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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Chapter
Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

The organic products from the basic hydrolysis of an amide are

  1. a. a carboxylic acid and an amine salt
  2. b. a carboxylic acid salt and an amine salt
  3. c. a carboxylic acid and an amine
  4. d. no correct response

Interpretation Introduction

Interpretation:

On basic hydrolysis of amide, the organic products that are obtained has to be chosen from the given options.

Concept Introduction:

Amides are derivatives of carboxylic acid.  Amides are not much reactive as of carboxylic acids.  They are also stable relatively in aqueous solution.  But under strenuous conditions amides undergo hydrolysis.  The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt.  Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Organic And Biological Chemistry, Chapter 6.18, Problem 2QQ , additional homework tip  1

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine.  Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Organic And Biological Chemistry, Chapter 6.18, Problem 2QQ , additional homework tip  2

Explanation

Reason for correct option:

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine.  Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

In all the options given in the problem statement there is no statement that says carboxylic acid salt and amine is obtained as product.

Therefore, option (d) is a correct one.

Reason for incorrect option:

Option (a) tells that organic products obtained from basic hydrolysis of amides are carboxylic acid and an amine salt...

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