a) Interpretation: The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given. Concept introduction: Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester. To give: The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Question

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 24

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Students have asked these similar questions

How might you prepare this molecule using a nucleophilic displacement of an alkyl halide?

Amino acids can be prepared by the reaction of alkyl halides with diethyl acetamidomalonate, followed by heating the initial alkylation product with aqueous HCl. The reaction to form alanine involves the following steps: Reaction of diethyl acetamidomalonate with sodium ethoxide to form enolate anion 1; The enolate anion acts as a nucleophile in an SN2 reaction with alkyl iodide 2 to form alkylated intermediate 2; Heating in the presence of aqueous acid hydrolyzes both the ester and the amide bonds, and induces decarboxylation to form alanine. Draw the structure of enolate anion 1.

Show how the following products can be synthesized via a Michael reaction.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 24

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 24

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 24

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Answer 5

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 24

Answer 6

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 4

Answer 7

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 8

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 2

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 3

Answer 13

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 4

Answer 14

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 8

Answer 15

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 16

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 6

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 7

Answer 21

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 8

Answer 22

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 12

Answer 23

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 24

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 10

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 11

Answer 29

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 12

Answer 30

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 16

Answer 31

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 32

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 14

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 15

Answer 37

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 16

Answer 38

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 20

Answer 39

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 40

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 18

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 19

Answer 45

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 20

Answer 46

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 24

Answer 47

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 48

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 22

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Organic Chemistry, Chapter 23.SE, Problem 62AP , additional homework tip 23