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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

Indicate whether or not the two members of each of the following pairs of amines are constitutional isomers.

  1. a. CH3—CH2—CH2—CH2—NH2 and CH3—CH2—CH2—NH2
  2. b. CH3—CH2—CH2—NH—CH3 and CH3—CH2—NH—CH2—CH3

Chapter 6, Problem 6.27EP, Indicate whether or not the two members of each of the following pairs of amines are constitutional , example  1

Chapter 6, Problem 6.27EP, Indicate whether or not the two members of each of the following pairs of amines are constitutional , example  2

(a)

Interpretation Introduction

Interpretation:

Two members in the given pair of amines are constitutional isomers or not has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula.  Each and every compound has its own molecular formula.  Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula.  The main difference lies in the way the atoms are arranged in the structure.  Isomers have different chemical and physical properties even when they have same molecular formula.  This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism.  The isomers are known as constitutional isomers.  They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Explanation

Given structure of compounds are,

Constitutional isomers are the compounds which have same molecular formula but they differ only in the connectivity of the atoms in the molecule.

The molecular formula of the first structure is C4

(b)

Interpretation Introduction

Interpretation:

Two members in the given pair of amines are constitutional isomers or not has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula.  Each and every compound has its own molecular formula.  Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula.  The main difference lies in the way the atoms are arranged in the structure.  Isomers have different chemical and physical properties even when they have same molecular formula.  This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism.  The isomers are known as constitutional isomers.  They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

Two members in the given pair of amines are constitutional isomers or not has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula.  Each and every compound has its own molecular formula.  Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula.  The main difference lies in the way the atoms are arranged in the structure.  Isomers have different chemical and physical properties even when they have same molecular formula.  This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism.  The isomers are known as constitutional isomers.  They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

Two members in the given pair of amines are constitutional isomers or not has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula.  Each and every compound has its own molecular formula.  Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula.  The main difference lies in the way the atoms are arranged in the structure.  Isomers have different chemical and physical properties even when they have same molecular formula.  This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism.  The isomers are known as constitutional isomers.  They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

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