Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 25.5, Problem 12P
Interpretation Introduction

Interpretation:

The pyranose form of glucose is just one of the cyclic forms that glucose can adopt. It’s also possible for the hydroxyl group on C-4 of glucose to attack the aldehyde. This forms a five-membered ring. We call this form the furanose form, in reference to the cyclic 5-membered ether furan.

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(a) Figure 23-2 shows that the degradation of d-glucose gives d-arabinose, an aldopentose.Arabinose is most stable in its furanose form. Draw d-arabinofuranose.(b) Ribose, the C2 epimer of arabinose, is most stable in its furanose form. Drawd-ribofuranose.

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Organic Chemistry

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