Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 23.6, Problem 5P
Problem 23.5 The compound shown was required for the preparation of fluorescent markers for biological compounds. How can it be synthesized from
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How many signals do you expect in the 'H NMR spectrum for this molecule?
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
L
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in bottom
molecule…
now many signals do you expect in the 'H NMR spectrum for this molecule?
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
☐
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in bottom
molecule
Explanation
Check…
How many signals do you expect in the H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in bottom
molecule…
Chapter 23 Solutions
Organic Chemistry - Standalone book
Ch. 23.1 - Prob. 1PCh. 23.3 - Problem 23.2 One of the hydroxybenzoic acids is...Ch. 23.4 - Prob. 3PCh. 23.5 - Prob. 4PCh. 23.6 - Problem 23.5 The compound shown was required for...Ch. 23.8 - Prob. 6PCh. 23.8 - Prob. 7PCh. 23.9 - Prob. 8PCh. 23.9 - Prob. 9PCh. 23.10 - Prob. 10P
Ch. 23.12 - Prob. 11PCh. 23 - The IUPAC rules permit the use of common names for...Ch. 23 - Prob. 13PCh. 23 - Prob. 14PCh. 23 - Prob. 15PCh. 23 - Prob. 16PCh. 23 - Prob. 17PCh. 23 - Prob. 18PCh. 23 - Prob. 19PCh. 23 - Prob. 20PCh. 23 - Prob. 21PCh. 23 - Prob. 22PCh. 23 - Prob. 23PCh. 23 - Prob. 24PCh. 23 - Prob. 25PCh. 23 - Prob. 26PCh. 23 - Choose the reaction in each of the following pairs...Ch. 23 - Pentafluorophenol is readily prepared by heating...Ch. 23 - Prob. 29PCh. 23 - Treatment of p-hydroxybenzoic acid with aqueous...Ch. 23 - Prob. 31PCh. 23 - Prob. 32PCh. 23 - Treatment of 2,4,6-tri-tert-butylphenol with...Ch. 23 - Prob. 34PCh. 23 - Prob. 35PCh. 23 - Prob. 36DSPCh. 23 - Prob. 37DSPCh. 23 - Prob. 38DSPCh. 23 - Prob. 39DSP
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- Differentiate between atomic mass and atomic weight.arrow_forwardStudy this 'H NMR spectrum, and then answer the questions about it in the table below. 1.0- 0.5- 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 What unit symbol should be written on the horizontal axis? What is the chemical shift & of the quartet? If there is no quartet, just check the box instead. Give your answer to 2 significant digits. What is the chemical shift & of the signal immediately upfield of the doublet? If there is no doublet, or no signal upfield of it, check the box instead. What is the chemical shift 8 of the least deshielded proton? If you can't tell without more information, check the box instead. A 8=0 There is no quartet. No such signal. 8=0 Need more information. Explanation Check 2025 McGraw Hill LLC. All Rights Reserved. Terms ofarrow_forwardKinetics and Equilibrium = Calculating the solubility of an ionic compound when a common ion is... Calculate the solubility at 25 °C of PbCO 3 in pure water and in a 0.0090 M Pb (NO3), solution. You'll find K Round both of your answers to 2 significant digits. solubility in pure water: solubility in 0.0090 M Pb(NO3)2 solution: Explanation Check 口: g 口: x10 Х sp data in the ALEKS Data tab. 1/3 Ashley ✓ Solubility product constants (Ksp) ✓ HgS 4.00×10-54 Hg2SO4 6.5×10-7 PbBr2 6.60×10-6 00. PbCl 2 PbCO3 1.70×10-5 18 PbCrO4 7.40×10-14 2.00×10-14 Ar PbF2 3.3×10-8 PbI2 9.8×10-9 Pb(IO3)2 3.69×10-13 PbS 3.40×10-28 PbSO4 2.53×10-8 MgCO3 6.82×10-6 MgF2 5.16×10-11 Mg(OH)2 5.61×10-12 Mg3(PO4)2 Mn(OH)2 MnS -24 1.04×10¯ NiCO3 1.60×10-13 3.00×10-14 1.42×10-7 MOUN 16 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forward
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