Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Question
Chapter 22, Problem 26PS

(a)

Interpretation Introduction

Interpretation: The electronic configuration, magnetic character and the number of unpaired electrons for the given set of high spin tetrahedral complexes has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand.

The five d orbitals get divided into two sets that is dxy, dyz and dxz orbitals forms one set and dx2-y2and dz2 forms another set. The first set are oriented between the x, y and z axes whereas the second set gets oriented along the axis.

Electronic configuration: It is defined as the distribution of electrons present in the atom over orbitals following certain rules like electrons starts filling the lower energy orbital to higher energy, pairing of electrons does not occur until all the orbitals are singly filled and finally no electrons present in orbital can have same set of quantum numbers.

(b)

Interpretation Introduction

Interpretation: The electronic configuration, magnetic character and the number of unpaired electrons for the given set of high spin tetrahedral complexes has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand.

The five d orbitals get divided into two sets that is dxy, dyz and dxz orbitals forms one set and dx2-y2and dz2 forms another set. The first set are oriented between the x, y and z axes whereas the second set gets oriented along the axis.

Electronic configuration: It is defined as the distribution of electrons present in the atom over orbitals following certain rules like electrons starts filling the lower energy orbital to higher energy, pairing of electrons does not occur until all the orbitals are singly filled and finally no electrons present in orbital can have same set of quantum numbers.

(c)

Interpretation Introduction

Interpretation: The electronic configuration, magnetic character and the number of unpaired electrons for the given set of high spin tetrahedral complexes has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand.

The five d orbitals get divided into two sets that is dxy, dyz and dxz orbitals forms one set and dx2-y2and dz2 forms another set. The first set are oriented between the x, y and z axes whereas the second set gets oriented along the axis.

Electronic configuration: It is defined as the distribution of electrons present in the atom over orbitals following certain rules like electrons starts filling the lower energy orbital to higher energy, pairing of electrons does not occur until all the orbitals are singly filled and finally no electrons present in orbital can have same set of quantum numbers.

(d)

Interpretation Introduction

Interpretation: The electronic configuration, magnetic character and the number of unpaired electrons for the given set of high spin tetrahedral complexes has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand.

The five d orbitals get divided into two sets that is dxy, dyz and dxz orbitals forms one set and dx2-y2and dz2 forms another set. The first set are oriented between the x, y and z axes whereas the second set gets oriented along the axis.

Electronic configuration: It is defined as the distribution of electrons present in the atom over orbitals following certain rules like electrons starts filling the lower energy orbital to higher energy, pairing of electrons does not occur until all the orbitals are singly filled and finally no electrons present in orbital can have same set of quantum numbers.

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Chapter 22 Solutions

Chemistry & Chemical Reactivity

Ch. 22.3 - 2. What is the oxidation number of the metal in...Ch. 22.3 - Prob. 3RCCh. 22.3 - Prob. 4RCCh. 22.4 - What types of isomers are possible for the...Ch. 22.4 - Prob. 1RCCh. 22.4 - Prob. 2RCCh. 22.4 - Prob. 3RCCh. 22.4 - Prob. 4RCCh. 22.4 - Prob. 1QCh. 22.5 - Prob. 1CYUCh. 22.5 - Prob. 1RCCh. 22.5 - Prob. 2RCCh. 22.6 - Prob. 1QCh. 22.6 - Prob. 2QCh. 22.6 - Prob. 3QCh. 22.6 - Prob. 4QCh. 22.6 - Prob. 1CYUCh. 22.6 - Prob. 1RCCh. 22.6 - How are the d electrons of Pt distributed in a...Ch. 22.6 - What are the electron configurations for Nd and...Ch. 22.6 - Prob. 3CSCh. 22.6 - Prob. 4CSCh. 22.6 - Prob. 5CSCh. 22 - Prob. 1PSCh. 22 - Prob. 2PSCh. 22 - Identify a cation of a first series transition...Ch. 22 - Match up the isoelectronic ions on the following...Ch. 22 - Prob. 5PSCh. 22 - Prob. 6PSCh. 22 - Which of the following ligands is expected to be...Ch. 22 - One of the following nitrogen compounds or ions is...Ch. 22 - Prob. 9PSCh. 22 - Prob. 10PSCh. 22 - Prob. 11PSCh. 22 - Prob. 12PSCh. 22 - Prob. 13PSCh. 22 - Prob. 14PSCh. 22 - Prob. 15PSCh. 22 - Prob. 16PSCh. 22 - Give the name or formula for each ion or compound,...Ch. 22 - Prob. 18PSCh. 22 - Prob. 19PSCh. 22 - Prob. 20PSCh. 22 - Prob. 21PSCh. 22 - Prob. 22PSCh. 22 - Prob. 23PSCh. 22 - Prob. 24PSCh. 22 - Prob. 25PSCh. 22 - Prob. 26PSCh. 22 - Prob. 27PSCh. 22 - Prob. 28PSCh. 22 - Prob. 29PSCh. 22 - Prob. 30PSCh. 22 - In water, the titanium(III) ion, [Ti(H2O)6]3+, has...Ch. 22 - Prob. 32PSCh. 22 - Prob. 33GQCh. 22 - Prob. 34GQCh. 22 - How many unpaired electrons are expected for...Ch. 22 - Prob. 36GQCh. 22 - Which of the following complex ions is (are)...Ch. 22 - Prob. 38GQCh. 22 - How many geometric isomers are possible for the...Ch. 22 - For a tetrahedral complex of a metal in the first...Ch. 22 - Prob. 41GQCh. 22 - Prob. 42GQCh. 22 - Prob. 43GQCh. 22 - A platinum-containing compound, known as Magnuss...Ch. 22 - Prob. 45GQCh. 22 - Prob. 46GQCh. 22 - Prob. 47GQCh. 22 - How many geometric isomers of the complex ion...Ch. 22 - Prob. 49GQCh. 22 - Prob. 50GQCh. 22 - Prob. 51GQCh. 22 - The square-planar complex Pt(en)Cl2 has chloride...Ch. 22 - The complex [Mn(H2O)6]2+ has five unpaired...Ch. 22 - Experiments show that K4[Cr(CN)6] is paramagnetic...Ch. 22 - Give a systematic name or the formula for the...Ch. 22 - When CrCI3 dissolves in water, three different...Ch. 22 - Prob. 57GQCh. 22 - The glycinate ion, H2NCH2CO2, formed by...Ch. 22 - Prob. 59GQCh. 22 - Nickel and palladium both form complexes of the...Ch. 22 - The transition metals form a class of compounds...Ch. 22 - Cerium, as noted in Applying Chemical Principles:...Ch. 22 - Prob. 64GQCh. 22 - Two different coordination compounds containing...Ch. 22 - Prob. 71SCQCh. 22 - Prob. 69SCQCh. 22 - Prob. 70SCQ
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