BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

Solutions

Chapter
Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

Classify each of the amides in Problem 17-102 as a primary, secondary, or tertiary amide.

Chapter 6, Problem 6.104EP, Classify each of the amides in Problem 17-102 as a primary, secondary, or tertiary amide. , example  1

Chapter 6, Problem 6.104EP, Classify each of the amides in Problem 17-102 as a primary, secondary, or tertiary amide. , example  2

Chapter 6, Problem 6.104EP, Classify each of the amides in Problem 17-102 as a primary, secondary, or tertiary amide. , example  3

Chapter 6, Problem 6.104EP, Classify each of the amides in Problem 17-102 as a primary, secondary, or tertiary amide. , example  4

(a)

Interpretation Introduction

Interpretation:

Given amide has to be classified as primary, secondary, or tertiary amide.

Concept Introduction:

Organic compounds are the important basis of life.  They include gasoline, coal, dyes, and clothing fibers etc.  The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds.  Organic compounds are found in earth also apart from living organisms.  All the organic compounds contain the element carbon.  Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also.  Some of them are nitrogen, sulfur, oxygen etc.  Nitrogen containing organic compounds are of two important types and they are amines, amides.

One of the carboxylic acid derivatives is amide.  In this the carboxyl OH group is replaced by an amino or a substituted amino group.  The functional group of amide can be given as,

Organic And Biological Chemistry, Chapter 6, Problem 6.104EP , additional homework tip  1

Amides are also classified as primary, secondary, and tertiary amide.

Organic And Biological Chemistry, Chapter 6, Problem 6.104EP , additional homework tip  2

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms.  Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group.  Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups.  Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides.  They are formed by intramolecular condensation.  Cyclic amides are also known as lactams.

Explanation

Given structure of amide is,

Looking into the above structure, the nitrogen atom present in ...

(b)

Interpretation Introduction

Interpretation:

Given amide has to be classified as primary, secondary, or tertiary amide.

Concept Introduction:

Organic compounds are the important basis of life.  They include gasoline, coal, dyes, and clothing fibers etc.  The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds.  Organic compounds are found in earth also apart from living organisms.  All the organic compounds contain the element carbon.  Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also.  Some of them are nitrogen, sulfur, oxygen etc.  Nitrogen containing organic compounds are of two important types and they are amines, amides.

One of the carboxylic acid derivatives is amide.  In this the carboxyl OH group is replaced by an amino or a substituted amino group.  The functional group of amide can be given as,

Organic And Biological Chemistry, Chapter 6, Problem 6.104EP , additional homework tip  3

Amides are also classified as primary, secondary, and tertiary amide.

Organic And Biological Chemistry, Chapter 6, Problem 6.104EP , additional homework tip  4

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms.  Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group.  Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups.  Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides.  They are formed by intramolecular condensation.  Cyclic amides are also known as lactams.

(c)

Interpretation Introduction

Interpretation:

Given amide has to be classified as primary, secondary, or tertiary amide.

Concept Introduction:

Organic compounds are the important basis of life.  They include gasoline, coal, dyes, and clothing fibers etc.  The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds.  Organic compounds are found in earth also apart from living organisms.  All the organic compounds contain the element carbon.  Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also.  Some of them are nitrogen, sulfur, oxygen etc.  Nitrogen containing organic compounds are of two important types and they are amines, amides.

One of the carboxylic acid derivatives is amide.  In this the carboxyl OH group is replaced by an amino or a substituted amino group.  The functional group of amide can be given as,

Organic And Biological Chemistry, Chapter 6, Problem 6.104EP , additional homework tip  5

Amides are also classified as primary, secondary, and tertiary amide.

Organic And Biological Chemistry, Chapter 6, Problem 6.104EP , additional homework tip  6

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms.  Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group.  Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups.  Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides.  They are formed by intramolecular condensation.  Cyclic amides are also known as lactams.

(d)

Interpretation Introduction

Interpretation:

Given amide has to be classified as primary, secondary, or tertiary amide.

Concept Introduction:

Organic compounds are the important basis of life.  They include gasoline, coal, dyes, and clothing fibers etc.  The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds.  Organic compounds are found in earth also apart from living organisms.  All the organic compounds contain the element carbon.  Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also.  Some of them are nitrogen, sulfur, oxygen etc.  Nitrogen containing organic compounds are of two important types and they are amines, amides.

One of the carboxylic acid derivatives is amide.  In this the carboxyl OH group is replaced by an amino or a substituted amino group.  The functional group of amide can be given as,

Organic And Biological Chemistry, Chapter 6, Problem 6.104EP , additional homework tip  7

Amides are also classified as primary, secondary, and tertiary amide.

Organic And Biological Chemistry, Chapter 6, Problem 6.104EP , additional homework tip  8

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms.  Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group.  Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups.  Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides.  They are formed by intramolecular condensation.  Cyclic amides are also known as lactams.

Still sussing out bartleby?

Check out a sample textbook solution.

See a sample solution

The Solution to Your Study Problems

Bartleby provides explanations to thousands of textbook problems written by our experts, many with advanced degrees!

Get Started
Sect-6.4 P-1QQSect-6.4 P-2QQSect-6.5 P-1QQSect-6.5 P-2QQSect-6.5 P-3QQSect-6.6 P-1QQSect-6.6 P-2QQSect-6.6 P-3QQSect-6.7 P-1QQSect-6.7 P-2QQSect-6.7 P-3QQSect-6.8 P-1QQSect-6.8 P-2QQSect-6.8 P-3QQSect-6.8 P-4QQSect-6.9 P-1QQSect-6.9 P-2QQSect-6.10 P-1QQSect-6.10 P-2QQSect-6.10 P-3QQSect-6.10 P-4QQSect-6.11 P-1QQSect-6.11 P-2QQSect-6.11 P-3QQSect-6.12 P-1QQSect-6.12 P-2QQSect-6.12 P-3QQSect-6.12 P-4QQSect-6.13 P-1QQSect-6.13 P-2QQSect-6.13 P-3QQSect-6.13 P-4QQSect-6.14 P-1QQSect-6.14 P-2QQSect-6.14 P-3QQSect-6.15 P-1QQSect-6.15 P-2QQSect-6.16 P-1QQSect-6.16 P-2QQSect-6.16 P-3QQSect-6.17 P-1QQSect-6.17 P-2QQSect-6.17 P-3QQSect-6.18 P-1QQSect-6.18 P-2QQSect-6.18 P-3QQSect-6.19 P-1QQSect-6.19 P-2QQSect-6.19 P-3QQSect-6.19 P-4QQCh-6 P-6.1EPCh-6 P-6.2EPCh-6 P-6.3EPCh-6 P-6.4EPCh-6 P-6.5EPCh-6 P-6.6EPCh-6 P-6.7EPCh-6 P-6.8EPCh-6 P-6.9EPCh-6 P-6.10EPCh-6 P-6.11EPCh-6 P-6.12EPCh-6 P-6.13EPCh-6 P-6.14EPCh-6 P-6.15EPCh-6 P-6.16EPCh-6 P-6.17EPCh-6 P-6.18EPCh-6 P-6.19EPCh-6 P-6.20EPCh-6 P-6.21EPCh-6 P-6.22EPCh-6 P-6.23EPCh-6 P-6.24EPCh-6 P-6.25EPCh-6 P-6.26EPCh-6 P-6.27EPCh-6 P-6.28EPCh-6 P-6.29EPCh-6 P-6.30EPCh-6 P-6.31EPCh-6 P-6.32EPCh-6 P-6.33EPCh-6 P-6.34EPCh-6 P-6.35EPCh-6 P-6.36EPCh-6 P-6.37EPCh-6 P-6.38EPCh-6 P-6.39EPCh-6 P-6.40EPCh-6 P-6.41EPCh-6 P-6.42EPCh-6 P-6.43EPCh-6 P-6.44EPCh-6 P-6.45EPCh-6 P-6.46EPCh-6 P-6.47EPCh-6 P-6.48EPCh-6 P-6.49EPCh-6 P-6.50EPCh-6 P-6.51EPCh-6 P-6.52EPCh-6 P-6.53EPCh-6 P-6.54EPCh-6 P-6.55EPCh-6 P-6.56EPCh-6 P-6.57EPCh-6 P-6.58EPCh-6 P-6.59EPCh-6 P-6.60EPCh-6 P-6.61EPCh-6 P-6.62EPCh-6 P-6.63EPCh-6 P-6.64EPCh-6 P-6.65EPCh-6 P-6.66EPCh-6 P-6.67EPCh-6 P-6.68EPCh-6 P-6.69EPCh-6 P-6.70EPCh-6 P-6.71EPCh-6 P-6.72EPCh-6 P-6.73EPCh-6 P-6.74EPCh-6 P-6.75EPCh-6 P-6.76EPCh-6 P-6.77EPCh-6 P-6.78EPCh-6 P-6.79EPCh-6 P-6.80EPCh-6 P-6.81EPCh-6 P-6.82EPCh-6 P-6.83EPCh-6 P-6.84EPCh-6 P-6.85EPCh-6 P-6.86EPCh-6 P-6.87EPCh-6 P-6.88EPCh-6 P-6.89EPCh-6 P-6.90EPCh-6 P-6.91EPCh-6 P-6.92EPCh-6 P-6.93EPCh-6 P-6.94EPCh-6 P-6.95EPCh-6 P-6.96EPCh-6 P-6.97EPCh-6 P-6.98EPCh-6 P-6.99EPCh-6 P-6.100EPCh-6 P-6.101EPCh-6 P-6.102EPCh-6 P-6.103EPCh-6 P-6.104EPCh-6 P-6.105EPCh-6 P-6.106EPCh-6 P-6.107EPCh-6 P-6.108EPCh-6 P-6.109EPCh-6 P-6.110EPCh-6 P-6.111EPCh-6 P-6.112EPCh-6 P-6.113EPCh-6 P-6.114EPCh-6 P-6.115EPCh-6 P-6.116EPCh-6 P-6.117EPCh-6 P-6.118EPCh-6 P-6.119EPCh-6 P-6.120EPCh-6 P-6.121EPCh-6 P-6.122EPCh-6 P-6.123EPCh-6 P-6.124EPCh-6 P-6.125EPCh-6 P-6.126EPCh-6 P-6.127EPCh-6 P-6.128EPCh-6 P-6.129EPCh-6 P-6.130EPCh-6 P-6.131EPCh-6 P-6.132EPCh-6 P-6.133EPCh-6 P-6.134EPCh-6 P-6.135EPCh-6 P-6.136EPCh-6 P-6.137EPCh-6 P-6.138EPCh-6 P-6.139EPCh-6 P-6.140EPCh-6 P-6.141EPCh-6 P-6.142EPCh-6 P-6.143EPCh-6 P-6.144EPCh-6 P-6.145EPCh-6 P-6.146EPCh-6 P-6.147EPCh-6 P-6.148EPCh-6 P-6.149EPCh-6 P-6.150EPCh-6 P-6.151EPCh-6 P-6.152EPCh-6 P-6.153EPCh-6 P-6.154EP

Additional Science Solutions

Find more solutions based on key concepts

Show solutions add

7.23 Define the term lone pair.

Chemistry for Engineering Students

One way to evaluate any diet is to compare the total food amounts that it provides with those recommended by th...

Nutrition: Concepts and Controversies - Standalone book (MindTap Course List)

A triatomic molecule can have a linear configuration, as does CO2 (Fig. P20.40a). or it can be nonlinear, like ...

Physics for Scientists and Engineers, Technology Update (No access codes included)

How has the advent of containerized shipping changed world economics?

Oceanography: An Invitation To Marine Science, Loose-leaf Versin