Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap
Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap
8th Edition
ISBN: 9780134581064
Author: Bruice, Paula Yurkanis
Publisher: Prentice Hall
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Textbook Question
Chapter 4, Problem 1P

a. Draw three constitutional isomers with molecular formula C3H8O.

b. How many constitutional isomers can you draw for C4H10.O?

(a)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The three constitutional isomers of molecular formula C3H8O has to be drawn.

Concept introduction:

Constitutional isomers are having the same molecular formula and different bond connectivity between the atoms.

The general formula for an alkane is CnH2n+2.

Equation for finding constitutional isomers for a molecule

Answer to Problem 1P

Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap, Chapter 4, Problem 1P , additional homework tip  1

Explanation of Solution

The given molecular formula is C3H8O, it fulfils the general formula for an alkane CnH2n+2, so C3H8O contains only single bonds.

Therefore,

C3H8O can be an alcohol or ether.

The two possible alcohols are,

CH3CH2CH2OH , Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap, Chapter 4, Problem 1P , additional homework tip  2

The possible ether is,

CH3CH2OCH3

(b)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The numbers of constitutional isomers of molecular formula C4H10O has to be determined.

Concept introduction:

Constitutional isomers are having the same molecular formula and different bond connectivity between the atoms.

Answer to Problem 1P

The numbers of constitutional isomers of molecular formula C4H10O is 7

Explanation of Solution

The given molecular formula is C4H10O, it fulfils the general formula for an alkane CnH2n+2, so C4H10O contains only single bonds.

Therefore,

C4H10O can be an alcohol or ether.

There will be five alcohol isomers (due to four carbons) and two ether isomers.

Hence,

C4H10O have 7 constitutional isomers.

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Chapter 4 Solutions

Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap

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