Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Concept explainers

Question
Chapter 4, Problem 4.32EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

  • • The longest parent carbon chain is identified that includes the carbonyl group.
  • • The parent chain name is changed by replacing the suffix “-e” with “-one”.
  • • Numbering is done in a way that the carbonyl group gets the least numbering.  The position of the carbonyl group is indicated in the name.
  • • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
  • • Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring.  The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

  • • The longest parent carbon chain is identified that includes the carbonyl group.
  • • The parent chain name is changed by replacing the suffix “-e” with “-one”.
  • • Numbering is done in a way that the carbonyl group gets the least numbering.  The position of the carbonyl group is indicated in the name.
  • • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
  • • Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring.  The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

  • • The longest parent carbon chain is identified that includes the carbonyl group.
  • • The parent chain name is changed by replacing the suffix “-e” with “-one”.
  • • Numbering is done in a way that the carbonyl group gets the least numbering.  The position of the carbonyl group is indicated in the name.
  • • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
  • • Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring.  The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

  • • The longest parent carbon chain is identified that includes the carbonyl group.
  • • The parent chain name is changed by replacing the suffix “-e” with “-one”.
  • • Numbering is done in a way that the carbonyl group gets the least numbering.  The position of the carbonyl group is indicated in the name.
  • • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
  • • Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring.  The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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Chapter 4 Solutions

Organic And Biological Chemistry

Ch. 4.4 - Prob. 3QQCh. 4.4 - Prob. 4QQCh. 4.4 - Prob. 5QQCh. 4.5 - Prob. 1QQCh. 4.5 - Prob. 2QQCh. 4.5 - Prob. 3QQCh. 4.5 - Prob. 4QQCh. 4.5 - Prob. 5QQCh. 4.6 - Prob. 1QQCh. 4.6 - Prob. 2QQCh. 4.6 - Prob. 3QQCh. 4.7 - Prob. 1QQCh. 4.7 - Prob. 2QQCh. 4.8 - Prob. 1QQCh. 4.8 - Prob. 2QQCh. 4.9 - Prob. 1QQCh. 4.9 - Prob. 2QQCh. 4.10 - Prob. 1QQCh. 4.10 - Prob. 2QQCh. 4.10 - Prob. 3QQCh. 4.10 - Prob. 4QQCh. 4.11 - Prob. 1QQCh. 4.11 - Prob. 2QQCh. 4.11 - Prob. 3QQCh. 4.11 - Prob. 4QQCh. 4.11 - Prob. 5QQCh. 4.12 - Prob. 1QQCh. 4.12 - Prob. 2QQCh. 4 - Prob. 4.1EPCh. 4 - Prob. 4.2EPCh. 4 - Prob. 4.3EPCh. 4 - In terms of polarity, which carbonyl group atom...Ch. 4 - Prob. 4.5EPCh. 4 - Prob. 4.6EPCh. 4 - Prob. 4.7EPCh. 4 - Prob. 4.8EPCh. 4 - Prob. 4.9EPCh. 4 - Prob. 4.10EPCh. 4 - Prob. 4.11EPCh. 4 - Classify each of the following structures as an...Ch. 4 - Prob. 4.13EPCh. 4 - Prob. 4.14EPCh. 4 - Prob. 4.15EPCh. 4 - Prob. 4.16EPCh. 4 - Prob. 4.17EPCh. 4 - Prob. 4.18EPCh. 4 - Prob. 4.19EPCh. 4 - Prob. 4.20EPCh. 4 - Prob. 4.21EPCh. 4 - Prob. 4.22EPCh. 4 - Prob. 4.23EPCh. 4 - Prob. 4.24EPCh. 4 - Prob. 4.25EPCh. 4 - Prob. 4.26EPCh. 4 - Prob. 4.27EPCh. 4 - Prob. 4.28EPCh. 4 - Name the functional group(s) present in each of...Ch. 4 - Prob. 4.30EPCh. 4 - Prob. 4.31EPCh. 4 - Prob. 4.32EPCh. 4 - Prob. 4.33EPCh. 4 - Prob. 4.34EPCh. 4 - Prob. 4.35EPCh. 4 - Prob. 4.36EPCh. 4 - Draw a structural formula for each of the...Ch. 4 - Prob. 4.38EPCh. 4 - Prob. 4.39EPCh. 4 - Prob. 4.40EPCh. 4 - Draw a structural formula for each of the...Ch. 4 - Prob. 4.42EPCh. 4 - Prob. 4.43EPCh. 4 - Name the functional group(s) present in each of...Ch. 4 - Prob. 4.45EPCh. 4 - Prob. 4.46EPCh. 4 - Prob. 4.47EPCh. 4 - Prob. 4.48EPCh. 4 - Prob. 4.49EPCh. 4 - Give IUPAC names for all saturated...Ch. 4 - Prob. 4.51EPCh. 4 - Prob. 4.52EPCh. 4 - Prob. 4.53EPCh. 4 - Prob. 4.54EPCh. 4 - Prob. 4.55EPCh. 4 - Prob. 4.56EPCh. 4 - Prob. 4.57EPCh. 4 - Prob. 4.58EPCh. 4 - Prob. 4.59EPCh. 4 - Prob. 4.60EPCh. 4 - Prob. 4.61EPCh. 4 - Prob. 4.62EPCh. 4 - Prob. 4.63EPCh. 4 - Prob. 4.64EPCh. 4 - Which member in each of the following pairs of...Ch. 4 - Prob. 4.66EPCh. 4 - Which member in each of the following pairs of...Ch. 4 - Prob. 4.68EPCh. 4 - Prob. 4.69EPCh. 4 - How many hydrogen bonds can form between an...Ch. 4 - Prob. 4.71EPCh. 4 - Prob. 4.72EPCh. 4 - Draw the structure of the alcohol needed to...Ch. 4 - Prob. 4.74EPCh. 4 - Prob. 4.75EPCh. 4 - Prob. 4.76EPCh. 4 - Prob. 4.77EPCh. 4 - Prob. 4.78EPCh. 4 - Prob. 4.79EPCh. 4 - Prob. 4.80EPCh. 4 - Prob. 4.81EPCh. 4 - Which of the following compounds would react with...Ch. 4 - Prob. 4.83EPCh. 4 - Prob. 4.84EPCh. 4 - Which of the three compounds pentanal,...Ch. 4 - Prob. 4.86EPCh. 4 - Prob. 4.87EPCh. 4 - Prob. 4.88EPCh. 4 - Prob. 4.89EPCh. 4 - Prob. 4.90EPCh. 4 - Prob. 4.91EPCh. 4 - Indicate whether each of the following compounds...Ch. 4 - Which carbon atom is the hemiacetal carbon atom in...Ch. 4 - Which carbon atom is the hemiacetal carbon atom in...Ch. 4 - Prob. 4.95EPCh. 4 - Prob. 4.96EPCh. 4 - Prob. 4.97EPCh. 4 - Prob. 4.98EPCh. 4 - Prob. 4.99EPCh. 4 - Indicate whether each of the following compounds...Ch. 4 - Prob. 4.101EPCh. 4 - Prob. 4.102EPCh. 4 - Prob. 4.103EPCh. 4 - Prob. 4.104EPCh. 4 - Prob. 4.105EPCh. 4 - Prob. 4.106EPCh. 4 - Prob. 4.107EPCh. 4 - Name each of the compounds in Problem 15-106 in...Ch. 4 - Prob. 4.109EPCh. 4 - Prob. 4.110EPCh. 4 - Prob. 4.111EPCh. 4 - Prob. 4.112EPCh. 4 - Prob. 4.113EPCh. 4 - Prob. 4.114EPCh. 4 - Prob. 4.115EPCh. 4 - Prob. 4.116EPCh. 4 - Prob. 4.117EPCh. 4 - Prob. 4.118EP
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