Fundamentals of Chemical Engineering Thermodynamics (MindTap Course List)
Fundamentals of Chemical Engineering Thermodynamics (MindTap Course List)
1st Edition
ISBN: 9781111580704
Author: Kevin D. Dahm, Donald P. Visco
Publisher: Cengage Learning
Question
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Chapter 6.6, Problem 14P

A)

Interpretation Introduction

Interpretation:

The work produced in the turbine has to be determined.

Concept introduction:

Use the given equation of state derive the value of residual molar internal energy, enthalpy, and entropy in terms of constant, temperature, and coefficient of thermal expansion then use the energy balance and entropy expression to obtain the work produced in the turbine and the actual temperature of the exiting stream.

The expression for the reversible process for a turbine is given as follows:

S_2S_1=0S_2R+(S_2igS_1ig)S_1R=0

Here, turbine inlet and outlet molar entropy is S_1 and S_2, inlet and outlet turbine residual molar entropy is S_1R and S_2R, turbine inlet and outlet molar entropy for an ideal gas state is S_1ig and S_2ig respectively.

The expression for the change in entropy as given as follows:

S_2igS_1ig=CPln(T2,revT1)+Rln(P1P2)

Here, constant pressure heat capacity on a mass basis is CP, gas constant is R, inlet temperature and pressure is T1 and P1, outlet pressure of turbine is P2, and outlet temperature for a reversible process is T2,rev.

The expression for the efficiency of the turbine;

η=W˙S,actW˙S,rev

theexpression for the work produced in the turbine is given as follows:

W˙S,actn˙=CP(T2T1)

Here, actual temperature of the exiting stream is T2.

B)

Interpretation Introduction

Interpretation:

The actual temperature of the exiting stream has to be determined.

Concept introduction:

Write the expression for the work produced in the turbine is given as follows:

W˙S,actn˙=CP(T2T1)

Here, actual temperature of the exiting stream is T2.

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