Science
ChemistryPhysical ChemistryUse equation 4.25 to argue that the Gibbs energy always increases as the pressure increases while at constant T .

Use equation 4.25 to argue that the Gibbs energy always increases as the pressure increases while at constant T .

BuyFind

Physical Chemistry

2nd Edition
Ball + 3 others
Publisher: Wadsworth Cengage Learning,
ISBN: 9781133958437
BuyFind

Physical Chemistry

2nd Edition
Ball + 3 others
Publisher: Wadsworth Cengage Learning,
ISBN: 9781133958437

Solutions

Chapter
Section
Problem 4.1E
Problem 4.2E
Problem 4.3E
Problem 4.4E
Problem 4.5E
Problem 4.6E
Problem 4.7E
Problem 4.8E
Problem 4.9E
Problem 4.10E
Problem 4.11E
Problem 4.12E
Problem 4.13E
Problem 4.14E
Problem 4.15E
Problem 4.16E
Problem 4.17E
Problem 4.18E
Problem 4.19E
Problem 4.20E
Problem 4.21E
Problem 4.22E
Problem 4.23E
Problem 4.24E
Problem 4.25E
Problem 4.26E
Problem 4.27E
Problem 4.28E
Problem 4.29E
Problem 4.30E
Problem 4.31E
Problem 4.32E
Problem 4.33E
Problem 4.34E
Problem 4.35E
Problem 4.36E
Problem 4.37E
Problem 4.38E
Problem 4.39E
Problem 4.40E
Problem 4.41E
Problem 4.42E
Problem 4.43E
Problem 4.44E
Problem 4.45E
Problem 4.46E
Problem 4.47E
Problem 4.48E
Problem 4.49E
Problem 4.50E
Problem 4.51E
Problem 4.52E
Problem 4.53E
Problem 4.54E
Problem 4.55E
Problem 4.56E
Problem 4.57E
Problem 4.58E
Problem 4.59E
Problem 4.60E
Problem 4.61E
Problem 4.62E
Problem 4.63E
Problem 4.64E
Problem 4.65E
Problem 4.66E
Problem 4.67E
Problem 4.68E
Problem 4.69E
Problem 4.70E
Problem 4.71E
Problem 4.72E
Problem 4.73E
Problem 4.74E
Problem 4.75E
Problem 4.76E
Chapter 4, Problem 4.32E
Textbook Problem

Use equation 4.25 to argue that the Gibbs energy always increases as the pressure increases while at constant T .

Expert Solution

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Chapter 4,
Problem 4.31E
Chapter 4,
Problem 4.33E

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Chapter 4 Solutions

Physical Chemistry
Ch. 4 - List the sets of conditions that allow dS, dU, and...Ch. 4 - Explain why conditions for using S>0 as a strict...Ch. 4 - Explain how the equation dU+pdVTdS0 is consistent...Ch. 4 - Explain why the spontaneity conditions given in...Ch. 4 - Prove that the adiabatic free expansion of an...Ch. 4 - Derive equation 4.6 from equation 4.5.Ch. 4 - Derive equation 4.8 from equation 4.7.Ch. 4 - The third part of equation 4.9 mentions a...Ch. 4 - Calculate A for a process in which 0.160mole of an...Ch. 4 - What is the maximum amount of non-pV work that can...
Ch. 4 - Consider a piston whose compression ratio is 10:1;...Ch. 4 - When one dives, water pressure increases by 1atm...Ch. 4 - Calculate G(25C) for this chemical reaction, which...Ch. 4 - Thermodynamic properties can also be determined...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - For the reaction C(graphite)C(diamond) at 25C,...Ch. 4 - Determine G for the following reaction at 0C and...Ch. 4 - What is the maximum amount of electrical that is,...Ch. 4 - When a person performs work, it is non-pV work....Ch. 4 - Can non-pV work be obtained from a process for...Ch. 4 - Can pV work be obtained from a process for which...Ch. 4 - Batteries are chemical systems that can be used to...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - Under what conditions is A=0 for a phase change?...Ch. 4 - Example 4.2 calculated A for one step of a Carnot...Ch. 4 - Can CV and Cp be easily defined using the natural...Ch. 4 - Analogous to equation 4.26, what is the expression...Ch. 4 - Show that dS=dV+(S/p)V(S/p)VdT where is the...Ch. 4 - Show that the units in equations 4.18-4.25 are...Ch. 4 - Use equation 4.25 to argue that the Gibbs energy...Ch. 4 - Although ideally, U=H=0 for a gas-phase process at...Ch. 4 - Use equations 4.21 and 4.25 to explain why H and G...Ch. 4 - Derive equations 4.35-4.37.Ch. 4 - Which of the following functions are exact...Ch. 4 - Show that (S/p)T=V.Ch. 4 - Starting with the natural variable equation for...Ch. 4 - When changes in the conditions of a system are...Ch. 4 - Equation 4.19 says that (UV)S=p If we are...Ch. 4 - For an isentropic process, what is the approximate...Ch. 4 - Use the ideal gas law to demonstrate the cyclic...Ch. 4 - Show that for an ideal gas, [Cp(UT)p(Hp)S(pT)V]=0Ch. 4 - Show that (VS)T=1 where is the expansion...Ch. 4 - Evaluate (U/V)T for an ideal gas. Use the...Ch. 4 - Evaluate (U/V)T for a van der Waals gas. Use the...Ch. 4 - Repeat the previous exercise for a gas that...Ch. 4 - Determine an expression for (p/S)T for an ideal...Ch. 4 - Determine the value of the derivative {[(G)]/T}p...Ch. 4 - Derive the equivalent of the Gibbs-Helmholtz...Ch. 4 - A plot of 1/T versus G/T has what slope?Ch. 4 - A 0.988-mole sample of argon expands from 25.0L to...Ch. 4 - A 3.66-mol sample of He contracts from 15.5L to...Ch. 4 - Verify the manipulation of equation 4.41 into...Ch. 4 - Verify that you can get equation 4.44 from...Ch. 4 - Use the Gibbs-Helmholtz equation to demonstrate...Ch. 4 - For the equation 2H2(g)+O2(g)2H2O(g)...Ch. 4 - Use equation 4.46 as an example and find an...Ch. 4 - What is the value of G when 1.00mol of water at...Ch. 4 - a For 1.00molH2O at 25C see previous exercise,...Ch. 4 - Propose a form of the Gibbs-Helmholtz equation for...Ch. 4 - Like the entropy of mixing, a Gibbs energy of...Ch. 4 - Why is there no n variable in equation 4.55 like...Ch. 4 - What does (T)p equal? Hint: See equation 4.40.Ch. 4 - What is the change in the chemical potential of a...Ch. 4 - Is an extensive or intensive variable? What about...Ch. 4 - Write the fundamental equation of chemical...Ch. 4 - Calculate the molar change in chemical potential...Ch. 4 - Calculate the change in chemical potential of an...Ch. 4 - Can equation 4.62 be used to calculate for an...Ch. 4 - Which, if either, in each pair of systems do you...Ch. 4 - Of helium and oxygen gases, which one do you...Ch. 4 - Suppose a gas has an equation of state that...Ch. 4 - Use equation 4.39 to determine a numerical value...Ch. 4 - The following table lists the compressibilities of...Ch. 4 - Consider 1.00mol total of two gases A and B....

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