BuyFindarrow_forward

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074

Solutions

Chapter
Section
BuyFindarrow_forward

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074
Textbook Problem

Aromatic compounds react with a mixture of nitric and sulfuric acid to form aromatic compounds containing a nitro (−NO2) group. Two isomeric compounds are formed by nitration of 1,2-dimethylbenzene. Draw the structures and name these compounds.

Interpretation Introduction

Interpretation: The equation for the nitartion reaction of 1,2-dimethylbenzene should be written. The structures with name of the two organic product formed should be drawn.

Concept introduction:

Nitration reaction: The reaction where a nitro group is introduced to an organic compound which reacts with conc. HNO3 in presence of H2SO4 is known as Nitration reaction. The nitration of benzene ring occurs via NO2+ intermediate. The electrophile will be substituted at ortho and para position of the ring.

Explanation

The nitration reaction of benzene with conc. HNO3 and H2SO4 gives ortho and para nitro substituted products.

While for the given reactant 1,2-dimethylbenzene one of the ortho position is already occupied by methyl group so one product will be para substituted with respect to the methyl group in the first carbon.

The second product will be when nitro group is substituted to other ortho position of methyl group in the second carbon atom

The reaction is written as follows,

  • For the first product the benzene ring is substituted at 1 and 2 positions by two methyl groups and third position by NO2 group

    So these methyl groups and nitro group come in prefix as 1,2-dimethyl-3-nitro of the systematic name with parent name benzene

Still sussing out bartleby?

Check out a sample textbook solution.

See a sample solution

The Solution to Your Study Problems

Bartleby provides explanations to thousands of textbook problems written by our experts, many with advanced degrees!

Get Started

Chapter 23 Solutions

Show all chapter solutions add
Sect-23.5 P-1.3ACPSect-23.5 P-2.1ACPSect-23.5 P-2.2ACPSect-23.5 P-2.3ACPSect-23.5 P-3.1ACPSect-23.5 P-3.2ACPSect-23.5 P-3.3ACPSect-23.5 P-3.4ACPSect-23.5 P-3.5ACPCh-23 P-1PSCh-23 P-2PSCh-23 P-3PSCh-23 P-4PSCh-23 P-5PSCh-23 P-6PSCh-23 P-7PSCh-23 P-8PSCh-23 P-9PSCh-23 P-10PSCh-23 P-11PSCh-23 P-12PSCh-23 P-13PSCh-23 P-14PSCh-23 P-15PSCh-23 P-16PSCh-23 P-17PSCh-23 P-18PSCh-23 P-19PSCh-23 P-20PSCh-23 P-21PSCh-23 P-22PSCh-23 P-23PSCh-23 P-24PSCh-23 P-25PSCh-23 P-26PSCh-23 P-27PSCh-23 P-28PSCh-23 P-29PSCh-23 P-30PSCh-23 P-31PSCh-23 P-32PSCh-23 P-33PSCh-23 P-34PSCh-23 P-35PSCh-23 P-36PSCh-23 P-37PSCh-23 P-38PSCh-23 P-39PSCh-23 P-40PSCh-23 P-41PSCh-23 P-42PSCh-23 P-43PSCh-23 P-44PSCh-23 P-45PSCh-23 P-46PSCh-23 P-47PSCh-23 P-48PSCh-23 P-49PSCh-23 P-50PSCh-23 P-51PSCh-23 P-52PSCh-23 P-53PSCh-23 P-54PSCh-23 P-55PSCh-23 P-56PSCh-23 P-57PSCh-23 P-58PSCh-23 P-59PSCh-23 P-60PSCh-23 P-61PSCh-23 P-62PSCh-23 P-63PSCh-23 P-64PSCh-23 P-65PSCh-23 P-66PSCh-23 P-67PSCh-23 P-68PSCh-23 P-69PSCh-23 P-70PSCh-23 P-71PSCh-23 P-72PSCh-23 P-73PSCh-23 P-74PSCh-23 P-75GQCh-23 P-76GQCh-23 P-77GQCh-23 P-78GQCh-23 P-79GQCh-23 P-80GQCh-23 P-81GQCh-23 P-82GQCh-23 P-83GQCh-23 P-84GQCh-23 P-85GQCh-23 P-86GQCh-23 P-87GQCh-23 P-88GQCh-23 P-89GQCh-23 P-90GQCh-23 P-91GQCh-23 P-92GQCh-23 P-93GQCh-23 P-94GQCh-23 P-95GQCh-23 P-96GQCh-23 P-97GQCh-23 P-98GQCh-23 P-99GQCh-23 P-100GQCh-23 P-101GQCh-23 P-102GQCh-23 P-103ILCh-23 P-104ILCh-23 P-105ILCh-23 P-106ILCh-23 P-107ILCh-23 P-108ILCh-23 P-109ILCh-23 P-110ILCh-23 P-111ILCh-23 P-112ILCh-23 P-113ILCh-23 P-114ILCh-23 P-115SCQCh-23 P-116SCQCh-23 P-117SCQCh-23 P-118SCQCh-23 P-119SCQCh-23 P-120SCQCh-23 P-121SCQ

Additional Science Solutions

Find more solutions based on key concepts

Show solutions add

Name the following compounds. a Na2SO4 b Na3N c CuCl d Cr2O3

General Chemistry - Standalone book (MindTap Course List)

By law, food labels must name the ingredients in descending order of predominance by weight and in ordinary lan...

Nutrition: Concepts and Controversies - Standalone book (MindTap Course List)

What are sister chromatids?

Human Heredity: Principles and Issues (MindTap Course List)

How is the ocean stratified by density? What names are given to the oceans density zones?

Oceanography: An Invitation To Marine Science, Loose-leaf Versin

Comet Halley (Fig. P13.23) approaches the Sun to within 0.570 AU, and its orbital period is 75.6 yr. (AU is the...

Physics for Scientists and Engineers, Technology Update (No access codes included)