Organic Chemistry As a Second Language: Second Semester Topics
Organic Chemistry As a Second Language: Second Semester Topics
4th Edition
ISBN: 9781119110651
Author: David R. Klein
Publisher: WILEY
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Chapter 7.7, Problem 7.48P
Interpretation Introduction

Interpretation:

Efficient synthesis has to be proposed for the given transformation.

Organic Chemistry As a Second Language: Second Semester Topics, Chapter 7.7, Problem 7.48P , additional homework tip 1

Expert Solution & Answer
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Explanation of Solution

Given transformation is,

Organic Chemistry As a Second Language: Second Semester Topics, Chapter 7.7, Problem 7.48P , additional homework tip 2

Looking into the reactant and product, it is found that the methoxy group is converted into chloride.  In order to accomplish the given transformation, the ester has to be converted into carboxylic acid and then to acid halide.

Conversion of carboxylic acid ester to carboxylic acid can be done using aqueous acid.

Organic Chemistry As a Second Language: Second Semester Topics, Chapter 7.7, Problem 7.48P , additional homework tip 3

Carboxylic acid when treated with thionyl chloride gives acid halide as the product.  This can be represented as,

Organic Chemistry As a Second Language: Second Semester Topics, Chapter 7.7, Problem 7.48P , additional homework tip 4

Therefore, the efficient synthesis can be given as,

Organic Chemistry As a Second Language: Second Semester Topics, Chapter 7.7, Problem 7.48P , additional homework tip 5

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Identify the reagents you would use to achieve each of the following transformations.
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Provide the reagents needed to accomplish the following transformations

Chapter 7 Solutions

Organic Chemistry As a Second Language: Second Semester Topics

Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Predict the major product in each of the following...Ch. 7.3 - Predict the major product in each of the following...Ch. 7.3 - Predict the major product in each of the following...Ch. 7.3 - Predict the major product in each of the following...Ch. 7.3 - Predict the major product in each of the following...
Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.4 - Predict the major products for each of the...Ch. 7.4 - Predict the major products for each of the...Ch. 7.4 - Predict the major products for each of the...Ch. 7.5 - Prob. 7.23PCh. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - In the space provided, draw a mechanism for each...Ch. 7.5 - In the space provided, draw a mechanism for each...Ch. 7.5 - Prob. 7.33PCh. 7.5 - Prob. 7.34PCh. 7.5 - Prob. 7.35PCh. 7.5 - Prob. 7.36PCh. 7.6 - Based on everything we have just seen, propose a...Ch. 7.6 - Prob. 7.39PCh. 7.6 - Prob. 7.40PCh. 7.6 - Prob. 7.41PCh. 7.6 - Propose a mechanism for the following reaction:Ch. 7.6 - Prob. 7.44PCh. 7.6 - Prob. 7.45PCh. 7.6 - Prob. 7.46PCh. 7.7 - Prob. 7.48PCh. 7.7 - Prob. 7.49PCh. 7.7 - Prob. 7.50PCh. 7.7 - Prob. 7.51PCh. 7.7 - Prob. 7.52PCh. 7.7 - Prob. 7.53PCh. 7.7 - Prob. 7.55PCh. 7.7 - Prob. 7.56PCh. 7.7 - Prob. 7.57PCh. 7.7 - Prob. 7.58PCh. 7.7 - Prob. 7.59PCh. 7.7 - Prob. 7.60PCh. 7.7 - Prob. 7.61PCh. 7.7 - Prob. 7.62PCh. 7.7 - Prob. 7.63PCh. 7.7 - Prob. 7.64PCh. 7.7 - Prob. 7.65P
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