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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Chapter
Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

Any —OH group to the left of a chiral center in a Fischer projection formula points in which of the following directions in a Haworth projection formula?

  1. a. points to the right
  2. b. points up
  3. c. points down
  4. d. no correct response

Interpretation Introduction

Interpretation: In Haworth projection, the direction of any OH group which point left of a chiral center in a Fisher projection formula has to be predicted.

Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection.  The substituents which are present on the right side in the Fischer projection are drawn below the ring in the Haworth projection.  Similarly, the substituents which are present on the left side in the Fischer projection are drawn above the ring in the Haworth projection.

Explanation

Reason for correct option:

The substituents which are present on the left side in the Fischer projection are drawn above the ring in the Haworth projection.  Therefore, the OH group to the left of a chiral center in a Fisher projection formula will point in upward direction

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