General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Textbook Question
Chapter 5, Problem 5.76EP
Four hypothetical elements, A, B, C, and D, have electronegativities A = 3.4, B = 3.1, C = 2.5, end D = 1.7. These elements form the compounds CB, DC, DA, and BA. Arrange the compounds in order of
- a. Increasing ionic bond character
- b. Decreasing covalent bond character
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Draw the Lewis Structure for each covalent system a-e below, and answer the question that follows:
Electronegativites: H = 2.1 C = 2.5, B = 2.0N = 3.0, 0 = 3.5 S = 2.5, F = 4.0, Xe = 2.6
a. (OF 2 )Is this molecular POLAR or NONPOLAR?
b. (XeF2) What is the geometry of this molecule?
c. (SO 3 ^ 2- )What is the polyatomic ion geometry? (Assume "S" obeys octet)
d.( CH 2 F 2 )Is this molecular POLAR or NONPOLAR?
e.( BF 3 )Is this molecular POLAR NONPOLAR
The standard heat of formation of BaBr2BaBr2 is −−764 kJ/molkJ/mol. The first ionization energy of BaBa is 503 kJ/molkJ/mol and its second ionization energy is 965 kJ/molkJ/mol. The heat of sublimation of Ba[Ba(s)→Ba(g)]Ba[Ba(s)→Ba(g)] is 175 kJ/molkJ/mol. The bond energy of Br2Br2 is 193 kJ/molkJ/mol, the heat of vaporization of Br2(l)Br2(l) is 31 kJ/molkJ/mol, and the electron affinity of BrBr is −−325 kJ/molkJ/mol.
Calculate the lattice energy of BaBr2BaBr2.
Use formal charge to determine which of the following two Lewis structures is better (Figure 1).
A. Structure I is the better Lewis structure.
B. Structure II is the better Lewis structure.
Chapter 5 Solutions
General, Organic, and Biological Chemistry
Ch. 5.1 - Covalent bond formation most often involves...Ch. 5.1 - Which of the following concepts is closely...Ch. 5.1 - Prob. 3QQCh. 5.1 - Prob. 4QQCh. 5.2 - Prob. 1QQCh. 5.2 - Prob. 2QQCh. 5.2 - Prob. 3QQCh. 5.2 - Prob. 4QQCh. 5.2 - Prob. 5QQCh. 5.2 - Prob. 6QQ
Ch. 5.3 - Prob. 1QQCh. 5.3 - Prob. 2QQCh. 5.3 - Prob. 3QQCh. 5.3 - Prob. 4QQCh. 5.3 - Prob. 5QQCh. 5.4 - Prob. 1QQCh. 5.4 - Prob. 2QQCh. 5.4 - Prob. 3QQCh. 5.5 - Which of the following is an incorrect statement...Ch. 5.5 - Prob. 2QQCh. 5.5 - Prob. 3QQCh. 5.6 - Prob. 1QQCh. 5.6 - Prob. 2QQCh. 5.6 - Prob. 3QQCh. 5.6 - Prob. 4QQCh. 5.6 - Prob. 5QQCh. 5.7 - Prob. 1QQCh. 5.7 - Prob. 2QQCh. 5.7 - Prob. 3QQCh. 5.8 - Prob. 1QQCh. 5.8 - In VSEPR theory, an angular molecular geometry is...Ch. 5.8 - Prob. 3QQCh. 5.8 - Prob. 4QQCh. 5.8 - Prob. 5QQCh. 5.9 - Prob. 1QQCh. 5.9 - Prob. 2QQCh. 5.9 - Prob. 3QQCh. 5.9 - Prob. 4QQCh. 5.10 - Prob. 1QQCh. 5.10 - Prob. 2QQCh. 5.10 - Prob. 3QQCh. 5.10 - As the difference in electronegativity between two...Ch. 5.10 - Prob. 5QQCh. 5.10 - Prob. 6QQCh. 5.11 - Prob. 1QQCh. 5.11 - Prob. 2QQCh. 5.11 - Prob. 3QQCh. 5.11 - Prob. 4QQCh. 5.11 - Prob. 5QQCh. 5.12 - Prob. 1QQCh. 5.12 - Prob. 2QQCh. 5.12 - Prob. 3QQCh. 5.12 - Prob. 4QQCh. 5.12 - Prob. 5QQCh. 5.12 - Prob. 6QQCh. 5 - Contrast the types of elements involved in ionic...Ch. 5 - Contrast the mechanisms by which ionic and...Ch. 5 - Prob. 5.3EPCh. 5 - Prob. 5.4EPCh. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - The component elements for four binary molecular...Ch. 5 - The component elements for four binary molecular...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Prob. 5.17EPCh. 5 - Prob. 5.18EPCh. 5 - Prob. 5.19EPCh. 5 - Identify the Period 3 nonmetal that would normally...Ch. 5 - How many valence electrons do atoms possess that...Ch. 5 - Prob. 5.22EPCh. 5 - What aspect of the following Lewis structure...Ch. 5 - What aspect of the following Lewis structure...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Prob. 5.29EPCh. 5 - Prob. 5.30EPCh. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - How many electron dots should appear in the Lewis...Ch. 5 - Prob. 5.36EPCh. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - Prob. 5.45EPCh. 5 - What is the molecular geometry associated with...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Prob. 5.49EPCh. 5 - Prob. 5.50EPCh. 5 - Prob. 5.51EPCh. 5 - Prob. 5.52EPCh. 5 - Prob. 5.53EPCh. 5 - Prob. 5.54EPCh. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Prob. 5.57EPCh. 5 - Specify both the VSEPR electron group geometry...Ch. 5 - Prob. 5.59EPCh. 5 - Prob. 5.60EPCh. 5 - Using a periodic table, but not a table of...Ch. 5 - Using a periodic table, but not a table of...Ch. 5 - Prob. 5.63EPCh. 5 - Prob. 5.64EPCh. 5 - Place + above the atom that is relatively positive...Ch. 5 - Place + above the atom that is relatively positive...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Prob. 5.71EPCh. 5 - Prob. 5.72EPCh. 5 - Fill in the blanks in each line of the following...Ch. 5 - Fill in the blanks in each line of the following...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Indicate whether each of the following...Ch. 5 - Prob. 5.78EPCh. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Prob. 5.83EPCh. 5 - Prob. 5.84EPCh. 5 - Indicate which molecule in each of the following...Ch. 5 - Indicate which molecule in each of the following...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Prob. 5.89EPCh. 5 - Indicate whether or not each of the following...Ch. 5 - Prob. 5.91EPCh. 5 - Name the following binary molecular compounds? a....Ch. 5 - Prob. 5.93EPCh. 5 - Prob. 5.94EPCh. 5 - Prob. 5.95EPCh. 5 - Prob. 5.96EPCh. 5 - Prob. 5.97EPCh. 5 - Prob. 5.98EPCh. 5 - Write chemical formulas for the following binary...Ch. 5 - Write chemical formulas for the following binary...Ch. 5 - Prob. 5.101EPCh. 5 - Prob. 5.102EPCh. 5 - The compound whose molecles contain one atom of C...Ch. 5 - Prob. 5.104EPCh. 5 - Prob. 5.105EPCh. 5 - The correct name for the compound K2SO4 is not...Ch. 5 - Prob. 5.107EPCh. 5 - Prob. 5.108EP
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