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The sulfamate ion, H 2 NSO 3 – , can be thought of as having been formed from the amide ion, NH 2 – , and sulphur trioxide, SO 3 . (a) What are the electron-pair and molecular geometries or the amide ion and or SO 3 ? What are the hybridizations of the N and S atoms, respectively? (b) Sketch a structure for the sulfamate ion, and estimate the bond angles. (c) What changes in hybridization do you expect for N and S in the course of the reaction NH 2 – + SO 3 → H 2 N—SO 3 – ? (d) Is SO 3 the donor of an electron pair or the acceptor of an electron pair in the reaction with amide ion? Does the electrostatic potential map shown below confirm your prediction?

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Chemistry & Chemical Reactivity

9th Edition
John C. Kotz + 3 others
Publisher: Cengage Learning
ISBN: 9781133949640

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Chapter
Section
BuyFindarrow_forward

Chemistry & Chemical Reactivity

9th Edition
John C. Kotz + 3 others
Publisher: Cengage Learning
ISBN: 9781133949640
Chapter 9, Problem 53IL
Textbook Problem
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The sulfamate ion, H2NSO3, can be thought of as having been formed from the amide ion, NH2, and sulphur trioxide, SO3.

(a) What are the electron-pair and molecular geometries or the amide ion and or SO3? What are the hybridizations of the N and S atoms, respectively?

(b) Sketch a structure for the sulfamate ion, and estimate the bond angles.

(c) What changes in hybridization do you expect for N and S in the course of the reaction

NH2 + SO3 → H2N—SO3?

(d) Is SO3 the donor of an electron pair or the acceptor of an electron pair in the reaction with amide ion? Does the electrostatic potential map shown below confirm your prediction?

Chapter 9, Problem 53IL, The sulfamate ion, H2NSO3, can be thought of as having been formed from the amide ion, NH2, and

(a)

Interpretation Introduction

Interpretation:

Electron pair and molecular geometries of the amide ion and of SO3 and the hybridizations of respective central atoms should be determined.

Concept Introduction:

Hybridization is the mixing of valence atomic orbitals to get equivalent hybridized orbitals that having similar characteristics and energy.

Electron geometry is the shape of a molecule predicted by considering both bond electron pairs and lone pair of electrons.

Molecular geometry is the shape of a molecule predicted by considering only bond pair of electrons

Geometry of different types of molecule with respect to the hybridizations are mentioned are mentioned below,

TypeofmoleculeHybridaizationAtomicorbitalsusedforhybridaizationGeometryAX2sp1s+1pLinearAX3,AX2Bsp21s+2pTrigonalplanarAX4,AX3B,AX2B2sp31s+3pTetrahedralAX5,AX4B,AX3B2,AX2B3sp3d1s+3p+1dTrigonalbipyramidalAX6,AX5B,AX4B2sp3d21s+3p+2dOctahedralACentralatomXAtomsbondedtoABNonbondingelectronpairsonA

Explanation of Solution

The Lewis structure and molecular geometry and hybridization of amine ion and sulfur trioxide molecule can be determined as follows,

Sulfur trioxide (SO3) molecule

Lewis structure has shown below for SO3

The Lewis structure of amide (NH2 ) ions

(b)

Interpretation Introduction

Interpretation:

Structure of sulfamate ion should be drawn and its bond angles should be determined.

Concept Introduction:

Hybridization is the mixing of valence atomic orbitals to get equivalent hybridized orbitals that having similar characteristics and energy.

TypeofmoleculeHybridaizationGeometryBondangleAX2spLinear180°AX3,AX2Bsp2Trigonalplanar120°AX4,AX3B,AX2B2sp3Tetrahedral109.5°AX5,AX4B,AX3B2,AX2B3sp3dTrigonalbipyramidal120°,90°AX6,AX5B,AX4B2sp3d2Octahedral90°ACentralatomXAtomsbondedtoABNonbondingelectronpairsonA

(c)

Interpretation Introduction

Interpretation:

Changes in hybridization for Nitrogen and Sulfur should be determined for the given reaction.

Concept Introduction:

Hybridization is the mixing of valence atomic orbitals to get equivalent hybridized orbitals that having similar characteristics and energy.

TypeofmoleculeHybridaizationGeometryBondangleAX2spLinear180°AX3,AX2Bsp2Trigonalplanar120°AX4,AX3B,AX2B2sp3Tetrahedral109.5°AX5,AX4B,AX3B2,AX2B3sp3dTrigonalbipyramidal120°,90°AX6,AX5B,AX4B2sp3d2Octahedral90°ACentralatomXAtomsbondedtoABNonbondingelectronpairsonA

(d)

Interpretation Introduction

Interpretation:

Based on the given electrostatic potential map of sulfur trioxide, check whether the SO3 is the donor of an electron pair or the acceptor of an electron pair in the reaction with amide ion.

Concept Introduction:

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Chemistry & Chemical Reactivity
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