Chemistry for Today: General, Organic, and Biochemistry
Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Textbook Question
Chapter 8, Problem 8.52E

Use Le Chȃtelier’s principle to predict the direction of the equilibrium shift in the following equilibria when the indicated stress is applied:

a. Ag + ( aq ) + Cl ( aq ) AgCl ( s ) ; some Ag + is removed.

b. 2 HI ( g ) + heat H 2 ( g ) + I 2 ( g ) ; the system is heated.

c. 6Cu ( s ) + N 2 ( g ) + heat 2Cu 3 N ( s ) ; the system is cooled and some N 2 is removed.

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Chapter 8 Solutions

Chemistry for Today: General, Organic, and Biochemistry

Ch. 8 - Classify the following processes according to...Ch. 8 - Describe the observations or measurements that...Ch. 8 - Prob. 8.13ECh. 8 - Consider the following hypothetical reaction: A+BC...Ch. 8 - Consider the following hypothetical reaction: A+BC...Ch. 8 - A reaction generates chlorine gas (Cl2) as a...Ch. 8 - A reaction generates hydrogen gas (H2) as a...Ch. 8 - Prob. 8.18ECh. 8 - Prob. 8.19ECh. 8 - In each of the following, which reaction mechanism...Ch. 8 - Which reaction mechanism assumptions are...Ch. 8 - Prob. 8.22ECh. 8 - Sketch energy diagrams to represent each of the...Ch. 8 - Prob. 8.24ECh. 8 - Use energy diagrams to compare catalyzed and...Ch. 8 - Prob. 8.26ECh. 8 - The following reactions are proposed. Make a rough...Ch. 8 - Prob. 8.28ECh. 8 - Prob. 8.29ECh. 8 - Suppose you are running a reaction and you want to...Ch. 8 - A reaction is started by mixing reactants. As time...Ch. 8 - A reaction is run at 10C and takes 3.7hours to go...Ch. 8 - What factor is more important than simply the...Ch. 8 - Prob. 8.34ECh. 8 - Describe the establishment of equilibrium in a...Ch. 8 - Prob. 8.36ECh. 8 - Prob. 8.37ECh. 8 - Colorless hydrogen gas (H2) and red-brown colored...Ch. 8 - Colorless N2O4 gas decomposes to form red-brown...Ch. 8 - Prob. 8.40ECh. 8 - Write an equilibrium expression for each of the...Ch. 8 - Prob. 8.42ECh. 8 - Prob. 8.43ECh. 8 - Prob. 8.44ECh. 8 - Prob. 8.45ECh. 8 - A sample of gaseous BrCl is allowed to decompose...Ch. 8 - At 600C, gaseous CO and Cl2 are mixed together in...Ch. 8 - A mixture of the gases NOCl, Cl2 and NO is allowed...Ch. 8 - Consider the following equilibrium constants....Ch. 8 - Prob. 8.50ECh. 8 - Use Le Chteliers principle to predict the...Ch. 8 - Use Le Chteliers principle to predict the...Ch. 8 - Use Le Chteliers principle to predict the...Ch. 8 - Prob. 8.54ECh. 8 - Tell what will happen to each equilibrium...Ch. 8 - Tell what will happen to each equilibrium...Ch. 8 - The gaseous reaction 2HBr(g)H2(g)+Br2(g) is...Ch. 8 - Prob. 8.58ECh. 8 - Prob. 8.59ECh. 8 - Prob. 8.60ECh. 8 - Prob. 8.61ECh. 8 - Prob. 8.62ECh. 8 - Prob. 8.63ECh. 8 - Prob. 8.64ECh. 8 - Prob. 8.65ECh. 8 - Prob. 8.66ECh. 8 - Refer to Figure 8.10 and answer the questions....Ch. 8 - Refer to Figure 8.13 and answer the questions....Ch. 8 - Prob. 8.69ECh. 8 - Prob. 8.70ECh. 8 - Suppose you have two identical unopened bottles of...Ch. 8 - Someone once suggested that it is impossible to...Ch. 8 - A reaction takes place between an acid and...Ch. 8 - If the reaction:A+BC+D is designated as first...Ch. 8 - Prob. 8.75ECh. 8 - A book is held 6 feet above the floor and then...Ch. 8 - Prob. 8.77ECh. 8 - Prob. 8.78ECh. 8 - Prob. 8.79ECh. 8 - Prob. 8.80ECh. 8 - Prob. 8.81ECh. 8 - Which of the following is the best example of...Ch. 8 - Which is NOT an example of an endothermic change?...Ch. 8 - Which of the following processes is endothermic?...Ch. 8 - Which sentence best describes the following...Ch. 8 - By which of the following mechanisms does a...Ch. 8 - Which of the following is NOT true of reversible...Ch. 8 - Given the reaction: 2CO(g)+O2(g)2CO2(g) When there...Ch. 8 - Prob. 8.89ECh. 8 - Consider the reaction N2(g)+3H2(g)2NH3(g)+heat....Ch. 8 - Prob. 8.91ECh. 8 - Prob. 8.92ECh. 8 - For the reaction: H2(g)+Br2(g)2HBr(g), the...Ch. 8 - Prob. 8.94E
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  • What is Le Chteliers principle? Consider the reaction 2NOCI(g)2NO(g)+Cl2(g) If this reaction is at equilibrium. what happens when the following changes occur? a. NOCI(g) is added. b. NO(g) is added. c. NOCI(g) is removed. d. Cl2(g) is removed. e. The container volume is decreased. For each of these changes, what happens to the value of K for the reaction as equilibrium is reached again? Give an example of a reaction for which the addition or removal of one of the reactants or products has no effect on the equilibrium position. In general, how will the equilibrium position of a gas-phase reaction be affected if the volume of the reaction vessel changes? Are there reactions that will not have their equilibria shifted by a change in volume? Explain. Why does changing the pressure in a rigid container by adding an inert gas not shift the equilibrium position for a gas-phase reaction?
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