Concept explainers
Which system in each pair best represents equilibrium species under standard conditions of temperature and pressure? You may have to apply some basic knowledge of chemistry.
(a)
(b)
(c)
(d)
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Physical Chemistry
- At a certain temperature, K=0.29 for the decomposition of two moles of iodine trichloride, ICl3(s), to chlorine and iodine gases. The partial pressure of chlorine gas at equilibrium is three times that of iodine gas. What are the partial pressures of iodine and chlorine at equilibrium?arrow_forwardDescribe a nonchemical system that is not in equilibrium, and explain why equilibrium has not been achieved.arrow_forwardFor the system 2SO3(g)2SO2(g)+O2(g) K=1.32 at 627. What is the equilibrium constant at 555C?arrow_forward
- Show that the complete chemical equation, the total ionic equation, and the net ionic equation for the reaction represented by the equation KI(aq)+I2(aq)KI3(aq) give the same expression for the reaction quotient. KI3 is composed of the ions K+ and I3-.arrow_forward5.49. Consider the following equilibrium: What is the effect on the equilibrium of each of the following changes? (You may need to calculate some standard enthalpy or Gibbs energy changes to answer these.) (a) The pressure is increased by decreasing the volume. (b) The temperature is decreased. (c) The pressure is increased by the addition of nitrogen gas, .arrow_forwardGiven the following data: PtCl42(aq)+2ePt(s)+4Cl(aq)Ered=0.73VPt2+(aq)+2ePt(s)Ered=1.20V Find Kffor PtCl42- at 25°C.arrow_forward
- Calculate the standard Gibbs energy change for the following reaction at 298 K H2(g) + Cl2(g) ® 2HCl(g) [DfHo = –92.3 kJ mol–1 for HCl; S in J K–1 mol–1 is 131, 223, and 187 for H2, Cl2 and HCl, respectively].arrow_forwardWrite the equilibrium constant for the reaction P4(s) + 6 H2(g) ⇋ 4 PH3(g), with the gases treated as perfect.arrow_forwardEstimate the temperature at which the equilibrium constant for CuSO4 ⋅ 5 H2O(s) → CuSO4(s) + 5 H2O(g) becomes 1; assume pH2O = 1 bar.arrow_forward
- Calculate the Gibbs energy and equilibrium constant for the chemical reaction at a temperature of 298.15 K. Hg2Cl2(s) → → 2 Hg(l) +Cl2(g). Does the value of the equilibrium constant you calculated describe your understanding of the spontaneity of the reaction in the direction of the arrow?arrow_forward5. What is the standard enthalpy of a reaction for which the equilibrium constant is (a) doubled, (b) halved when the temperature is increased by 15 K at 310 K?arrow_forwardExpress the equilibrium constant for the following reaction. NaClO3(s)<-->NaClO(s)+O2(g)arrow_forward
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