Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 31.SE, Problem 23AP
Show the structure of the
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What monomer(s) would you use to produce the polyester analogous to nylon-6,10?
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Chapter 31 Solutions
Organic Chemistry
Ch. 31.1 - Order the following monomers with respect to their...Ch. 31.1 - Order the following monomers with respect to their...Ch. 31.1 - Prob. 3PCh. 31.2 - Prob. 4PCh. 31.2 - Prob. 5PCh. 31.3 - Prob. 6PCh. 31.3 - Prob. 7PCh. 31.4 - Prob. 8PCh. 31.4 - Show the mechanism of the nucleophilic addition...Ch. 31.5 - Prob. 10P
Ch. 31.6 - Prob. 11PCh. 31.6 - Prob. 12PCh. 31.SE - Prob. 13VCCh. 31.SE - Prob. 14VCCh. 31.SE - Prob. 15MPCh. 31.SE - The polyurethane foam used for home insulation...Ch. 31.SE - Prob. 17MPCh. 31.SE - Prob. 18MPCh. 31.SE - Prob. 19MPCh. 31.SE - Identify the monomer units from which each of the...Ch. 31.SE - Prob. 21APCh. 31.SE - Draw the structure of Kodel, a polyester prepared...Ch. 31.SE - Show the structure of the polymer that results...Ch. 31.SE - Prob. 24APCh. 31.SE - Prob. 25APCh. 31.SE - 1, 3-Cyclopentadiene undergoes thermal...Ch. 31.SE - Prob. 27APCh. 31.SE - Prob. 28APCh. 31.SE - Prob. 29APCh. 31.SE - Prob. 30APCh. 31.SE - Prob. 31APCh. 31.SE - Prob. 32APCh. 31.SE - Prob. 33APCh. 31.SE - Prob. 34APCh. 31.SE - Prob. 35AP
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- Draw a structural formula of the polymer resulting from base-catalyzed polymerization of each compound. Would you expect the polymers to be optically active? (S)-(+)-lactide is the dilactone formed from two molecules of (S)-(+)-lactic acid.arrow_forwardRadical polymerization of styrene gives a linear polymer. Radical polymerization of a mixture of styrene and 1,4-divinylbenzene gives a cross-linked network polymer of the type shown in Figure 29.1. Show by drawing structural formulas how incorporation of a few percent of 1,4-divinylbenzene in the polymerization mixture gives a cross-linked polymer.arrow_forwardShow the first three steps (as far as the tetramer) in the BF3@catalyzed polymerization of propylene to form polypropylene.arrow_forward
- QUESTION1: (this is the full question however can you answer part c,e and f) Methyl methacrylate is polymerized by free radical polymerization at 70 oC to form long polymer chains.(a) Draw the chemical structure of methyl methacrylate, define its molecular formula and molecular weight (in g/mol). (b) If benzoyl peroxide is used as the initiator for the polymerization of methyl methacrylate please write the chemical structures of the compounds formed during the initiation step ofthe polymerization. What would happen if the reaction is not heated at 70 oC? (c) Write the chemical structures of the polymers formed during the propagation and termination steps of the polymerization. (d) Write the trade name of the polymer formed by the polymerization of methyl methacrylate and two of its common applications. (e) If a polymer with degree of polymerization 100 is synthesized during the reaction, determine its molecular weight (in g/mol). (f) If from the polymerization of methyl methacrylate a…arrow_forwarddraw a mechanism for the polymerization of caprolactam to nylon using curved arrows to show the flow of electrons and indicate whether it is a chain reaction or a step-growth reaction.arrow_forwardList the following group of monomers in order of decreasing ability to undergo cationic polymerization.arrow_forward
- >Look at the structures of Vestenamer and Norsorex and show how they might be made by olefin metathesis polymerization.arrow_forwardPolyisobutylene is one of the components of butyl rubber used for making inner tubes. What conditions (cationic, anionic, free-radical) would be most appropriate for polymerization of isobutylene? Explain your answer.arrow_forwardUrylon fibers are used in premium fishing nets because the polymer is relatively stable to UV light and aqueous acid and base. Urylon has the structure shown. Is Urylon a chain-growth polymer or a step-growth polymer?arrow_forward
- (a) Draw the structure of the prepolymer A formed from 1,4-dihydroxybenzene and excess epichlorohydrin. (b) Draw the structure of the cross-linked polymer B formed when A is treated with H2NCH2CH2CH2NH2 as the hardening agent.arrow_forwardEpoxy adhesives are prepared in two steps. SN2 reaction of the disodium salt of bisphenol A with epichlorohydrin forms a prepolymer, which is then cured by treatment with a triamine such as H2NCH2CH2NHCH2CH2NH2. Draw structures to show how addition of the triamine results in a strengthening of the polymer.arrow_forward
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