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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Chapter
Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

For each of the following pairs of compounds, select the compound that has the higher boiling point.

  1. a. CH3—CH2—CH2—SH or CH3—CH2—CH2—OH
  2. b. CH3—CH2—CH2—SH or CH3—CH2—CH2—CH3

(a)

Interpretation Introduction

Interpretation:

The compound that has higher boiling point among the given pair of compounds has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group.  Alcohols contain both nonpolar and polar groups in it.  Hydroxyl group is the polar group and the alkyl group is the nonpolar group.  Physical properties of alcohol depend on which of the two groups dominate.

Boiling point depends upon hydrogen bonding in alcohols.

Explanation

Alcohols have a hydroxyl group present in its structure.  Thiols have a sulfhydryl group present in it.  The given set of compounds are, CH3CH2CH2SH and CH3CH2CH2OH

(b)

Interpretation Introduction

Interpretation:

The compound that has higher boiling point among the given pair of compounds has to be identified.

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