Fundamentals of Chemical Engineering Thermodynamics (MindTap Course List)
Fundamentals of Chemical Engineering Thermodynamics (MindTap Course List)
1st Edition
ISBN: 9781111580704
Author: Kevin D. Dahm, Donald P. Visco
Publisher: Cengage Learning
Question
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Chapter 3.9, Problem 21P

(A)

Interpretation Introduction

Interpretation:

Determine the fraction of initial contents (qin) of the vessel were in the vapor phase

Concept Introduction:

The expression to calculate the initial specific volume (V^in) of vessel.

V^in=VMin

Here, volume of vessel is V and initial mass in vessel is M.

The expression to calculate the fraction of initial contents (qin) of the vessel were in the vapor phase.

V^in=(1qin)V^L+qinV^V

Here, specific volume in liquid phase is V^L and specific volume in vapor phase is V^V.

(B)

Interpretation Introduction

Interpretation:

Determine the fraction of final contents (qfinal) of the vessel is in the vapor phase

Concept Introduction:

The expression to determine the final specific volume (V^final) of vessel.

V^final=VM

Here, volume of vessel is V, and total mass is M.

The expression to calculate the fraction of initial contents (qin) of the vessel were in the vapor phase.

V^in=(1qin)V^L+qinV^V

Here, specific volume in liquid phase is V^L and specific volume in vapor phase is V^V.

(C)

Interpretation Introduction

Interpretation:

Determine the heat removed (Q) from the system

Concept Introduction:

The steady state energy balance equation for the heat exchanger.

Δ{M(U^+V22+gh)}=[j=1j=J{mj,in(H^j+Vj22+ghj)}k=1k=K{mk,out(H^k+Vk22+ghk)}+WEC+WS+Q]

Here, total mass is M, specific internal energy is U^, velocity is V, acceleration due to gravity is g, height is h, individual quantities of mass added to and removed from the process are mj,inandmk,out respectively, initial specific enthalpy are H^j, final specific enthalpy is H^k, initial velocity is Vj, final velocity is Vk, initial height of the gas is hj, final height of the gas is hk, shaft work is added to the system is WS, work is added to the system through expansion or contraction of the system is WEC, and heat is added to the system is Q.

Write the expression to calculate the initial specific internal energy (U^initial).

U^initial=(1qin)U^L+qinU^V

Here, specific internal energy in liquid phase is U^L, and specific internal energy in phase is U^V.

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