a) Interpretation: Whether CH 3 Cl is likely to behave as a nucleophile or electrophile or both to be stated. Concept introduction: A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site. To state: Whether CH 3 Cl will behave as nucleophile or electrophile or both.

Question

Which of the following species cannot be considered a nucleophile?

Answer 1

Question

Chapter 6.4, Problem 4P

Interpretation Introduction

a)

Interpretation:

Whether CH₃Cl is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃Cl will behave as nucleophile or electrophile or both.

Interpretation Introduction

b)

Interpretation:

Whether CH₃S^- is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃S^- will behave as nucleophile or electrophile or both.

Interpretation Introduction

c)

Interpretation:

Whether the compound given is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether the compound given will behave as nucleophile or electrophile or both.

Interpretation Introduction

d)

Interpretation:

Whether CH₃CHO is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃CHO will behave as nucleophile or electrophile or both.

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Which of the following species cannot be considered a nucleophile?

Predict whether the following nucleophiles are excellent nucleophiles, good nucleophiles, or poor nucleophiles based on their structure, and sort them accordingly.

Which of the following is/are false concerning nucleophiles donates an e- pair to an electrophile to form a chemical bond they are all molecules or ions with a free pair of electrons or at least one pi bond they are Lewis acids they are attracted to a full or partial positive charge

Answer 2

Question

Chapter 6.4, Problem 4P

Interpretation Introduction

a)

Interpretation:

Whether CH₃Cl is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃Cl will behave as nucleophile or electrophile or both.

Interpretation Introduction

b)

Interpretation:

Whether CH₃S^- is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃S^- will behave as nucleophile or electrophile or both.

Interpretation Introduction

c)

Interpretation:

Whether the compound given is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether the compound given will behave as nucleophile or electrophile or both.

Interpretation Introduction

d)

Interpretation:

Whether CH₃CHO is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃CHO will behave as nucleophile or electrophile or both.

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Answer 3

Question

Chapter 6.4, Problem 4P

Interpretation Introduction

a)

Interpretation:

Whether CH₃Cl is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃Cl will behave as nucleophile or electrophile or both.

Interpretation Introduction

b)

Interpretation:

Whether CH₃S^- is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃S^- will behave as nucleophile or electrophile or both.

Interpretation Introduction

c)

Interpretation:

Whether the compound given is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether the compound given will behave as nucleophile or electrophile or both.

Interpretation Introduction

d)

Interpretation:

Whether CH₃CHO is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃CHO will behave as nucleophile or electrophile or both.

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Answer 4

Question

Chapter 6.4, Problem 4P

Interpretation Introduction

a)

Interpretation:

Whether CH₃Cl is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃Cl will behave as nucleophile or electrophile or both.

Interpretation Introduction

b)

Interpretation:

Whether CH₃S^- is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃S^- will behave as nucleophile or electrophile or both.

Interpretation Introduction

c)

Interpretation:

Whether the compound given is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether the compound given will behave as nucleophile or electrophile or both.

Interpretation Introduction

d)

Interpretation:

Whether CH₃CHO is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃CHO will behave as nucleophile or electrophile or both.

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Answer 5

Chapter 6.4, Problem 4P

Interpretation Introduction

a)

Interpretation:

Whether CH₃Cl is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃Cl will behave as nucleophile or electrophile or both.

Interpretation Introduction

b)

Interpretation:

Whether CH₃S^- is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃S^- will behave as nucleophile or electrophile or both.

Interpretation Introduction

c)

Interpretation:

Whether the compound given is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether the compound given will behave as nucleophile or electrophile or both.

Interpretation Introduction

d)

Interpretation:

Whether CH₃CHO is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃CHO will behave as nucleophile or electrophile or both.

Answer 6

Chapter 6.4, Problem 4P

Interpretation Introduction

a)

Interpretation:

Whether CH₃Cl is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃Cl will behave as nucleophile or electrophile or both.

Answer 7

Chapter 6.4, Problem 4P

Interpretation Introduction

a)

Interpretation:

Whether CH₃Cl is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃Cl will behave as nucleophile or electrophile or both.

Answer 8

Interpretation Introduction

b)

Interpretation:

Whether CH₃S^- is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃S^- will behave as nucleophile or electrophile or both.

Answer 9

Interpretation Introduction

b)

Interpretation:

Whether CH₃S^- is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃S^- will behave as nucleophile or electrophile or both.

Answer 10

Interpretation Introduction

c)

Interpretation:

Whether the compound given is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether the compound given will behave as nucleophile or electrophile or both.

Answer 11

Interpretation Introduction

c)

Interpretation:

Whether the compound given is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether the compound given will behave as nucleophile or electrophile or both.

Answer 12

Interpretation Introduction

d)

Interpretation:

Whether CH₃CHO is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃CHO will behave as nucleophile or electrophile or both.

Answer 13

Interpretation Introduction

d)

Interpretation:

Whether CH₃CHO is likely to behave as a nucleophile or electrophile or both to be stated.

Concept introduction:

A nucleophile (either negatively charged or a neutral molecule containing an atom with at least one lone pair of electrons) has an electron rich-site. An electrophile (either positively charged or a neutral molecule containing an electron deficient atom) has an electron poor-site.

To state:

Whether CH₃CHO will behave as nucleophile or electrophile or both.

Answer 14

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Ch. 6.1 - Prob. 1P Ch. 6.3 - Prob. 2P Ch. 6.3 - Using curved fishhook arrows, propose a mechanism...Ch. 6.4 - Prob. 4P Ch. 6.4 - An electrostatic potential map of boron...Ch. 6.5 - What product would you expect from reaction of...Ch. 6.5 - Reaction of HBr with 2-methylpropene yields...Ch. 6.6 - Prob. 8P Ch. 6.6 - Predict the products of the following polar...Ch. 6.7 - Which reaction is more energetically favored, one...

Solution Summary: The author explains that the C-Cl bond in CH 3 Cl is polar as chlorine is more electronegative than carbon.

Chapter 6 Solutions