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Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074

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BuyFindarrow_forward

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074
Textbook Problem

Collision of an electron and a positron results in formation of two γ rays. In the process, their masses are convened completely into energy.

  1. (a) Calculate the energy evolved from the annihilation of an electron and a positron, in kilojoules per mole.
  2. (b) Using Planck’s equation (Equation 6.2), determine the frequency of the γ rays emitted in this process.

(a)

Interpretation Introduction

Interpretation:

Energy evolved from the annihilation of an electron and a positron should be calculated.

Concept introduction:

Mass defect can be calculated using following formula,

Δm = mR- mp

Here

Δm is mass defect for the process

mR is mass for the reactants

mp is mass of the products

Conversion of amu to kJ

  1amu=931.5MeV×(1.602×1010kJ)1MeV

Explanation

Annihilation of an electron and positron gives two gamma rays.

  e10+β+102γ

Mass of electron is 0.00054amu.

Mass of positron is 0.00054amu .

  Δm = mR- mp

Here

  Δm is mass defect for the process

  mR is mass for the reactants

  mp is mass of the products

0.00054amuformR0.00054amuformβ0forγ

Substitute the values in the equation

Δm = (0.0054 + 0

(b)

Interpretation Introduction

Interpretation:

Frequency of the gamma rays should be calculated using Planck’s equation.

Concept introduction:

Planck’s equation is given as:

    E=where, ν=frequencyh=Planck’sconstant

The energy increases as the wavelength of the light decreases.

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