Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Question
Chapter 23, Problem 108SCQ
Interpretation Introduction
Interpretation:
The reason for why there is a high barrier to rotation arround a carbon–carbon double bond than carbon–carbon single bond has to be explained
Concept introduction:
In Orbital overlap model of bonding , two nuclei’s of two atoms are approach each other and overlap their atomic orbitals. As the overlapping the energy increases, the interaction decreases.
After some distance the minimum energy is reached and it corresponds to the bonding distance. The two atoms of nuclei begin to repel and energy increases.
There is a high barrier to rotation arround a carbon –carbon double bond than carbon-carbon single bond because higher energy require to break the pi-bond than the sigma bond.
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Chapter 23 Solutions
Chemistry & Chemical Reactivity
Ch. 23.2 - (a) Draw the nine isomers having the formula...Ch. 23.2 - Prob. 2CYUCh. 23.2 - There are 17 possible alkene isomers with the...Ch. 23.2 - Prob. 4CYUCh. 23.2 - Aniline, C6H5NH2, is the common name for...Ch. 23.2 - What is the systematic name for this alkane? (a)...Ch. 23.2 - Prob. 2RCCh. 23.2 - Prob. 3RCCh. 23.2 - Prob. 4RCCh. 23.2 - 5. How many isomers are possible for C6H4(CH3)Cl,...
Ch. 23.3 - Draw the structure of 1-butanol and alcohols that...Ch. 23.3 - Prob. 1RCCh. 23.3 - Prob. 2RCCh. 23.3 - What is the hybridization of nitrogen in...Ch. 23.3 - Prob. 4RCCh. 23.4 - (a) Name each of the following compounds and its...Ch. 23.4 - Prob. 1RCCh. 23.4 - Prob. 2RCCh. 23.4 - Prob. 3RCCh. 23.4 - Prob. 4RCCh. 23.4 - Prob. 1QCh. 23.4 - Prob. 2QCh. 23.4 - Prob. 3QCh. 23.5 - Kevlar is a well-known polymer that is now used to...Ch. 23.5 - Prob. 1QCh. 23.5 - Prob. 2QCh. 23.5 - Prob. 3QCh. 23.5 - Prob. 1RCCh. 23.5 - What is the atom economy for the reaction of...Ch. 23.5 - Prob. 5QCh. 23.5 - If drinking from a polycarbonate bottle, does a 15...Ch. 23.5 - Assume you weigh 156 lb. How much BPA do you...Ch. 23.5 - Prob. 8QCh. 23 - Prob. 1PSCh. 23 - What is the molecular formula for an alkane with...Ch. 23 - Prob. 3PSCh. 23 - Prob. 4PSCh. 23 - One of the structural isomers with the formula...Ch. 23 - Prob. 6PSCh. 23 - Prob. 7PSCh. 23 - Give the systematic name for the following alkane....Ch. 23 - Draw the structure of each of the following...Ch. 23 - Draw structures for the following compounds. (a)...Ch. 23 - Prob. 11PSCh. 23 - Prob. 12PSCh. 23 - Draw the structure of the chair form of...Ch. 23 - Prob. 14PSCh. 23 - Prob. 15PSCh. 23 - Prob. 16PSCh. 23 - Prob. 17PSCh. 23 - Prob. 18PSCh. 23 - Prob. 19PSCh. 23 - What structural requirement is necessary for an...Ch. 23 - A hydrocarbon with the formula C5H10, can be...Ch. 23 - Prob. 22PSCh. 23 - Prob. 23PSCh. 23 - Prob. 24PSCh. 23 - The compound 2-bromobutane is a product of...Ch. 23 - The compound 2,3-dibromo-2-methylhexane is formed...Ch. 23 - Prob. 27PSCh. 23 - Prob. 28PSCh. 23 - Prob. 29PSCh. 23 - Prob. 30PSCh. 23 - Prob. 31PSCh. 23 - Give the systematic name for each of the following...Ch. 23 - Prob. 33PSCh. 23 - Write an equation for the preparation of...Ch. 23 - Prob. 35PSCh. 23 - Prob. 36PSCh. 23 - Prob. 37PSCh. 23 - Prob. 38PSCh. 23 - Prob. 39PSCh. 23 - Name the following amines: (a) CH3CH2CH2NH2 (b)...Ch. 23 - Draw structural formulas for the four possible...Ch. 23 - Prob. 42PSCh. 23 - Prob. 43PSCh. 23 - Prob. 44PSCh. 23 - Prob. 45PSCh. 23 - Prob. 46PSCh. 23 - Prob. 47PSCh. 23 - Prob. 48PSCh. 23 - Prob. 49PSCh. 23 - Prob. 50PSCh. 23 - Give the structural formula and systematic name...Ch. 23 - Prob. 52PSCh. 23 - Prob. 53PSCh. 23 - Prob. 54PSCh. 23 - Prob. 55PSCh. 23 - Prob. 56PSCh. 23 - Prob. 57PSCh. 23 - Prob. 58PSCh. 23 - Prob. 59PSCh. 23 - Prob. 60PSCh. 23 - Identify the functional groups in the following...Ch. 23 - Prob. 62PSCh. 23 - Prob. 63PSCh. 23 - Prob. 64PSCh. 23 - Prob. 65PSCh. 23 - Prob. 66PSCh. 23 - Prob. 67GQCh. 23 - Prob. 68GQCh. 23 - Prob. 69GQCh. 23 - Prob. 70GQCh. 23 - Prob. 71GQCh. 23 - Prob. 72GQCh. 23 - Prob. 73GQCh. 23 - Write equations for the following reactions,...Ch. 23 - Prob. 75GQCh. 23 - Prob. 76GQCh. 23 - Draw the structure of each of the following...Ch. 23 - Prob. 78GQCh. 23 - Prob. 79GQCh. 23 - Draw structural formulas for possible isomers with...Ch. 23 - Prob. 81GQCh. 23 - Prob. 82GQCh. 23 - Prob. 83GQCh. 23 - Prob. 84GQCh. 23 - Prob. 85GQCh. 23 - Prob. 86GQCh. 23 - Draw the structure of glyceryl trilaurate, a fat....Ch. 23 - Prob. 88GQCh. 23 - Prob. 89GQCh. 23 - Prob. 90GQCh. 23 - Prob. 91GQCh. 23 - There are three ethers with the formula C4H10O....Ch. 23 - Review the opening photograph about chocolate...Ch. 23 - Prob. 94GQCh. 23 - Prob. 95ILCh. 23 - Prob. 96ILCh. 23 - Prob. 97ILCh. 23 - Prob. 98ILCh. 23 - Prob. 99ILCh. 23 - Prob. 100ILCh. 23 - Prob. 101ILCh. 23 - Prob. 102ILCh. 23 - Prob. 103ILCh. 23 - Prob. 104ILCh. 23 - Prob. 105ILCh. 23 - Prob. 106ILCh. 23 - Prob. 107SCQCh. 23 - Prob. 108SCQCh. 23 - Prob. 109SCQCh. 23 - Prob. 110SCQCh. 23 - Prob. 111SCQCh. 23 - Prob. 112SCQCh. 23 - Prob. 113SCQ
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Similar questions
- Alcohols A, B and C all have the composition C4H 100. Molecules of alcohol A contain a branched carbon chain and can be oxidized to an aldehyde; molecules of alcohol B contain a linear carbon chain and can be oxidized to a ketone; and molecules of alcohol C can be oxidized to neither an aldehyde nor a ketone. Write the Lewis structures of these molecules.arrow_forwardWhat is the hybridization of the carbon atoms in the carbon-carbon double bond?arrow_forwardSome alkenes have cis-trans isomers because a. the carbon atoms in the double bond are free to rotate. b. one of the carbon atoms in the double bond has two identical groups attached to it. c. all of the carbon atoms in the compound are rigid and cannot rotate. d. each of the carbon atoms in the double bond has four different groups attached to it. e. the carbon atoms in the double bond cannot rotate.arrow_forward
- Alcohols A, B, and C all have the composition C4H10O. Molecules of alcohol A contain a branched carbon chain and can be oxidized to an aldehyde; molecules of alcohol B contain a linear carbon chain and can be oxidizedto a ketone; and molecules of alcohol C can be oxidized to neither an aldehyde nor a ketone. Write the Lewis structures of these molecules.arrow_forwardWhy are aldehydes and ketones relatively weaker than alcohol in the context of hydrogen bond formation?arrow_forwardDefine Semivolatile organic compounds (SVOCs).arrow_forward
- Define attached Bonding in a Carbon-Carbon Double Bond ?arrow_forwardAlkanes are hydrocarbons containing only single bonds. Acyclic alkanes have carbon atoms arranged in chains, whereas cycloalkanes have carbon atoms arranged in one or more rings. How many hydrogen atoms are in an acyclic alkane with 6 carbon atoms?arrow_forward1. Explain the term, selective solubility.2. Name five solvents available to the organic chemists for use in the purification of organic compounds.3. Explain the term sublimation.arrow_forward
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