General Chemistry: Atoms First
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 23, Problem 23.33CP
Interpretation Introduction

Interpretation:

The condensed structure and possible isomers should be drawn and identified for the given molecular model structure.

Concept Introduction:

Condensed Structure: It is the one, where the symbols of atoms are listed in order as they appear in the molecules structure with bond dashes omitted or limited.

  1. 1. A molecular formula explains only the number of atoms of each element in a molecule of the compound.
  2. 2. Condensed structure shows all atoms, but it omits the vertical bonds and most or all of the vertical bonds and most or all of the horizontal single bonds.

Isomers: The molecules with same molecular formula but differ in the way in which the atoms are arranged is known as isomers.

In other words compounds have the same molecular formula but have different structural formula and different names.

Expert Solution & Answer
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Answer to Problem 23.33CP

Condensed structure of given molecular model is,

General Chemistry: Atoms First, Chapter 23, Problem 23.33CP , additional homework tip  1

Explanation of Solution

Given molecular model presence of seven carbon atoms and 14 hydrogen atoms and all hydrogen atoms horizontally connected to respective carbon atoms, so given molecular model is correctly matched for a  5-methylhex-5-ene-2-ol molecule and condensed structure is shown below.

General Chemistry: Atoms First, Chapter 23, Problem 23.33CP , additional homework tip  2

Determination of possible isomers:

Above the condensed structure was found to have two possible isomers, the possible isomers structure are shown below,

General Chemistry: Atoms First, Chapter 23, Problem 23.33CP , additional homework tip  3

5-methyl hex-5-en-2-ol:

General Chemistry: Atoms First, Chapter 23, Problem 23.33CP , additional homework tip  4

The above structure, 11 hydrogen atoms are horizontally connected to respective carbon atoms, one methyl groups is connected in branched position and another one hydroxyl group connected in (C2) carbon atom in branched position, hence one possible isomer is 5-methyl hex-5-en-2-ol and condensed structure is shown above.

5-methoxy-2-methylpent-2-ene:

Given molecular model structure was founded to have another possible isomers,

General Chemistry: Atoms First, Chapter 23, Problem 23.33CP , additional homework tip  5

In second molecule 11 hydrogen atoms are horizontally connected to respective carbon atoms, and one methyl group is connected in branched position, than another one methoxy group connected in (C5) carbon atom in linear position, the another one possible condensed structure is placed above.

Conclusion

For the given molecular model, the condensed structure was drawn and possible isomers were determined.

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Chapter 23 Solutions

General Chemistry: Atoms First

Ch. 23.4 - Prob. 23.11PCh. 23.4 - Prob. 23.12PCh. 23.4 - Prob. 23.13PCh. 23.5 - Prob. 23.14PCh. 23.5 - Draw structures corresponding to the following...Ch. 23.6 - Draw structures corresponding to the following...Ch. 23.6 - Write the products from reaction of the following...Ch. 23.6 - Reaction of Br2/FeBr3 with toluene (methylbenzene)...Ch. 23.7 - Prob. 23.19PCh. 23.8 - Draw structures corresponding to the following...Ch. 23.8 - Prob. 23.21PCh. 23.8 - Prob. 23.22CPCh. 23.10 - Prob. 23.23PCh. 23.10 - Prob. 23.24PCh. 23.10 - Prob. 23.25PCh. 23.11 - Prob. 23.26PCh. 23.12 - Show the structure of glyceryl trioleate, a fat...Ch. 23.13 - Prob. 23.28PCh. 23.13 - Prob. 23.29PCh. 23.13 - Prob. 23.30PCh. 23.13 - Prob. 23.31CPCh. 23.13 - Prob. 23.32PCh. 23 - Prob. 23.33CPCh. 23 - Prob. 23.34CPCh. 23 - Prob. 23.35CPCh. 23 - Prob. 23.36CPCh. 23 - Prob. 23.37CPCh. 23 - Prob. 23.38CPCh. 23 - Prob. 23.39CPCh. 23 - Prob. 23.40SPCh. 23 - Prob. 23.41SPCh. 23 - Prob. 23.42SPCh. 23 - Prob. 23.43SPCh. 23 - Prob. 23.44SPCh. 23 - Prob. 23.45SPCh. 23 - Prob. 23.46SPCh. 23 - Prob. 23.47SPCh. 23 - Prob. 23.48SPCh. 23 - What is wrong with each of the following...Ch. 23 - What are the IUPAC names of the following alkanes?Ch. 23 - Prob. 23.51SPCh. 23 - Prob. 23.52SPCh. 23 - Prob. 23.53SPCh. 23 - Prob. 23.54SPCh. 23 - Prob. 23.55SPCh. 23 - Prob. 23.56SPCh. 23 - Prob. 23.57SPCh. 23 - Prob. 23.58SPCh. 23 - Prob. 23.59SPCh. 23 - Prob. 23.60SPCh. 23 - Prob. 23.61SPCh. 23 - Prob. 23.62SPCh. 23 - Prob. 23.63SPCh. 23 - Draw structures corresponding to the following (a)...Ch. 23 - Prob. 23.65SPCh. 23 - Prob. 23.66SPCh. 23 - Prob. 23.67SPCh. 23 - Prob. 23.68SPCh. 23 - Draw and name compounds that meet the following...Ch. 23 - Prob. 23.70SPCh. 23 - Prob. 23.71SPCh. 23 - Prob. 23.72SPCh. 23 - Prob. 23.73SPCh. 23 - Prob. 23.74SPCh. 23 - Prob. 23.75SPCh. 23 - Prob. 23.76SPCh. 23 - Prob. 23.77SPCh. 23 - Prob. 23.78SPCh. 23 - Prob. 23.79SPCh. 23 - Prob. 23.80SPCh. 23 - Prob. 23.81SPCh. 23 - Prob. 23.82SPCh. 23 - Prob. 23.83SPCh. 23 - Prob. 23.84SPCh. 23 - Prob. 23.85SPCh. 23 - Prob. 23.86SPCh. 23 - Prob. 23.87SPCh. 23 - There are two isomeric fat molecules whose...Ch. 23 - Prob. 23.89SPCh. 23 - What is a nucleotide, and what three kinds of...Ch. 23 - What are the names of the sugars in DNA and RNA,...Ch. 23 - Prob. 23.92SPCh. 23 - Prob. 23.93SPCh. 23 - Prob. 23.94SPCh. 23 - Prob. 23.95SPCh. 23 - Prob. 23.96SPCh. 23 - Prob. 23.97SPCh. 23 - Prob. 23.98CHPCh. 23 - Prob. 23.99CHPCh. 23 - Prob. 23.100CHPCh. 23 - Prob. 23.101CHPCh. 23 - Write full structures for the following peptides,...Ch. 23 - Prob. 23.103CHPCh. 23 - Prob. 23.104CHPCh. 23 - Prob. 23.105CHPCh. 23 - Prob. 23.106CHPCh. 23 - Elaidic acid, a component of so-called trans fats,...Ch. 23 - Fumaric acid is an organic substance widely used...
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