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ChemistryChemistry & Chemical Reactivity10th Edition

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Chapter 23, Problem 41PS
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Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074

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Problem 2PS
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Problem 6PS
Problem 7PS
Problem 8PS
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Problem 11PS
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Problem 13PS
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Problem 15PS
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Problem 18PS
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Problem 20PS
Problem 21PS
Problem 22PS
Problem 23PS
Problem 24PS
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Problem 38PS
Problem 39PS
Problem 40PS
Problem 41PS
Problem 42PS
Problem 43PS
Problem 44PS
Problem 45PS
Problem 46PS
Problem 47PS
Problem 48PS
Problem 49PS
Problem 50PS
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Problem 92GQ
Problem 93GQ
Problem 94GQ
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Problem 96GQ
Problem 97GQ
Problem 98GQ
Problem 99GQ
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Problem 101GQ
Problem 102GQ
Problem 103IL
Problem 104IL
Problem 105IL
Problem 106IL
Problem 107IL
Problem 108IL
Problem 109IL
Problem 110IL
Problem 111IL
Problem 112IL
Problem 113IL
Problem 114IL
Problem 115SCQ
Problem 116SCQ
Problem 117SCQ
Problem 118SCQ
Problem 119SCQ
Problem 120SCQ
Problem 121SCQ
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Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074
Textbook Problem

Write the equation for the reaction of 1,4-dimethylbenzene with CH3Cl and AlCl3. What is the structure and name of the single organic compound produced?

Interpretation Introduction

Interpretation: The equation for the reaction of 1,4-trimethylbenzene with CH3Cl and AlCl3 has to be written. The structure with name of the single organic product has to be given.

Concept introduction:

Friedel-Craft alkylation reaction: The reaction between alkyl halide and benzene derivative in presence of AlCl3 is known as Friedel-Craft alkylation reaction in presence of AlCl3 is known as Friedel-Craft alkylation reaction. The alkylation of benzene ring occurs via carbocation intermediate. The benzene ring with deactivating groups does not undergo Friedel-Craft raction. As the reactivity for these derivatives are less than that of benzene.

Explanation

The given reaction is known as Friedel-Craft alkylation reaction in which benzene or benzene derivatives undergo alkylation in the presence of a lewis acid AlCl3.

The alkylation takes place at 2 or ortho-position as already both the para positions are occupied.

The alkylating agent used is CH3Cl, which gives the methyl carbocation CH3+.

The methyl carbocation is substituted at 2 of the benzene ring via the attack of pi bond of benzene ring

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Sect-23.2 P-23.1CYUSect-23.2 P-23.2CYUSect-23.2 P-23.3CYUSect-23.2 P-23.4CYUSect-23.2 P-23.5CYUSect-23.3 P-23.6CYUSect-23.4 P-23.7CYUSect-23.5 P-23.8CYUSect-23.5 P-1.1ACPSect-23.5 P-1.2ACP
Sect-23.5 P-1.3ACPSect-23.5 P-2.1ACPSect-23.5 P-2.2ACPSect-23.5 P-2.3ACPSect-23.5 P-3.1ACPSect-23.5 P-3.2ACPSect-23.5 P-3.3ACPSect-23.5 P-3.4ACPSect-23.5 P-3.5ACPCh-23 P-1PSCh-23 P-2PSCh-23 P-3PSCh-23 P-4PSCh-23 P-5PSCh-23 P-6PSCh-23 P-7PSCh-23 P-8PSCh-23 P-9PSCh-23 P-10PSCh-23 P-11PSCh-23 P-12PSCh-23 P-13PSCh-23 P-14PSCh-23 P-15PSCh-23 P-16PSCh-23 P-17PSCh-23 P-18PSCh-23 P-19PSCh-23 P-20PSCh-23 P-21PSCh-23 P-22PSCh-23 P-23PSCh-23 P-24PSCh-23 P-25PSCh-23 P-26PSCh-23 P-27PSCh-23 P-28PSCh-23 P-29PSCh-23 P-30PSCh-23 P-31PSCh-23 P-32PSCh-23 P-33PSCh-23 P-34PSCh-23 P-35PSCh-23 P-36PSCh-23 P-37PSCh-23 P-38PSCh-23 P-39PSCh-23 P-40PSCh-23 P-41PSCh-23 P-42PSCh-23 P-43PSCh-23 P-44PSCh-23 P-45PSCh-23 P-46PSCh-23 P-47PSCh-23 P-48PSCh-23 P-49PSCh-23 P-50PSCh-23 P-51PSCh-23 P-52PSCh-23 P-53PSCh-23 P-54PSCh-23 P-55PSCh-23 P-56PSCh-23 P-57PSCh-23 P-58PSCh-23 P-59PSCh-23 P-60PSCh-23 P-61PSCh-23 P-62PSCh-23 P-63PSCh-23 P-64PSCh-23 P-65PSCh-23 P-66PSCh-23 P-67PSCh-23 P-68PSCh-23 P-69PSCh-23 P-70PSCh-23 P-71PSCh-23 P-72PSCh-23 P-73PSCh-23 P-74PSCh-23 P-75GQCh-23 P-76GQCh-23 P-77GQCh-23 P-78GQCh-23 P-79GQCh-23 P-80GQCh-23 P-81GQCh-23 P-82GQCh-23 P-83GQCh-23 P-84GQCh-23 P-85GQCh-23 P-86GQCh-23 P-87GQCh-23 P-88GQCh-23 P-89GQCh-23 P-90GQCh-23 P-91GQCh-23 P-92GQCh-23 P-93GQCh-23 P-94GQCh-23 P-95GQCh-23 P-96GQCh-23 P-97GQCh-23 P-98GQCh-23 P-99GQCh-23 P-100GQCh-23 P-101GQCh-23 P-102GQCh-23 P-103ILCh-23 P-104ILCh-23 P-105ILCh-23 P-106ILCh-23 P-107ILCh-23 P-108ILCh-23 P-109ILCh-23 P-110ILCh-23 P-111ILCh-23 P-112ILCh-23 P-113ILCh-23 P-114ILCh-23 P-115SCQCh-23 P-116SCQCh-23 P-117SCQCh-23 P-118SCQCh-23 P-119SCQCh-23 P-120SCQCh-23 P-121SCQ

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