Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 25, Problem 29P
A synthesis of triacylglycerols has been described that begins with the substance shown.
Outline a series of reactions suitable for the preparation of a triacylglycerol of the type
illustrated in the equation, where R and R′ are different.
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4. Convert the following structure to a line-angle structure.
H
HH
H
1
H
H
=
H CH
H
CII
H H H
5. Which atom in structure B forms a hydrogen bond with the circled hydrogen in structure
A?
N-H
H
H
+
H
2 N
1 H
CH
Structure A
Structure B
will form H-bonding with circled
8. Assign each chiral center as having either R or S configuration. How many stereoisomers
are possible for this compound?
A
N
CI
HN--->
H
7. If possible, draw the enantiomer of the molecule shown below.
HaComm
H
CH₂OH
CH3
AIRBAG
017
-SET
Chapter 25 Solutions
Organic Chemistry - Standalone book
Ch. 25.2 - What fatty acids are produced on hydrolysis of...Ch. 25.3 - Give the structure of the keto acyl-ACP formed...Ch. 25.4 - Prob. 3PCh. 25.4 - Prob. 4PCh. 25.5 - Prob. 5PCh. 25.6 - Write the structural formula and give the IUPAC...Ch. 25.6 - Prob. 7PCh. 25.7 - Locate the isoprene units in each of the...Ch. 25.7 - Prob. 9PCh. 25.9 - Prob. 10P
Ch. 25.9 - Prob. 11PCh. 25.10 - Prob. 12PCh. 25.11 - Prob. 13PCh. 25.11 - Prob. 14PCh. 25.12 - Prob. 15PCh. 25.16 - Prob. 16PCh. 25 - Prob. 17PCh. 25 - Prob. 18PCh. 25 - Prob. 19PCh. 25 - Pyrethrins are a group of naturally occurring...Ch. 25 - Prob. 21PCh. 25 - Prob. 22PCh. 25 - Prob. 23PCh. 25 - Prob. 24PCh. 25 - Prob. 25PCh. 25 - Prob. 26PCh. 25 - Prob. 27PCh. 25 - Prob. 28PCh. 25 - A synthesis of triacylglycerols has been described...Ch. 25 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - Prob. 32PCh. 25 - Prob. 33DSPCh. 25 - Prob. 34DSPCh. 25 - Prob. 35DSPCh. 25 - Prob. 36DSPCh. 25 - Prob. 37DSPCh. 25 - Prob. 38DSP
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- MBA WAZIMO IMA 4. Convert the following structure to a line-angle structure. Jnem HHHH | \/ HCC CH \/\/\/\/ HOCO Corts bns H:02 HD bis inol296 CC 00005 wlbnd bilegno12 sdt ai rbidWytibios ni bevisa C CH HH / \ // \ HCH H Sytibios evitsisi ni gonsarrow_forwardLT SET 10. Synthesize the following compound beginning with acetylene. You may use any readily available organic or inorganic reactants. Show all steps and all conditions for each step. H CH3 CH اسarrow_forwardA For the best experi Draw the product of the reaction shown below. Ignore inorganic byproducts. + H NaBH4 CH3CH2OH Drawingarrow_forward
- For the best experier Draw the product of the reaction shown below. Ignore inorganic byproducts. + Br 1. LiAlH4 2. H₂O Drawing Drarrow_forwardDraw the following reaction scheme. Include all atoms, bonds, reaction arrows, names, ions, charges, etc. OCH3 H H H methyl acetate QUESTION 2 (5pts): Draw the following compounds. a) b) H H + HÖCH3 methanol CHO HIIII.. C H3C CH₂OHarrow_forwardDraw the following intermediate. Be sure to use curved arrows, rather than straight reaction arrows to show electron movement. OH да QUESTION 4 (10pts): Flip through your textbook. Choose a mechanism and replicate it. Make sure to include all atoms, bonds, reaction arrows, names, ions, charges, curved arrows, etc. Remember mechanisms show the movement of electrons. The curved arrows are important. Some mechanisms you may find: Aldol Condensation Benzilic Acid Rearrangement Clemmensen Reduction Elimination Reaction (E1 or E2) Fischer Indole Synthesis Grignard Reaction Hydroboration-Oxidation Michael Addition Strecker Synthesis Acetoacetic Ester Synthesis Baeyer-Villiger Oxidation Birch Reduction Dieckmann Condensation Oxymercuration-Demercuration Friedel-Crafts Acylation Haloform Reaction Malonic Ester Synthesis Esterification Wittig Reaction Aldol Addition Benzoin Condensation Claisen Condensation Diels-Alder Reaction Epoxidation Friedel-Crafts Alkylation Ene Reaction Mannich Reaction…arrow_forward
- Write the electron configuration of an atom of the element highlighted in this outline of the Periodic Table: 1 2 3 4 LO 5 CO 6 7 Hint: you do not need to know the name or symbol of the highlighted element! He Ne Ar Kr Xe Rn Хarrow_forwardExplain how the polarity of the compounds yields an expected order of elution (Caffeine, Benzoic acid, oxalic acid, salicyclic acid). You will need to bring in structure images of the compounds and explain how the polarity of each compound is relative to one another. Be complete, add as needed.arrow_forwardWhich of the given compounds does not produce benzoic acid when treated with potassium permanganate (KMnO4) in the presence of a strong base and heat? (A) diclorofenilmetanol (B) fenilmetanol (C) 2-fenilheptano (D) 1-fenil heptanolarrow_forward
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Lipids - Fatty Acids, Triglycerides, Phospholipids, Terpenes, Waxes, Eicosanoids; Author: The Organic Chemistry Tutor;https://www.youtube.com/watch?v=7dmoH5dAvpY;License: Standard YouTube License, CC-BY