Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
bartleby

Concept explainers

Question
Book Icon
Chapter 5, Problem 5.7QAP
Interpretation Introduction

(a)

Interpretation:

The signal-to-noise ratio is to be stated.

Concept introduction:

The signal and noise are two components of instrument measurement. One component is the signal, which carries information that is of interest to scientists and another component is noise, which is the unwanted fluctuations of signals.

Expert Solution
Check Mark

Answer to Problem 5.7QAP

The signal-to-noise ratio is 338.74.

Explanation of Solution

The magnitude of signal is denoted by S and the magnitude of noise is denoted by N.

The expression for the mean of the measurements is:

x¯=i=1NxlN ...... (I)

Here, the total number of measurement is N and the measurement is xi where i=1,2,3,4,...,9.

Substitute 1.003 for x1, 1.000 for x2. 1.001 for x3, 1.004 for x4, 1.005 for x5, 1.006 for x6, 1.001 for x7, 0.999 for x8, 1.007 for x9, and 9 for N.

x¯=[1.002+1.000+0.997+1.004+1.003+1.001+1.005+0.999+1.007]9=9.0189=1.002

The expression for the standard deviation is:

s=i=1N(xix¯)2N1 ...... (II)

Substitute 1.003 for x1, 1.000 for x2. 1.001 for x3, 1.004 for x4, 1.005 for x5, 1.006 for x6, 1.001 for x7, 0.999 for x8, 1.007 for x9, 1.002 for x¯, and 9 for N.

s=[(1.0031.002)2+(1.0001.002)2+(1.0011.002)2+(1.0041.002)2+(1.0051.002)2+(1.0011.002)2+(1.0061.002)2+(0.9991.002)2+(1.0071.002)2]91=[(106)+(4×106)+(106)+(4×106)+(9×106)+(106)+(16×106)+(9×106)+(25×106)]91=70×1068=2.958×103

The expression for the signal to noise ratio is:

SN=x¯s ...... (III)

Substitute 2.5 for s and 1.002 for x¯ in Equation (III).

SN=1.0022.958×103=338.74

Interpretation Introduction

(b)

Interpretation:

The number of measurements required to obtain a S/N of 500 is to be stated.

Concept introduction:

The signal and noise are two components of instrument measurement. One component is the signal, which carries information that is of interest to scientists and another component is noise, which is the unwanted fluctuations of signals. For n number of repetitions, the signal to noise ratio is proportional to square root of number of repetitions.

Expert Solution
Check Mark

Answer to Problem 5.7QAP

The number of measurement required to obtain a S/N of 500 is 18.

Explanation of Solution

The expression for n number of repetitions is:

(SN)n=n(SN)i ...... (IV)

Here, the signal to noise at initial point is (SN)i.

Substitute 338.74 for (SN)n and 9 for N in Equation (IV).

338.74=9(SN)i(SN)i=338.743(SN)i=112.913

Substitute 112.913 for (SN)i and 500 for (SN)n in Equation (IV).

500=n(112.913)n=(500112.913)2n=19.6n20

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
The following data were obtained for repetitive mass measurements of 1.004-g standard mass on a top-loading balance: 1.002, 1.000, 0.997, 1.004, 1.003, 1.001, 1.005, 0.999, 1.007. a. assuming the noise is random, calculate the signal-to-noise ratio for the balance.   b. How many measurements would have to be averaged to obtain a S/N of 500?
A standard solution was prepared containing 10.0 ppm of an analyte and 15.0 ppm of an internal standard. Analysis of the sample gave signals for the analyte and internal standard of 0.155 and 0.233 (arbitrary units), respectively. Sufficient internal standard was added to an unknown sample to make it 15.0 ppm in the internal standard. Analysis of the unknown sample yielded signals for the analyte and internal standard of 0.274 and 0.198, respectively. Calculate the concentration of analyte in the unknown sample.
What is the actual or real-life application of electrogravimetric analysis? Include the specific methodology.
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Fundamentals Of Analytical Chemistry
Chemistry
ISBN:9781285640686
Author:Skoog
Publisher:Cengage
Text book image
Appl Of Ms Excel In Analytical Chemistry
Chemistry
ISBN:9781285686691
Author:Crouch
Publisher:Cengage