BuyFindarrow_forward

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074

Solutions

Chapter
Section
BuyFindarrow_forward

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074
Textbook Problem

One compound found in alkaline batteries is NiOOH, a compound containing Ni3+ ions. When the battery is discharged, the Ni3+ is reduced to Ni2+ ions [as in Ni(OH)2]. Using orbital box diagrams and the noble gas notation, show electron configurations of these ions. Are either of these ions paramagnetic?

Interpretation Introduction

Interpretation:

For the Nickel ions given Ni2+ and Ni3+ ions electronic configuration and magnetic properties has to be derived using its orbital notation box and noble gas electron filling method.

Concept Introduction:

Electronic configuration: The electronic configuration is the distribution of electrons of an given molecule or respective atoms in atomic or molecular orbitals.

The important there rules for electronic configuration given below:

Paramagnetic: The Paramagnetic properties are due to the presence of some unpaired electrons, and from the realignment of the electron paths caused by the external magnetic field.

Diamagnetic properties: In diamagnetic materials all the electron are paired so there is no permanent net magnetic moment per atom.

Explanation
  • Now we consider the orbital filling method for Nickel element.

  AtomicnumberofNickel(Ni)=28spdfwith orbtital notation=[1s22s22p63s23p63d84s2Orbital filling method       1s22s22p63s23p63d84s2spdfwith noble gas notation=[Ar]3d84s2Orbitalboxnotation       =  [Ar]3d84s2

The electronic configuration of Nickel (Ni) = 1s22s22p63s23p63d84s2 and noble gas configuration of [Ar]3d84s2 

  • Let us consider the orbital filling method of Nickel (Ni2+) ions

Than Nickel (Ni) atom were oxidized to (Ni2+) ions, it lost for two electrons in outermost (4s) orbitals.

This electronic filling method is shown below.

  AtomicnumberofNickel(Ni)=28Loss of four electrons in Nickelatoms=28-2=26spdfwith orbtital notation=[1s22s22p63s23p63d84s0Orbital filling method       1s22s22p63s2

Still sussing out bartleby?

Check out a sample textbook solution.

See a sample solution

The Solution to Your Study Problems

Bartleby provides explanations to thousands of textbook problems written by our experts, many with advanced degrees!

Get Started

Additional Science Solutions

Find more solutions based on key concepts

Show solutions add

What are the moral implications of using ergogenic aids?

Understanding Nutrition (MindTap Course List)

Digestible carbohydrates are absorbed as through the small intestinal wall and are delivered to the liver, whic...

Nutrition: Concepts and Controversies - Standalone book (MindTap Course List)

Provide two reasons why meiosis leads to genetic variation in diploid organisms.

Human Heredity: Principles and Issues (MindTap Course List)