ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
6th Edition
ISBN: 9781266633973
Author: SMITH
Publisher: MCG
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Chapter 6.3, Problem 3P

By taking into account electronegativity differences, draw the products formed by heterolysis of the carbon-heteroatom bond in each molecule. Classify the organic reactive intermediate as a carbocation or a carbanion.

a.Chapter 6.3, Problem 3P, Problem 6.3 By taking into account electronegativity differences, draw the products formed by , example  1 b. Chapter 6.3, Problem 3P, Problem 6.3 By taking into account electronegativity differences, draw the products formed by , example  2 c. Chapter 6.3, Problem 3P, Problem 6.3 By taking into account electronegativity differences, draw the products formed by , example  3

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Provide reactants/reagents and solvents that could be used to synthesize these products from an alkyl halide via substitution or elimination.
7. (Chapters 6 and 8) Within the following set, which is more stable, and why? CH3 CH3 H3C- -C=CH- CH2 H2C=Ć- -CH CH3 8. (Chapter 12) What type of instability will an intermediate need to address following the reaction of a nucleophile/base that has a negative charge with a pi bond that has uneven electron distribution between atoms with different electronegativities (C=O)? 9. (Chapter 9) Circle the carbon that will be unstable in the intermediate of the following reaction. Then, state the reason for your choice, and also indicate what type of instability it will be. H,C-CH,- C ECH with NaNH2 10. (Chapters 12 and 13) What are three sources used to provide electrons to an electron-deficient carbon with a leaving group? 1. 2. 3.
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ORGANIC CHEMISTRY

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