Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
Question
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Chapter 30, Problem 30.11NP

(a)

Interpretation Introduction

Interpretation:The sets have the same energy should be demonstrated.

Concept Introduction:

The formula for calculation total energy is given as:

  E =nεn an ....

Whereas εn is the energy of the nth energy state level.

(b)

Interpretation Introduction

Interpretation:The set which is most probable should be determined

Concept Introduction:Stirling's approximation is an approximate formula, for  n! = 1×2×3× … ×n (n factorial) with weight configuration formula.

Those sets having large value of weight configuration of mass such set is most probable set among all sets.

  W=N!aa! a1.....an!  whereas W is the weight  configuration of mass of set,N is total numbers of oscilator for components and a is occupation number of set configuration.

(c)

Interpretation Introduction

Interpretation: For the most probable set whether the distribution of energy is consistent with the Boltzmann distribution should be determined.

Concept Introduction:

The occupation gap between the energy levels of set C.

  The occupation number is as follows,an=e-PnqWhereas q is the partition function ,an is the occupation number,Pn Probablity of energy levels.

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Chapter 30 Solutions

Physical Chemistry

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