Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 94SCQ
There are many ionic compounds that dissolve in water to a very small extent. One example is lead(II) chloride. When it dissolves an equilibrium is established between the solid salt and its component ions. Suppose you stir some solid PbCl2 into water. Explain how you would prove that the compound dissolves but to a small extent? Is the dissolving process product-favored or reactant-favored?
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Chapter 3 Solutions
Chemistry & Chemical Reactivity
Ch. 3.2 - (a) Butane gas, C4H10, can burn completely in air...Ch. 3.4 - Predict whether each of the following ionic...Ch. 3.5 - In each of the following cases, does a...Ch. 3.5 - In each of the following cases, aqueous solutions...Ch. 3.6 - Prob. 3.5CYUCh. 3.6 - Prob. 3.6CYUCh. 3.7 - Prob. 3.7CYUCh. 3.8 - Assign an oxidation number to the underlined atom...Ch. 3.8 - Prob. 3.9CYUCh. 3.9 - Prob. 3.10CYU
Ch. 3.9 - Prob. 1.1ACPCh. 3.9 - Prob. 1.2ACPCh. 3.9 - Prob. 1.3ACPCh. 3.9 - Prob. 1.4ACPCh. 3.9 - Prob. 1.5ACPCh. 3.9 - Prob. 2.1ACPCh. 3.9 - Prob. 2.2ACPCh. 3.9 - Prob. 3.1ACPCh. 3.9 - Prob. 3.2ACPCh. 3 - The equation for the oxidation of phosphorus in...Ch. 3 - Write an equation from the following description:...Ch. 3 - The equation for the reaction of phosphorus and...Ch. 3 - The equation for the reaction of aluminum and...Ch. 3 - Oxidation of 1.00 g of carbon monoxide, CO,...Ch. 3 - A 0.20 mol sample of magnesium burns in air to...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Prob. 9PSCh. 3 - Prob. 10PSCh. 3 - Prob. 11PSCh. 3 - Balance the following equations, and name each...Ch. 3 - Prob. 13PSCh. 3 - Prob. 14PSCh. 3 - Equal amounts of two acidsHCl and HCO2H (formic...Ch. 3 - Prob. 16PSCh. 3 - What is an electrolyte? How can you differentiate...Ch. 3 - Name and give the formulas of two acids that are...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - Decide whether each of the following is...Ch. 3 - Decide whether each of the following is...Ch. 3 - Balance the equation for the following...Ch. 3 - Balance the equation for the following...Ch. 3 - Predict the products of each precipitation...Ch. 3 - Prob. 28PSCh. 3 - Write a balanced equation for the ionization of...Ch. 3 - Write a balanced equation for the ionization of...Ch. 3 - Prob. 31PSCh. 3 - Phosphoric add can supply one, two, or three H3O+...Ch. 3 - Prob. 33PSCh. 3 - Prob. 34PSCh. 3 - Prob. 35PSCh. 3 - Prob. 36PSCh. 3 - Prob. 37PSCh. 3 - Prob. 38PSCh. 3 - Write an equation that describes the equilibrium...Ch. 3 - Write an equation that describes the equilibrium...Ch. 3 - Prob. 41PSCh. 3 - Write two chemical equations, one in which H2PO4...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Prob. 45PSCh. 3 - Balance each of the following equations, and then...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Siderite is a mineral consisting largely of...Ch. 3 - The mineral rhodothrosite is manganese()...Ch. 3 - Prob. 51PSCh. 3 - Prob. 52PSCh. 3 - Determine the oxidation number of each element in...Ch. 3 - Determine the oxidation number of each element in...Ch. 3 - Prob. 55PSCh. 3 - Which two of the following reactions are...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - Balance the following equations, and then classify...Ch. 3 - Prob. 60PSCh. 3 - Classify each of the following reactions as a...Ch. 3 - Prob. 62PSCh. 3 - Balance each of the following equations, and...Ch. 3 - Complete and balance the equations below, and...Ch. 3 - Prob. 65PSCh. 3 - Prob. 66PSCh. 3 - Balance the following equations: (a) for the...Ch. 3 - Balance the following equations: (a) for the...Ch. 3 - Prob. 69GQCh. 3 - Give the formula for each of the following...Ch. 3 - Prob. 71GQCh. 3 - Name two anions that combine with Al3+ ion to...Ch. 3 - Write the net ionic equation and identify the...Ch. 3 - Identify and name the water-insoluble product in...Ch. 3 - Bromine is obtained from sea water by the...Ch. 3 - Identify each of the blowing substances as a...Ch. 3 - The mineral dolomite contains magnesium...Ch. 3 - Aqueous solutions of ammonium sulfide, (NH4)2S,...Ch. 3 - Prob. 79GQCh. 3 - Prob. 80GQCh. 3 - Balance equations for these reactions that occur...Ch. 3 - Prob. 82GQCh. 3 - You are given mixtures containing the following...Ch. 3 - Identify, from each list below, the compound or...Ch. 3 - Prob. 85GQCh. 3 - Prob. 86GQCh. 3 - Gas evolution was observed when a solution of Na2S...Ch. 3 - Prob. 89ILCh. 3 - Prob. 90ILCh. 3 - Prob. 91ILCh. 3 - A Suggest a laboratory method for preparing barium...Ch. 3 - The Toliens test for the presence of reducing...Ch. 3 - There are many ionic compounds that dissolve in...Ch. 3 - Most naturally occurring acids are weak acids....Ch. 3 - You want to prepare barium chloride, BaC12, using...Ch. 3 - Prob. 97SCQCh. 3 - A Describe how to prepare zinc chloride by (a) an...Ch. 3 - A common method for analyzing for the nickel...Ch. 3 - The presence of arsenic in a sample that may also...
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- Using the following data, calculate the value of Ksp for Ba(NO3)2, one of the least soluble of the common nitrate salts. Species Gfo Ba2+(aq) 561 KJ/mol NO3(aq) 109 KJ/mol Ba(NO3)2(s) 797KJ/molarrow_forwardUse the solubility product constant from Appendix F to determine whether a precipitate will form if 10.0 mL of 1.0 106 M iron(II) chloride is added to 20.0 mL of 3.0 104 M barium hydroxide.arrow_forwardNeither PbCl2 nor PbF2 is appreciably soluble in water. If solid PbCl2 and solid PbF2 are placed in equal amounts of water in separate beakers, in which beaker is the concentration of Pb2+ greater? Equilibrium constants for these solids dissolving in water are as follows: PbCl2(s) Pb2+(aq) + 2 Cl(aq)Kc = 1.7 105 PbF2(s) Pb2+(aq) + 2 F(aq)Kc = 3.7 108arrow_forward
- The following question is taken from a Chemistry Advanced Placement Examination and is used with the permission of the Educational Testing Service. Solve the following problem: MgF2(s)Mg2+(aq)+2F(aq) In a saturated solution of MgF2 at 18 C, the concentration of Mg2+ is 1.21103M . The equilibrium is represented by the preceding equation. (a) Write the expression for the solubility-product constant, Ksp, and calculate its value at 18 C. (b) Calculate the equilibrium concentration of Mg2+ in 1.000 L of saturated MgF2 solution at 18 C to which 0.100 mol of solid KF has been added. The KF dissolves completely. Assume the volume change is negligible. (c) Predict whether a precipitate of MgF2 will form when 100.0 mL of a 3.00103 -M solution of Mg(NO3)2 is mixed with 200.0 mL of a .2.00103 -M solution of NaF at 18 C. Show the calculations to support your prediction.. (d) At 27 C the concentration of Mg2+ in a saturated solution of MgF2 is 1.17103M . Is the dissolving of MgF2 in water all endothermic or an exothermic process? Give an explanation to support your conclusion.arrow_forwardBecause calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go a step further and examine the equilibrium between carbonate ion and CaCOj. The reaction is Ca2+(aq) + COj2_(aq) ** CaCO,(s) The equilibrium constant for this reaction is 2.1 X 10*. If the initial calcium ion concentration is 0.02 AI and the carbonate concentration is 0.03 AI, what are the equilibrium concentrations of the ions? A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H2COj(aq) H+(aq) + HCO}‘(aq) K = 4.4 X 10"7 She starts with 0.1000 AI carbonic acid. What are the concentrations of all species at equilibrium?arrow_forwardSodium chloride is added to water (at 25C) until it is saturated. Calculate the Cl concentration in such a solution. Species G(kJ/mol) NaCl(s) 384 Na+(aq) 262 Cl(aq) 131arrow_forward
- Calculate equilibrium constants for the following reactions at 208 K. Indicate whether the equilibrium as written is reactant- or product-favored at equilibrium. (a) Co(s) + Ni2+(aq) Co2+(aq) + Ni(s) (b) Fe3+(aq) + Cr2+(aq) Cr3+(aq) + Fe2+(aq)arrow_forwardConsider the system 4 NH3(g) + 3 O2(g) ⇌ 2 N2(g) + 6 H20(ℓ) ΔrH° = −1530.4 kJ/mol How will the amount of ammonia at equilibrium be affected by removing O2(g) without changing the total gas volume? adding N2(g) without changing the total gas volume? adding water without changing the total gas volume? expanding the container? increasing the temperature? Which of these changes (i to v) increases the value of K? Which decreases it?arrow_forward
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