Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Question
Chapter 7, Problem 38QAP
Interpretation Introduction
(a)
Interpretation:
The ideal bond angles in
Concept introduction:
- In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.
- The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.
- The geometry of a given can be predicted based on the general formula: AXn Em where A = central atom, X = surrounding atoms, E = lone pairs on the central atom
Interpretation Introduction
(b)
Interpretation:
The ideal bond angles in BF3 need to be determined.
Concept introduction:
- In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.
- The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.
- The geometry of a given can be predicted based on the general formula: AXn Em where A = central atom, X = surrounding atoms, E = lone pairs on the central atom
Interpretation Introduction
(c)
Interpretation:
The ideal bond angles in HNO3 need to be determined.
Concept introduction:
- In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.
- The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.
- The geometry of a given can be predicted based on the general formula: AXn Em where A = central atom, X = surrounding atoms, E = lone pairs on the central atom
Interpretation Introduction
(d)
Interpretation:
The ideal bond angles in CH3 NH2 need to be determined.
Concept introduction:
- In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.
- The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.
- The geometry of a given can be predicted based on the general formula: AXn Em where A = central atom, X = surrounding atoms, E = lone pairs on the central atom
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Chapter 7 Solutions
Chemistry: Principles and Reactions
Ch. 7 - Prob. 1QAPCh. 7 - Prob. 2QAPCh. 7 - Follow the directions of Question 1 for (a) IO2-...Ch. 7 - Follow the directions of Question 1 for (a) CIF4-...Ch. 7 - Follow the directions of Question 1 for (a) OCl2...Ch. 7 - Follow the directions of Question 1 for (a) C22-...Ch. 7 - Oxalic acid, H2C2O4, is a poisonous compound found...Ch. 7 - Radio astronomers have detected the isoformyl ion,...Ch. 7 - Draw Lewis structures for the following species....Ch. 7 - Follow the directions of Question 9 for the...
Ch. 7 - Dinitrogen pentoxide, N2O5, when bubbled into...Ch. 7 - Formic acid is the irritating substance that gets...Ch. 7 - Two different molecules have the formula C2H2Cl2....Ch. 7 - Two different molecules have the formula C2H6O....Ch. 7 - Prob. 15QAPCh. 7 - Prob. 16QAPCh. 7 - Write a Lewis structure for (a) XeF3+ (b) PCl4+...Ch. 7 - Write a Lewis structure for (a) BCl4 (b) ClO- (c)...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Prob. 21QAPCh. 7 - Draw resonance structures for (a) SeO3 (b) CS32-...Ch. 7 - Prob. 23QAPCh. 7 - Prob. 24QAPCh. 7 - The skeleton structure for disulfur dinitride,...Ch. 7 - Borazine, B3N3H6, has the skeleton Draw the...Ch. 7 - What is the formal charge on the indicated atom in...Ch. 7 - Prob. 28QAPCh. 7 - Below are two different Lewis structures for...Ch. 7 - Below are two different Lewis structures for the...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Give all the ideal bond angles (109.5, 120, or...Ch. 7 - Prob. 38QAPCh. 7 - Prob. 39QAPCh. 7 - An objectionable component of smog is acetyl...Ch. 7 - The uracil molecule is one of the bases in DNA....Ch. 7 - Niacin is one of the B vitamins (B3). Estimate the...Ch. 7 - Which of the species with octets in Question 31...Ch. 7 - Which of the species with octets in Question 32...Ch. 7 - Which of the species with octets in Question 33...Ch. 7 - Prob. 46QAPCh. 7 - There are three compounds with the formula...Ch. 7 - There are two different molecules with the formula...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - In each of the following polyatomic ions, the...Ch. 7 - Follow the directions of Question 55 for the...Ch. 7 - Give the hybridization of each atom (except H) in...Ch. 7 - Acrylonitrile, C3H3N is the building mer Orlon....Ch. 7 - What is the hybridization of nitrogen inCh. 7 - What is the hybridization of carbon inCh. 7 - Give the hybridization of the central atom...Ch. 7 - Give the hybridization of the central atom...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - In which of the following molecules does the...Ch. 7 - Consider the pyrosulfate ion, S2O72-. It has no...Ch. 7 - Consider acetyl salicylic acid, better known as...Ch. 7 - Complete the table on next page.Ch. 7 - Given the following electro negativities...Ch. 7 - Based on the concept of formal charge, what is the...Ch. 7 - Describe the geometry of the species in which...Ch. 7 - Consider the following molecules: SiH4, PH3, H2S....Ch. 7 - Prob. 75QAPCh. 7 - In each of the following molecules, a central atom...Ch. 7 - Prob. 77QAPCh. 7 - A compound of chlorine and fluorine, CIFx, reacts...Ch. 7 - Draw the Lewis structure and describe the geometry...Ch. 7 - Consider the polyatomic ion IO65-. How many pairs...Ch. 7 - It is possible to write a simple Lewis structure...Ch. 7 - Phosphoryl chloride, POCl3, has the skeleton...
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- A paper published in the research Journal Science in 2007 (S. Vallina and R. Simo, Science, Vol. 315, p. 506, January 26, 2007) reported studies of dimethylsulfide (DMS), an important green-house gas that is released by marine phytoplankton. This gas represents the largest natural source of atmospheric sulfur and a major precursor of hygroscopic (i.e., cloud-forming) particles in clean air over the remote oceans, thereby acting to reduce the amount of solar radiation that crosses the atmosphere and is absorbed by the ocean. (a) Sketch the Lewis structure of dimethylsulfide, CH3SCH3, and list the bond angles in the molecule. (b) Use electronegativities to decide where the positive and negative charges lie in the molecule. Is the molecule polar? (c) The mean seawater concentration of DMS in the ocean in the region between 15 north latitude and 15 south latitude is 2.7 nM (nanomolar). How many molecules of DMS are present in 1.0 m3 of seawater?arrow_forwardWhat is the lewis dot structrue for C2H3O2Clarrow_forwardIn the methoxide anion (CH3O-), is it possible for a double bond to exist between C and O, given that the negative chargeresides on O? Explain why or why not.arrow_forward
- Identify the name of the Following bond line-structures.arrow_forwardHydrazine (N2H4) is used as a reducing agent and in themanufacture of rocket fuels. How do you expect its boiling point to compare with that of ethylene (C2H4)?arrow_forwardHow many electron groups does the central atom of CH2O have according to VSEPR theory?arrow_forward
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