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Organic Chemistry

9th Edition
John E. McMurry
Publisher: Cengage Learning
ISBN: 9781305080485

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BuyFindarrow_forward

Organic Chemistry

9th Edition
John E. McMurry
Publisher: Cengage Learning
ISBN: 9781305080485
Chapter 4.SE, Problem 24VC
Textbook Problem
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A trisubstituted cyclohexane with three substituents-red, green, and blue-undergoes a ring-flip to its alternate chair conformation. Identify each substituent as axial or equatorial, and show the positions occupied by the three substituents in the ring-flipped form.

Chapter 4.SE, Problem 24VC, A trisubstituted cyclohexane with three substituents-red, green, and blue-undergoes a ring-flip to

Interpretation Introduction

Interpretation:

The position of each substituent in cyclohexane is to be determined before and after flipping of the ring.

Concept introduction:

Organic Chemistry, Chapter 4.SE, Problem 24VC , additional homework tip  1

The position of substituent prior to cyclohexane is to be determined.

Organic Chemistry, Chapter 4.SE, Problem 24VC , additional homework tip  2

The position of substituent after ring flip is to be determined.

Explanation of Solution

The position of each substituent in cyclohexane is to be identified as axial or equatorial and after ring...

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Chapter 4 Solutions

Organic Chemistry
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Ch. 4.4 - Two conformations of cis-l, 3-dimethylcyclobutane...Ch. 4.6 - Draw two different chair conformations of...Ch. 4.6 - Draw two differant chair conformations of trans-1,...Ch. 4.6 - Identify each of the colored positions-red, blue,...Ch. 4.7 - What is the energy difference between the axial...Ch. 4.7 - Why do you suppose an axial cyano (-CN)...Ch. 4.7 - Look at Figure 4-12 on page 105, and estimate the...Ch. 4.8 - Draw the more stable chair conformation of the...Ch. 4.8 - Identify each substituent in the following...Ch. 4.9 - Which isomer is more stable, cis-decalin or...Ch. 4.9 - Look at the following structure of the female...Ch. 4.SE - Name the following cycloalkanes:Ch. 4.SE - Name the following compound, identify each...Ch. 4.SE - A trisubstituted cyclohexane with three...Ch. 4.SE - The following cyclohexane derivative has three...Ch. 4.SE - Glucose exists in two forms having a 36:64 ratio...Ch. 4.SE - Draw the five cycloalkanes with the formula C5H10.Ch. 4.SE - Draw two constitutional isomers of cis-1,...Ch. 4.SE - Draw a stereoisomer of trans-1,...Ch. 4.SE - Tell whether the following pairs of compounds are...Ch. 4.SE - Identify each pair of relationships among the -OH...Ch. 4.SE - Identify each pair of relationships among the -OH...Ch. 4.SE - Draw 1, 3, 5-trimethylcyclohexane using a hexagon...Ch. 4.SE - Hydrocortisone, a naturally occurring hormone...Ch. 4.SE - A 1, 2-cis disubstituted cyclohexane, such as...Ch. 4.SE - A 1, 2-trans disubstituted cyclohexane must have...Ch. 4.SE - Why is a l, 3-cis disubstituted cyclohexane more...Ch. 4.SE - Which is more stable, a 1, 4-trans disubstituted...Ch. 4.SE - cis-1, 2-Dimethylcyclobutane is less stable than...Ch. 4.SE - From the data in Figure 4-12 and Table 4-1,...Ch. 4.SE - Assume that you have a variety of cyclohexanes...Ch. 4.SE - Draw the two chair conformations of...Ch. 4.SE - Draw the two chair conformations of...Ch. 4.SE - Galactose, a sugar related to glucose, contains a...Ch. 4.SE - There are four cis-trans isomers of menthol...Ch. 4.SE - There are four cis-trans isomers of menthol...Ch. 4.SE - The diaxial conformation of cis-1,...Ch. 4.SE - Approximately how much steric strain does the...Ch. 4.SE - In light of your answer to Problem 4-43, draw the...Ch. 4.SE - One of the two chair structures of...Ch. 4.SE - We saw in Problem 4-20 that cis-decalin is less...Ch. 4.SE - Using molecular models as well as structural...Ch. 4.SE - trans-Decalin is more stable than its cis isomer,...Ch. 4.SE - As mentioned in Problem 3-53, the statin drugs,...Ch. 4.SE - myo-Inositol, one of the isomers of...Ch. 4.SE - How many cis–trans stereoisomers of myo-inositol...Ch. 4.SE - The German chemist J. Bredt proposed in 1935 that...Ch. 4.SE - Tell whether each of the following substituents on...Ch. 4.SE - Amantadine is an antiviral agent that is active...Ch. 4.SE - Heres a difficult one. There are two different...Ch. 4.SE - Ketones react with alcohols to yield products...Ch. 4.SE - Alcohols undergo an oxidation reaction to yield...

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