Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 4.2, Problem 4TY
Interpretation Introduction

Interpretation:

Whether the difference in standard deviations of the two sets each of which have 13 replications is significant or not has to be explained.

Concept Introduction:

Comparison of Standard Deviation with F Test:

For the comparison of mean values of two sets of measurements, we decide whether the standard deviations of the two sets are “statistically different”. This is done by F test.

The F test with quotient F is given as:

Fcalculated=s12s22

Where, s1 and s2 are standard deviations for the set of measurements using original instrument and substitute instrument. Always consider larger standard deviation in the numerator.

If Fcalculated>Ftable , then the difference is significant.

Degrees of Freedom:

For a n set of measurement, the degrees of freedom will be (n1)

To Explain: Whether the difference in standard deviations of the two sets each of which have 13 replications is significant or not

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