Loose Leaf for Organic Chemistry
Loose Leaf for Organic Chemistry
5th Edition
ISBN: 9781259637025
Author: Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 6, Problem 6.1P

Classify each transformation as substitution, elimination, or addition.

a. Chapter 6, Problem 6.1P, Problem 6.1 Classify each transformation as substitution, elimination, or addition.
a.    c. 
b. d. , example  1 c. Chapter 6, Problem 6.1P, Problem 6.1 Classify each transformation as substitution, elimination, or addition.
a.    c. 
b. d. , example  2

b. Chapter 6, Problem 6.1P, Problem 6.1 Classify each transformation as substitution, elimination, or addition.
a.    c. 
b. d. , example  3d. Chapter 6, Problem 6.1P, Problem 6.1 Classify each transformation as substitution, elimination, or addition.
a.    c. 
b. d. , example  4

Expert Solution
Check Mark
Interpretation Introduction

(a)

Interpretation: The given transformation is to be classified as substitution, elimination, or addition reaction.

Concept introduction: The substitution reactions involve the substitution or replacement of an atom or group of atoms in a compound by another atom or groups of atoms. In the substitution reactions, the replacement takes place by the break down of sigma bonds.

In elimination reaction, the formation of π bonds occurs due to the removal of an atom or group of atoms from the starting material, whereas the addition reaction involves the addition of elements into the starting material.

Answer to Problem 6.1P

The given transformation is an example of a substitution reaction.

Explanation of Solution

The given transformation is shown as,

Loose Leaf for Organic Chemistry, Chapter 6, Problem 6.1P , additional homework tip  1

Figure 1

In the above reaction, the hydroxyl group is replaced by a bromine atom. The breakdown of the sigma bond precedes the mechanism. On replacement of the hydroxyl group, one sigma bond breaks and another is formed at the same position. Therefore, it is classified as the substitution reaction.

Conclusion

The given transformation is classified as a substitution reaction.

Expert Solution
Check Mark
Interpretation Introduction

(b)

Interpretation: The given transformation is to be classified as substitution, elimination, or addition reaction.

Concept introduction: The substitution reactions involve the substitution or replacement of an atom or group of atoms in a compound by another atom or groups of atoms. In the substitution reactions, the replacement takes place by the break down of sigma bonds.

In elimination reaction, the formation of π bonds occurs due to the removal of an atom or group of atoms from the starting material, whereas the addition reaction involves the addition of elements into the starting material.

Answer to Problem 6.1P

The given transformation is an example of an addition reaction.

Explanation of Solution

The given transformation is shown as,

Loose Leaf for Organic Chemistry, Chapter 6, Problem 6.1P , additional homework tip  2

Figure 2

The above reaction involves the breakdown of π bond. In this reaction, C=O bond is converted into OH group by the addition of two hydrogen atoms. Therefore, this reaction is an example of an addition reaction.

Conclusion

The given transformation is classified as an addition reaction.

Expert Solution
Check Mark
Interpretation Introduction

(c)

Interpretation: The given transformation is to be classified as substitution, elimination, or addition.

Concept introduction: The substitution reactions involve the substitution or replacement of an atom or group of atoms in a compound by another atom or groups of atoms. In the substitution reactions, the replacement takes place by the break down of sigma bonds.

In elimination reaction, the formation of π bonds occurs due to the removal of an atom or group of atoms from the starting material, whereas the addition reaction involves the addition of elements into the starting material.

Answer to Problem 6.1P

The given transformation is an example of a substitution reaction.

Explanation of Solution

The given transformation is shown as,

Loose Leaf for Organic Chemistry, Chapter 6, Problem 6.1P , additional homework tip  3

Figure 3

In the above reaction, the hydrogen is replaced by chlorine. The breakdown of the sigma bond precedes the mechanism. On the replacement of hydrogen, one sigma bond breaks and another sigma bond is formed between carbon and substituent atom.

Conclusion

The given transformation is classified as a substitution reaction.

Expert Solution
Check Mark
Interpretation Introduction

(d)

Interpretation: The given transformation as substitution, elimination, or addition is to be classified.

Concept introduction: The substitution reactions involve the substitution or replacement of an atom or group of atoms in a compound by another atom or groups of atoms. In the substitution reactions, the replacement takes place by the break down of sigma bonds.

In elimination reaction, the formation of π bonds occurs due to the removal of an atom or group of atoms from the starting material, whereas the addition reaction involves the addition of elements into the starting material.

Answer to Problem 6.1P

The given transformation is an example of an elimination reaction.

Explanation of Solution

The given transformation is shown as,

Loose Leaf for Organic Chemistry, Chapter 6, Problem 6.1P , additional homework tip  4

Figure 4

In this reaction, the formation of π bond takes place by the removal of a water molecule from the starting material. Therefore, it is an example of an elimination reaction.

Conclusion

The given transformation is classified as an elimination reaction.

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Chapter 6 Solutions

Loose Leaf for Organic Chemistry

Ch. 6 - Given each of the following values, is the...Ch. 6 - The equilibrium constant for the conversion of the...Ch. 6 - Prob. 6.13PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.17PCh. 6 - Prob. 6.18PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.22PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.24PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.29PCh. 6 - 6.30 Draw the products of each reaction by...Ch. 6 - 6.31 (a) Add curved arrows for each step to show...Ch. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Calculate H for each reaction. a HO+CH4CH3+H2O b...Ch. 6 - Homolysis of the indicated CH bond in propene...Ch. 6 - Prob. 6.37PCh. 6 - Prob. 6.38PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.40PCh. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - 6.44 Consider the following reaction: . Use curved...Ch. 6 - Prob. 6.45PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.47PCh. 6 - Indicate which factors affect the rate of a...Ch. 6 - Prob. 6.49PCh. 6 - 6.50 The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - The conversion of (CH3)3Cl to (CH3)2C=CH2 can...Ch. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.59P
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