Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Question
Chapter 6, Problem 6.134EP

(a)

Interpretation Introduction

Interpretation:

Structure of carboxylic acid that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(a)

Expert Solution
Check Mark

Answer to Problem 6.134EP

Carboxylic acid that is required was,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  1

Explanation of Solution

Given structure of compound is,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  2

As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it, the amide is a primary amide.  Primary amide is produced by the reaction of ammonia with carboxylic acid.  The “parent” carboxylic acid can be identified as shown below,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  3

Hydrogen atom has to be added to the amine part and OH group has to be added to the acid part in order to obtain the parent molecules.  From this the carboxylic acid that is required to produce the given amide is,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  4

Conclusion

Structure of carboxylic acid that is required to produce the given compound is drawn.

(b)

Interpretation Introduction

Interpretation:

Structure of carboxylic acid that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(b)

Expert Solution
Check Mark

Answer to Problem 6.134EP

Carboxylic acid that is required was,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  5

Explanation of Solution

Given structure of compound is,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  6

As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it, the amide is a primary amide.  Primary amide is produced by the reaction of ammonia with carboxylic acid.  The “parent” carboxylic acid can be identified as shown below,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  7

Hydrogen atom has to be added to the amine part and OH group has to be added to the acid part in order to obtain the parent molecules.  From this the carboxylic acid that is required to produce the given amide is,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  8

Conclusion

Structure of carboxylic acid that is required to produce the given compound is drawn.

(c)

Interpretation Introduction

Interpretation:

Structure of carboxylic acid that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(c)

Expert Solution
Check Mark

Answer to Problem 6.134EP

Carboxylic acid that is required was,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  9

Explanation of Solution

Given structure of compound is,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  10

As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it, the amide is a primary amide.  Primary amide is produced by the reaction of ammonia with carboxylic acid.  The “parent” carboxylic acid can be identified as shown below,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  11

Hydrogen atom has to be added to the amine part and OH group has to be added to the acid part in order to obtain the parent molecules.  From this the carboxylic acid that is required to produce the given amide is,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  12

Conclusion

Structure of carboxylic acid that is required to produce the given compound is drawn.

(d)

Interpretation Introduction

Interpretation:

Structure of carboxylic acid that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(d)

Expert Solution
Check Mark

Answer to Problem 6.134EP

Carboxylic acid that is required was,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  13

Explanation of Solution

Given structure of compound is,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  14

As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it, the amide is a primary amide.  Primary amide is produced by the reaction of ammonia with carboxylic acid.  The “parent” carboxylic acid can be identified as shown below,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  15

Hydrogen atom has to be added to the amine part and OH group has to be added to the acid part in order to obtain the parent molecules.  From this the carboxylic acid that is required to produce the given amide is,

Organic And Biological Chemistry, Chapter 6, Problem 6.134EP , additional homework tip  16

Conclusion

Structure of carboxylic acid that is required to produce the given compound is drawn.

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Chapter 6 Solutions

Organic And Biological Chemistry

Ch. 6.4 - Prob. 1QQCh. 6.4 - Prob. 2QQCh. 6.5 - Prob. 1QQCh. 6.5 - Prob. 2QQCh. 6.5 - Prob. 3QQCh. 6.6 - Prob. 1QQCh. 6.6 - Prob. 2QQCh. 6.6 - Prob. 3QQCh. 6.7 - Prob. 1QQCh. 6.7 - Prob. 2QQCh. 6.7 - Prob. 3QQCh. 6.8 - Prob. 1QQCh. 6.8 - Prob. 2QQCh. 6.8 - Prob. 3QQCh. 6.8 - Prob. 4QQCh. 6.9 - Prob. 1QQCh. 6.9 - Prob. 2QQCh. 6.10 - Prob. 1QQCh. 6.10 - Prob. 2QQCh. 6.10 - Prob. 3QQCh. 6.10 - Prob. 4QQCh. 6.11 - Prob. 1QQCh. 6.11 - Prob. 2QQCh. 6.11 - Prob. 3QQCh. 6.12 - Prob. 1QQCh. 6.12 - Prob. 2QQCh. 6.12 - Prob. 3QQCh. 6.12 - Prob. 4QQCh. 6.13 - Prob. 1QQCh. 6.13 - Prob. 2QQCh. 6.13 - Prob. 3QQCh. 6.13 - Prob. 4QQCh. 6.14 - Prob. 1QQCh. 6.14 - Prob. 2QQCh. 6.14 - Prob. 3QQCh. 6.15 - Prob. 1QQCh. 6.15 - Prob. 2QQCh. 6.16 - Prob. 1QQCh. 6.16 - Prob. 2QQCh. 6.16 - Prob. 3QQCh. 6.17 - Prob. 1QQCh. 6.17 - Prob. 2QQCh. 6.17 - Prob. 3QQCh. 6.18 - Prob. 1QQCh. 6.18 - Prob. 2QQCh. 6.18 - Prob. 3QQCh. 6.19 - Prob. 1QQCh. 6.19 - Prob. 2QQCh. 6.19 - Prob. 3QQCh. 6.19 - Prob. 4QQCh. 6 - Prob. 6.1EPCh. 6 - Prob. 6.2EPCh. 6 - Prob. 6.3EPCh. 6 - Prob. 6.4EPCh. 6 - Prob. 6.5EPCh. 6 - Prob. 6.6EPCh. 6 - Prob. 6.7EPCh. 6 - Indicate whether or not each of the following...Ch. 6 - Indicate whether each of the compounds in Problem...Ch. 6 - Prob. 6.10EPCh. 6 - Prob. 6.11EPCh. 6 - Prob. 6.12EPCh. 6 - Prob. 6.13EPCh. 6 - Prob. 6.14EPCh. 6 - Prob. 6.15EPCh. 6 - Prob. 6.16EPCh. 6 - Prob. 6.17EPCh. 6 - Assign an IUPAC name to each of the following...Ch. 6 - Prob. 6.19EPCh. 6 - Prob. 6.20EPCh. 6 - Prob. 6.21EPCh. 6 - Prob. 6.22EPCh. 6 - Prob. 6.23EPCh. 6 - Prob. 6.24EPCh. 6 - Prob. 6.25EPCh. 6 - Classify each of the following compounds as a 1...Ch. 6 - Prob. 6.27EPCh. 6 - Prob. 6.28EPCh. 6 - Prob. 6.29EPCh. 6 - Prob. 6.30EPCh. 6 - Prob. 6.31EPCh. 6 - Prob. 6.32EPCh. 6 - Prob. 6.33EPCh. 6 - Prob. 6.34EPCh. 6 - Determine the maximum number of hydrogen bonds...Ch. 6 - Prob. 6.36EPCh. 6 - Although they have similar molecular masses (73...Ch. 6 - Prob. 6.38EPCh. 6 - Prob. 6.39EPCh. 6 - Prob. 6.40EPCh. 6 - Show the structures of the missing substance(s) in...Ch. 6 - Prob. 6.42EPCh. 6 - Prob. 6.43EPCh. 6 - Prob. 6.44EPCh. 6 - Prob. 6.45EPCh. 6 - Prob. 6.46EPCh. 6 - Prob. 6.47EPCh. 6 - Prob. 6.48EPCh. 6 - Prob. 6.49EPCh. 6 - Prob. 6.50EPCh. 6 - Prob. 6.51EPCh. 6 - Prob. 6.52EPCh. 6 - Prob. 6.53EPCh. 6 - Prob. 6.54EPCh. 6 - Prob. 6.55EPCh. 6 - Prob. 6.56EPCh. 6 - Prob. 6.57EPCh. 6 - Prob. 6.58EPCh. 6 - Prob. 6.59EPCh. 6 - Prob. 6.60EPCh. 6 - Prob. 6.61EPCh. 6 - Prob. 6.62EPCh. 6 - Prob. 6.63EPCh. 6 - Prob. 6.64EPCh. 6 - Prob. 6.65EPCh. 6 - Prob. 6.66EPCh. 6 - Prob. 6.67EPCh. 6 - Prob. 6.68EPCh. 6 - Prob. 6.69EPCh. 6 - Prob. 6.70EPCh. 6 - Prob. 6.71EPCh. 6 - Prob. 6.72EPCh. 6 - Prob. 6.73EPCh. 6 - Prob. 6.74EPCh. 6 - Name each of the salts in Problem 17-71. a....Ch. 6 - Prob. 6.76EPCh. 6 - Indicate whether or not each of the following...Ch. 6 - Prob. 6.78EPCh. 6 - Prob. 6.79EPCh. 6 - Prob. 6.80EPCh. 6 - Prob. 6.81EPCh. 6 - Prob. 6.82EPCh. 6 - Prob. 6.83EPCh. 6 - Prob. 6.84EPCh. 6 - Prob. 6.85EPCh. 6 - Prob. 6.86EPCh. 6 - Prob. 6.87EPCh. 6 - Prob. 6.88EPCh. 6 - Prob. 6.89EPCh. 6 - Prob. 6.90EPCh. 6 - Prob. 6.91EPCh. 6 - Indicate whether each of the following statements...Ch. 6 - Prob. 6.93EPCh. 6 - Prob. 6.94EPCh. 6 - Prob. 6.95EPCh. 6 - Prob. 6.96EPCh. 6 - Prob. 6.97EPCh. 6 - Prob. 6.98EPCh. 6 - Indicate whether or not each of the following...Ch. 6 - Prob. 6.100EPCh. 6 - Classify each of the following amides as...Ch. 6 - Classify each of the following amides as...Ch. 6 - Prob. 6.103EPCh. 6 - Prob. 6.104EPCh. 6 - Prob. 6.105EPCh. 6 - Prob. 6.106EPCh. 6 - Prob. 6.107EPCh. 6 - Assign an IUPAC name to each of the following...Ch. 6 - Prob. 6.109EPCh. 6 - Prob. 6.110EPCh. 6 - Prob. 6.111EPCh. 6 - Prob. 6.112EPCh. 6 - Prob. 6.113EPCh. 6 - Prob. 6.114EPCh. 6 - Prob. 6.115EPCh. 6 - Prob. 6.116EPCh. 6 - Prob. 6.117EPCh. 6 - Prob. 6.118EPCh. 6 - Prob. 6.119EPCh. 6 - Prob. 6.120EPCh. 6 - Prob. 6.121EPCh. 6 - Prob. 6.122EPCh. 6 - Prob. 6.123EPCh. 6 - Prob. 6.124EPCh. 6 - Prob. 6.125EPCh. 6 - Prob. 6.126EPCh. 6 - Prob. 6.127EPCh. 6 - Prob. 6.128EPCh. 6 - Prob. 6.129EPCh. 6 - Prob. 6.130EPCh. 6 - Prob. 6.131EPCh. 6 - Prob. 6.132EPCh. 6 - Prob. 6.133EPCh. 6 - Prob. 6.134EPCh. 6 - Prob. 6.135EPCh. 6 - Prob. 6.136EPCh. 6 - Prob. 6.137EPCh. 6 - Prob. 6.138EPCh. 6 - Prob. 6.139EPCh. 6 - Prob. 6.140EPCh. 6 - Prob. 6.141EPCh. 6 - Prob. 6.142EPCh. 6 - Prob. 6.143EPCh. 6 - Prob. 6.144EPCh. 6 - Prob. 6.145EPCh. 6 - Draw the structure of the nitrogen-containing...Ch. 6 - Prob. 6.147EPCh. 6 - Prob. 6.148EPCh. 6 - Prob. 6.149EPCh. 6 - Prob. 6.150EPCh. 6 - Prob. 6.151EPCh. 6 - Prob. 6.152EPCh. 6 - Prob. 6.153EPCh. 6 - Prob. 6.154EP
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