Chemistry: The Molecular Nature of Matter and Change
Chemistry: The Molecular Nature of Matter and Change
8th Edition
ISBN: 9781259631757
Author: Martin Silberberg Dr., Patricia Amateis Professor
Publisher: McGraw-Hill Education
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Concept explainers

Question
Chapter 5, Problem 5.1P

(a)

Interpretation Introduction

Interpretation:

The difference in the behaviour of a sample of gas from a sample of liquids when the sample is transferred from one container to a larger one is to be explained.

Concept introduction:

Gases have weak intramolecular forces of attraction in comparison to liquids. The weak intramolecular forces lead to very less attraction among the gaseous particles resulting in its free motion.

Liquids have stronger intramolecular forces of attraction than gases and this property of liquids make it highly fluid in nature.

(a)

Expert Solution
Check Mark

Answer to Problem 5.1P

The volume of the liquids has definite volume while the volume of gases doesn’t have a fixed volume. This is so because the volume of gas is dependent on the volume of the containers.

Explanation of Solution

The molecule of the gas moves more freely than the solid and liquids. The gas doesn’t have a definite shape and volume. The liquids have a definite volume but don’t have a fixed shape.

The volume of the gas is dependent on the volume of the containers, the volume of gas is increased as the volume of the containers increases while the liquids have fixed volume. This is so because the intermolecular forces between the gaseous molecules are weaker so, the molecules are move very fast than liquids molecules.

Conclusion

The volume of gases doesn’t have a fixed volume but the volume of liquids have a definite volume.

(b)

Interpretation Introduction

Interpretation:

The difference in the behaviour of a sample of gas from a sample of liquids when the sample heated in an expandable container is to be explained.

Concept introduction:

Gases have weak intramolecular forces of attraction in comparison to liquids. The weak intramolecular forces lead to very less attraction among the gaseous particles resulting in its free motion.

Liquids have stronger intramolecular forces of attraction than gases and this property of liquids make it highly fluid in nature.

The volume of the gas is dependent on the temperature, as the temperature increases the volume increase.

(b)

Expert Solution
Check Mark

Answer to Problem 5.1P

If the sample of gas is rapidly heated in the expandable container, the volume of the gas is increased but the volume of the liquids molecule will be the same.

Explanation of Solution

The gas volume will be changed significantly with temperature. When a sample of gas is rapidly heated, the volume of expandable containers having the gas is increased. This is so because the speed of the molecule is increased and result in more collision on the wall of the container. More the collisions on the container wall, more will be the pressure exerted by the gas particles. This results to increase the volume of the gas.

When a sample of liquid is rapidly heated, the volume of expandable containers having liquids will not be changed.

Conclusion

As temperature increases, the volume of expandable containers having the gas is increased.

(c)

Interpretation Introduction

Interpretation:

The difference in the behaviour of a sample of gas from a sample of liquids when the external force applied to the piston of an expandable container is to be explained.

Concept introduction:

Gases have weak intramolecular forces of attraction in comparison to liquids. The weak intramolecular forces lead to very less attraction among the gaseous particles resulting in its free motion.

Liquids have stronger intramolecular forces of attraction than gases and this property of liquids make it highly fluid in nature.

The volume of the gas is inversely proportional to the pressure, as the pressure increases the volume decrease.

(c)

Expert Solution
Check Mark

Answer to Problem 5.1P

As the pressure increases, the volume of the gas decreases while the volume of the liquid will be the same.

Explanation of Solution

The gas volume will be changed significantly with pressure. The sample of gas is present in the cylinder with a piston, as the external force applied on the piston increases, the volume of gas decreases. This is so because gases are compressible. As the pressure increases, the volume of the liquids doesn’t change because the liquids are incompressible.

Conclusion

Gases are compressible and the liquids are incompressible.

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Chapter 5 Solutions

Chemistry: The Molecular Nature of Matter and Change

Ch. 5.3 - Prob. 5.6AFPCh. 5.3 - A blimp is filled with 3950 kg of helium at 731...Ch. 5.3 - Prob. 5.7AFPCh. 5.3 - Prob. 5.7BFPCh. 5.4 - Prob. 5.8AFPCh. 5.4 - Prob. 5.8BFPCh. 5.4 - Prob. 5.9AFPCh. 5.4 - Prob. 5.9BFPCh. 5.4 - To prevent air from interacting with highly...Ch. 5.4 - Prob. 5.10BFPCh. 5.4 - Prob. 5.11AFPCh. 5.4 - Prob. 5.11BFPCh. 5.4 - Prob. 5.12AFPCh. 5.4 - Prob. 5.12BFPCh. 5.4 - Ammonia and hydrogen chloride gases react to form...Ch. 5.4 - Prob. 5.13BFPCh. 5.5 - If it takes 1.25 min for 0.010 mol of He to...Ch. 5.5 - If 7.23 mL of an unknown gas effuses in the same...Ch. 5.5 - Prob. B5.1PCh. 5.5 - Prob. B5.2PCh. 5.5 - Prob. B5.3PCh. 5.5 - Prob. B5.4PCh. 5 - Prob. 5.1PCh. 5 - Prob. 5.2PCh. 5 - Prob. 5.3PCh. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - Prob. 5.8PCh. 5 - Prob. 5.9PCh. 5 - In Figure P5.10, what is the pressure of the gas...Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - The gravitational force exerted by an object is...Ch. 5 - Prob. 5.16PCh. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - What is the effect of the following on volume of 1...Ch. 5 - Prob. 5.21PCh. 5 - Prob. 5.22PCh. 5 - What is the effect of the following on the volume...Ch. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Prob. 5.26PCh. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - Prob. 5.31PCh. 5 - Prob. 5.32PCh. 5 - Prob. 5.33PCh. 5 - Prob. 5.34PCh. 5 - Prob. 5.35PCh. 5 - You have 357 mL of chlorine trifluoride gas at 699...Ch. 5 - Prob. 5.37PCh. 5 - Prob. 5.38PCh. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Prob. 5.49PCh. 5 - Prob. 5.50PCh. 5 - After 0.600 L of Ar at 1.20 atm and 227°C is mixed...Ch. 5 - A 355-mL container holds 0.146 g of Ne and an...Ch. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - How many liters of hydrogen gas are collected over...Ch. 5 - Prob. 5.59PCh. 5 - Prob. 5.60PCh. 5 - Prob. 5.61PCh. 5 - Prob. 5.62PCh. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Freon-12 (CF2C12), widely used as a refrigerant...Ch. 5 - Prob. 5.66PCh. 5 - Prob. 5.67PCh. 5 - Prob. 5.68PCh. 5 - Prob. 5.69PCh. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Prob. 5.73PCh. 5 - Prob. 5.74PCh. 5 - Prob. 5.75PCh. 5 - Prob. 5.76PCh. 5 - Prob. 5.77PCh. 5 - Prob. 5.78PCh. 5 - Prob. 5.79PCh. 5 - Prob. 5.80PCh. 5 - Prob. 5.81PCh. 5 - Prob. 5.82PCh. 5 - Prob. 5.83PCh. 5 - Do interparticle attractions cause negative or...Ch. 5 - Prob. 5.85PCh. 5 - Prob. 5.86PCh. 5 - Prob. 5.87PCh. 5 - Prob. 5.88PCh. 5 - Prob. 5.89PCh. 5 - Prob. 5.90PCh. 5 - Prob. 5.91PCh. 5 - Prob. 5.92PCh. 5 - Prob. 5.93PCh. 5 - Prob. 5.94PCh. 5 - Prob. 5.95PCh. 5 - Prob. 5.96PCh. 5 - Prob. 5.97PCh. 5 - Prob. 5.98PCh. 5 - Prob. 5.99PCh. 5 - Prob. 5.100PCh. 5 - Prob. 5.101PCh. 5 - Prob. 5.102PCh. 5 - Prob. 5.103PCh. 5 - Prob. 5.104PCh. 5 - Prob. 5.105PCh. 5 - An atmospheric chemist studying the pollutant SO2...Ch. 5 - The thermal decomposition of ethylene occurs...Ch. 5 - Prob. 5.108PCh. 5 - Prob. 5.109PCh. 5 - Prob. 5.110PCh. 5 - Prob. 5.111PCh. 5 - Prob. 5.112PCh. 5 - Containers A, B and C are attached by closed...Ch. 5 - Prob. 5.114PCh. 5 - Prob. 5.115PCh. 5 - Prob. 5.116PCh. 5 - Prob. 5.117PCh. 5 - Prob. 5.118PCh. 5 - Prob. 5.119PCh. 5 - Prob. 5.120PCh. 5 - Prob. 5.121PCh. 5 - Prob. 5.122PCh. 5 - Prob. 5.123PCh. 5 - Prob. 5.124PCh. 5 - Prob. 5.125PCh. 5 - For each of the following, which shows the greater...Ch. 5 - Prob. 5.127PCh. 5 - Prob. 5.128PCh. 5 - Prob. 5.129PCh. 5 - Prob. 5.130PCh. 5 - Prob. 5.131PCh. 5 - Gases such as CO are gradually oxidized in the...Ch. 5 - Aqueous sulfurous acid (H2SO3) was made by...Ch. 5 - Prob. 5.134PCh. 5 - Prob. 5.135PCh. 5 - The lunar surface reaches 370 K at midday. The...Ch. 5 - Prob. 5.137PCh. 5 - Popcorn pops because the horny endosperm, a...Ch. 5 - Prob. 5.139PCh. 5 - Prob. 5.140PCh. 5 - Prob. 5.141PCh. 5 - Prob. 5.142PCh. 5 - Prob. 5.143PCh. 5 - Prob. 5.144PCh. 5 - Prob. 5.145PCh. 5 - Prob. 5.146PCh. 5 - Prob. 5.147PCh. 5 - Prob. 5.148PCh. 5 - An equimolar mixture of Ne and Xe is accidentally...Ch. 5 - Prob. 5.150PCh. 5 - A slight deviation from ideal behavior exists even...Ch. 5 - In preparation for a combustion demonstration, a...Ch. 5 - Prob. 5.153PCh. 5 - A truck tire has a volume of 218 L and is filled...Ch. 5 - Allotropes are different molecular forms of an...Ch. 5 - Prob. 5.156P
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