General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 25, Problem 25.107EP

(a)

Interpretation Introduction

Interpretation:

Whether crotonate, a C4 species is a (1) hydroxy acid, (2) keto acid, (3) saturated acid, or (4) unsaturated acid has to be identified.

Concept introduction:

Functional groups are defined as the group of atoms which are attached to the carbon backbone of organic compounds. These are generally heteroatoms which are attached to the parent hydrocarbon chain. Some examples of functional groups are as follows:

General, Organic, and Biological Chemistry, Chapter 25, Problem 25.107EP , additional homework tip  1

Here, R and R represent an alkyl group. In alkene, R1, R2, R3, and R4 can be the same or different or can be hydrogen. Alkanes are saturated hydrocarbons that contain covalently bonded hydrogen and carbon atoms. Alkenes have a double bond, hence; they are unsaturated compounds.

Keto acid has a ketone and a carboxylic acid (-COOH) group. Hydroxy acid has a hydroxy (-OH) group and a carboxylic acid (-COOH) group. Saturated acids contain single bonds between carbon atoms and a carboxylic group. Unsaturated acid contains a double or triple bond between carbon atoms and a carboxylic group.

A carboxylate group is formed by the removal of the acidic hydrogen from the carboxylic group. The conjugate base is formed by the removal of acidic hydrogen from the corresponding acid.

(b)

Interpretation Introduction

Interpretation:

Whether oxaloacetate, a C4 species is a (1) hydroxy acid, (2) keto acid, (3) saturated acid, or (4) unsaturated acid has to be identified.

Concept introduction:

Functional groups are defined as the group of atoms which are attached to the carbon backbone of organic compounds. These are generally heteroatoms which are attached to the parent hydrocarbon chain. Some examples of functional groups are as follows:

General, Organic, and Biological Chemistry, Chapter 25, Problem 25.107EP , additional homework tip  2

Here, R and R represent an alkyl group. In alkene, R1, R2, R3, and R4 can be the same or different or can be hydrogen. Alkanes are saturated hydrocarbons that contain covalently bonded hydrogen and carbon atoms. Alkenes have a double bond, hence; they are unsaturated compounds.

Keto acid has a ketone and a carboxylic acid (-COOH) group. Hydroxy acid has a hydroxy (-OH) group and a carboxylic acid (-COOH) group. Saturated acids contain single bonds between carbon atoms and a carboxylic group. Unsaturated acid contains a double or triple bond between carbon atoms and a carboxylic group.

A carboxylate group is formed by the removal of the acidic hydrogen from the carboxylic group. The conjugate base is formed by the removal of acidic hydrogen from the corresponding acid.

(c)

Interpretation Introduction

Interpretation:

Whether acetoacetate, a C4 species is a (1) hydroxy acid, (2) keto acid, (3) saturated acid, or (4) unsaturated acid has to be identified.

Concept introduction:

Functional groups are defined as the group of atoms which are attached to the carbon backbone of organic compounds. These are generally heteroatoms which are attached to the parent hydrocarbon chain. Some examples of functional groups are as follows:

General, Organic, and Biological Chemistry, Chapter 25, Problem 25.107EP , additional homework tip  3

Here, R and R represent an alkyl group. In alkene, R1, R2, R3, and R4 can be the same or different or can be hydrogen. Alkanes are saturated hydrocarbons that contain covalently bonded hydrogen and carbon atoms. Alkenes have a double bond, hence; they are unsaturated compounds.

Keto acid has a ketone and a carboxylic acid (-COOH) group. Hydroxy acid has a hydroxy (-OH) group and a carboxylic acid (-COOH) group. Saturated acids contain single bonds between carbon atoms and a carboxylic group. Unsaturated acid contains a double or triple bond between carbon atoms and a carboxylic group.

A carboxylate group is formed by the removal of the acidic hydrogen from the carboxylic group. The conjugate base is formed by the removal of acidic hydrogen from the corresponding acid.

(d)

Interpretation Introduction

Interpretation:

Whether malate, a C4 species is a (1) hydroxy acid, (2) keto acid, (3) saturated acid, or (4) unsaturated acid has to be identified.

Concept introduction:

Functional groups are defined as the group of atoms which are attached to the carbon backbone of organic compounds. These are generally heteroatoms which are attached to the parent hydrocarbon chain. Some examples of functional groups are as follows:

General, Organic, and Biological Chemistry, Chapter 25, Problem 25.107EP , additional homework tip  4

Here, R and R represent an alkyl group. In alkene, R1, R2, R3, and R4 can be the same or different or can be hydrogen. Alkanes are saturated hydrocarbons that contain covalently bonded hydrogen and carbon atoms. Alkenes have a double bond, hence; they are unsaturated compounds.

Keto acid has a ketone and a carboxylic acid (-COOH) group. Hydroxy acid has a hydroxy (-OH) group and a carboxylic acid (-COOH) group. Saturated acids contain single bonds between carbon atoms and a carboxylic group. Unsaturated acid contains a double or triple bond between carbon atoms and a carboxylic group.

A carboxylate group is formed by the removal of the acidic hydrogen from the carboxylic group. The conjugate base is formed by the removal of acidic hydrogen from the corresponding acid.

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Chapter 25 Solutions

General, Organic, and Biological Chemistry

Ch. 25.3 - Prob. 3QQCh. 25.4 - Prob. 1QQCh. 25.4 - Prob. 2QQCh. 25.4 - Prob. 3QQCh. 25.4 - Prob. 4QQCh. 25.4 - Prob. 5QQCh. 25.4 - Prob. 6QQCh. 25.5 - Prob. 1QQCh. 25.5 - Prob. 2QQCh. 25.5 - Prob. 3QQCh. 25.6 - Prob. 1QQCh. 25.6 - Prob. 2QQCh. 25.6 - Prob. 3QQCh. 25.6 - Prob. 4QQCh. 25.6 - Prob. 5QQCh. 25.6 - Prob. 6QQCh. 25.7 - Prob. 1QQCh. 25.7 - Prob. 2QQCh. 25.7 - Prob. 3QQCh. 25.7 - Prob. 4QQCh. 25.7 - The reducing agent needed in the process of...Ch. 25.7 - Prob. 6QQCh. 25.8 - Prob. 1QQCh. 25.8 - Prob. 2QQCh. 25.9 - Prob. 1QQCh. 25.9 - Prob. 2QQCh. 25.9 - Prob. 3QQCh. 25.9 - Prob. 4QQCh. 25.10 - Which of the following substances cannot be...Ch. 25.10 - Prob. 2QQCh. 25.10 - Which of the following processes occurs within the...Ch. 25.11 - Prob. 1QQCh. 25.11 - Prob. 2QQCh. 25.11 - Prob. 3QQCh. 25 - Indicate whether each of the following aspects of...Ch. 25 - Indicate whether each of the following aspects of...Ch. 25 - Indicate whether each of the following pairings of...Ch. 25 - Prob. 25.4EPCh. 25 - Indicate whether each of the following statements...Ch. 25 - Prob. 25.6EPCh. 25 - Prob. 25.7EPCh. 25 - What is a chylomicron?Ch. 25 - What are the products of the complete hydrolysis...Ch. 25 - What are the major products of the incomplete...Ch. 25 - Prob. 25.11EPCh. 25 - At what location are free fatty acids and...Ch. 25 - Prob. 25.13EPCh. 25 - Prob. 25.14EPCh. 25 - Prob. 25.15EPCh. 25 - Prob. 25.16EPCh. 25 - Prob. 25.17EPCh. 25 - Prob. 25.18EPCh. 25 - Prob. 25.19EPCh. 25 - Prob. 25.20EPCh. 25 - Prob. 25.21EPCh. 25 - Prob. 25.22EPCh. 25 - Prob. 25.23EPCh. 25 - Prob. 25.24EPCh. 25 - Prob. 25.25EPCh. 25 - Prob. 25.26EPCh. 25 - Prob. 25.27EPCh. 25 - Identify the oxidizing agent needed in Step 3 of a...Ch. 25 - Prob. 25.29EPCh. 25 - Prob. 25.30EPCh. 25 - Prob. 25.31EPCh. 25 - Prob. 25.32EPCh. 25 - Prob. 25.33EPCh. 25 - Prob. 25.34EPCh. 25 - Prob. 25.35EPCh. 25 - Prob. 25.36EPCh. 25 - Prob. 25.37EPCh. 25 - Prob. 25.38EPCh. 25 - Prob. 25.39EPCh. 25 - Prob. 25.40EPCh. 25 - Prob. 25.41EPCh. 25 - Prob. 25.42EPCh. 25 - How many turns of the -oxidation pathway would be...Ch. 25 - How many turns of the -oxidation pathway would be...Ch. 25 - Prob. 25.45EPCh. 25 - Prob. 25.46EPCh. 25 - Prob. 25.47EPCh. 25 - Prob. 25.48EPCh. 25 - Prob. 25.49EPCh. 25 - Explain why fatty acids cannot serve as fuel for...Ch. 25 - Prob. 25.51EPCh. 25 - Prob. 25.52EPCh. 25 - Prob. 25.53EPCh. 25 - Prob. 25.54EPCh. 25 - Prob. 25.55EPCh. 25 - Prob. 25.56EPCh. 25 - Prob. 25.57EPCh. 25 - Prob. 25.58EPCh. 25 - Prob. 25.59EPCh. 25 - Prob. 25.60EPCh. 25 - Prob. 25.61EPCh. 25 - Why does a deficiency of carbohydrates in the diet...Ch. 25 - Prob. 25.63EPCh. 25 - Prob. 25.64EPCh. 25 - Prob. 25.65EPCh. 25 - Prob. 25.66EPCh. 25 - Prob. 25.67EPCh. 25 - Prob. 25.68EPCh. 25 - Prob. 25.69EPCh. 25 - Prob. 25.70EPCh. 25 - Prob. 25.71EPCh. 25 - Prob. 25.72EPCh. 25 - Prob. 25.73EPCh. 25 - Prob. 25.74EPCh. 25 - Prob. 25.75EPCh. 25 - Severe ketosis situations produce acidosis....Ch. 25 - Prob. 25.77EPCh. 25 - Prob. 25.78EPCh. 25 - Prob. 25.79EPCh. 25 - Prob. 25.80EPCh. 25 - Prob. 25.81EPCh. 25 - Prob. 25.82EPCh. 25 - Prob. 25.83EPCh. 25 - Prob. 25.84EPCh. 25 - Prob. 25.85EPCh. 25 - Prob. 25.86EPCh. 25 - Prob. 25.87EPCh. 25 - Prob. 25.88EPCh. 25 - Prob. 25.89EPCh. 25 - Prob. 25.90EPCh. 25 - Prob. 25.91EPCh. 25 - Prob. 25.92EPCh. 25 - Prob. 25.93EPCh. 25 - Prob. 25.94EPCh. 25 - What role does molecular oxygen, O2, play in fatty...Ch. 25 - Prob. 25.96EPCh. 25 - Prob. 25.97EPCh. 25 - Prob. 25.98EPCh. 25 - Prob. 25.99EPCh. 25 - Prob. 25.100EPCh. 25 - Prob. 25.101EPCh. 25 - Prob. 25.102EPCh. 25 - Prob. 25.103EPCh. 25 - Prob. 25.104EPCh. 25 - Prob. 25.105EPCh. 25 - Prob. 25.106EPCh. 25 - Prob. 25.107EPCh. 25 - Prob. 25.108EPCh. 25 - Prob. 25.109EPCh. 25 - Prob. 25.110EPCh. 25 - Prob. 25.111EPCh. 25 - Prob. 25.112EPCh. 25 - Prob. 25.113EPCh. 25 - Prob. 25.114EP
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