$ is $1.01\times {10}^4\text{J}$.

To determine

The efficiency of the cycle.

Answer to Problem 22.73AP

The efficiency of the cycle is $28.9\%$.

Explanation of Solution

The pressure and volume at A are $5\text{atm}$ and $10\text{L}$ respectively, the pressure and volume at B are $1\text{atm}$ and $50\text{L}$ and the pressure and volume at C are $1\text{atm}$ and $10\text{L}$.

Write the formula to calculate the efficiency of the engine

    $e=\frac{W}{Q_{\text{T}}}$

Here, $e$ is the efficiency of engine and $W$ is the work done by the engine.

Conclusion:

Substitute $4.10\times {10}^3\text{J}$ for $W$ and $1.42\times {10}^4\text{J}$ for $Q_{\text{T}}$ in above equation to find the $e$.

    $\begin{array}{c}e=\frac{4.10\times {10}^3\text{J}}{1.42\times {10}^4\text{J}}\\ =0.28\left(\frac{100\%}{1}\right)\\ =28.9\%\end{array}$

Thus, the efficiency of the engine is $28.9\%$.

To determine

The comparison of efficiency to that of the Carnot engine.

Answer to Problem 22.73AP

The efficiency of Carnot engine is $80.0\%$, the efficiency of this cycle is much less than that of the Carnot cycle operating within the same temperature range.

Explanation of Solution

The pressure and volume at A are $5\text{atm}$ and $10\text{L}$ respectively, the pressure and volume at B are $1\text{atm}$ and $50\text{L}$ and the pressure and volume at C are $1\text{atm}$ and $10\text{L}$.

Write the formula to calculate the efficiency of the Carnot engine

    $e=1-\frac{T_{\text{C}}}{T_{\text{A}}}$

Conclusion:

Substitute $\frac{1.01\times {10}^3}{R}\text{K}$ for $T_{\text{C}}$, $\frac{5.05\times {10}^3}{R}\text{K}$ for $T_{\text{A}}$ in above equation to find the $e$

    $\begin{array}{c}e=1-\frac{\frac{1.01\times {10}^3}{R}\text{K}}{\frac{5.05\times {10}^3}{R}\text{K}}\\ \text{=1-0}\text{.2}\\ \text{=0}\text{.8}\left(\frac{100\%}{1}\right)\\ =80\%\end{array}$

Therefore, the efficiency of Carnot engine is $80.0\%$, the efficiency of this cycle is much less than that of the Carnot cycle operating within the same temperature range.